N-ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide | 557788-37-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide
• 英文别名: N-ethyl-N-(2-methoxyethyl)-N,N-dimethylammonium bis(trifluoromethanesulfonyl)amide；[N112,1O2]NTf2；Ethyl(2-methoxyethyl)dimethylammonium Bis(trifluoromethanesulfonyl)imide；bis(trifluoromethylsulfonyl)azanide;ethyl-(2-methoxyethyl)-dimethylazanium
• CAS: 557788-37-1
• 化学式: C₂F₆NO₄S₂*C₇H₁₈NO
• 分子量: 412.375
• InChiKey: NGLLWWMHAWYWLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.79
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  95.3
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  2-甲氧基-N,N-二甲基乙胺 以 水 、 乙腈 为溶剂， 反应 52.0h， 生成 N-ethyl-N,N-dimethyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide
  参考文献：
  名称：

  Dialkoxy functionalized quaternary ammonium ionic liquids as potential electrolytes and cellulose solvents

  摘要：

  一系列新型离子液体，基于二烷氧基功能化季铵阳离子{侧链：1=CH3、1O1=CH3OCH2、1O2=CH3OC2H4、2O2=C2H5OC2H4；阳离子：[N11,1O1,1O2]、[N11,1O1,2O2]、[N11,1O2,1O2]、[N11,1O2,2O2] 和 [N11,2O2,2O2]}，含 BF4−、(CF3SO2)已制备并表征了 2N− (NTf2) 和 CH3CO2− (OAc) 作为抗衡阴离子。对它们的光谱特性、熔点、玻璃化转变温度、热稳定性、电化学窗口、密度、折射率、粘度和电导率等基本性能进行了测量和比较研究。两条柔性烷氧基链的引入使得季铵盐非常适合作为低粘度和高导电性的室温离子液体，甚至其中一些季铵盐的流动性明显优于相似分子量的流行咪唑离子液体，例如[N11] ,1O1,2O2]BF4（151 cP 和 2.11 mS cm−1，Mw：249）与 [HMIm]BF4（220 cP 和 1.2 mS cm−1，Mw：256），25 °C。这些离子液体的电化学窗口高达 5.5 V。此外，发现二烷氧基 OAc 离子液体在温和条件下（例如在室温下）对纤维素具有优异的溶解能力。 80 °C 下 18 wt% 微晶纤维素的 [N11,2O2,2O2]OAc 溶液。通过用水沉淀，溶解的纤维素（I 晶体结构）再生为纳米纤维素 II 颗粒，其表面积增加，结晶度降低（由 FE-SEM 和 XRD 测定）。

  DOI：

  10.1039/c1nj20062c

文献信息

• IONIC COMPOUNDS HAVING A SILYLOXY GROUP
  申请人：HYDRO-QUÉBEC

  公开号：US20150093655A1

  公开（公告）日：2015-04-02

  There is provided an ionic compound having attached thereto a silyloxy group. There is also provided methods of making this ionic compound as well as electrolytes, electrochemical cells and capacitors comprising this ionic compound.

  提供了一种具有硅氧基团的离子化合物。还提供了制备该离子化合物的方法，以及包含该离子化合物的电解质、电化学电池和电容器。
• Low-Melting, Low-Viscous, Hydrophobic Ionic Liquids: Aliphatic Quaternary Ammonium Salts with Perfluoroalkyltrifluoroborates
  作者：Zhi-Bin Zhou、Hajime Matsumoto、Kuniaki Tatsumi

  DOI：10.1002/chem.200400817

  日期：2005.1.7

  A novel class of low-melting, hydrophobic ionic liquids based on relatively small aliphatic quaternary ammonium cations ([R(1)R(2)R(3)NR](+), wherein R(1), R(2), R(3) = CH(3) or C(2)H(5), R = n-C(3)H(7), n-C(4)H(9), CH(2)CH(2)OCH(3)) and perfluoroalkyltrifluoroborate anions ([R(F)BF(3)](-), R(F) = CF(3), C(2)F(5), n-C(3)F(7), n-C(4)F(9)) have been prepared and characterized. The important physicochemical

  基于相对较小的脂族季铵阳离子（[R（1）R（2）R（3）NR]（+）的新型一类低熔点疏水离子液体，其中R（1），R（2）， R（3）= CH（3）或C（2）H（5），R = nC（3）H（7），nC（4）H（9），CH（2）CH（2）OCH（3 ））和全氟烷基三氟硼酸根阴离子（[R（F）BF（3）]（-），R（F）= CF（3），C（2）F（5），nC（3）F（7），nC（ 4）F（9））已经制备并表征。已经确定了这些盐的重要物理化学和电化学性质，包括熔点，玻璃化转变，粘度，密度，离子电导率，热和电化学稳定性，并与基于相应的[BF（4）]（-）的那些进行了比较研究。和[（CF（3）SO（2））（2）N]（-）盐。讨论了季铵阳离子和全氟烷基三氟硼酸根（[R（F）BF（3）]（-））阴离子中的结构变化对上述理化性质的影响。这些盐大多数在25摄氏度时为液体，并且粘度低（在25摄氏度时为58-210
• ELECTRORECOVERY OF METALS
  申请人：Rodopoulos Theo

  公开号：US20120000790A1

  公开（公告）日：2012-01-05

  A method and ionic liquid for the electrorecovery of metal from a metal salt including at least one metal ion. The method includes the steps of dissolving the metal salt in an ionic liquid, the ionic liquid including an ionic liquid cation and an ionic liquid anion; whereby the metal ion of the metal salt forms a metal complex in solution with at least the ionic liquid cation; and subjecting the metal complex to an electrical potential between a cathode and anode to recover metal at the cathode. The ionic liquid includes an ionic liquid cation and an ionic liquid anion, wherein the ionic liquid cation has an affinity for the metal ion which is at least about equal to that of the ionic liquid anion for the metal ion.
• Dialkoxy functionalized quaternary ammonium ionic liquids as potential electrolytes and cellulose solvents
  作者：Zhengjian Chen、Shimin Liu、Zuopeng Li、Qinghua Zhang、Youquan Deng

  DOI：10.1039/c1nj20062c

  日期：——

  A series of new ionic liquids, based on dialkoxy-functionalized quaternary ammonium cations side chains: 1 = CH3, 1O1 = CH3OCH2, 1O2 = CH3OC2H4, 2O2 = C2H5OC2H4; cations: [N11,1O1,1O2], [N11,1O1,2O2], [N11,1O2,1O2], [N11,1O2,2O2] and [N11,2O2,2O2]}, with BF4−, (CF3SO2)2N− (NTf2) and CH3CO2− (OAc) as counteranions, have been prepared and characterized. Their basic properties, such as spectroscopic characteristics, melting point, glass transition temperature, thermal stability, electrochemical window, density, refractive index, viscosity and conductivity, were measured and comparatively studied. The incorporation of two flexible alkoxy chains makes the quaternary ammonium salts highly qualified to be low-viscous and high-conductive room temperature ILs, and even some of them have significantly better fluidity than the popular imidazolium ILs with a similar molecular weight, e.g.[N11,1O1,2O2]BF4 (151 cP and 2.11 mS cm−1, Mw: 249) vs.[HMIm]BF4 (220 cP and 1.2 mS cm−1, Mw: 256) at 25 °C. The electrochemical windows of these ILs were evaluated up to 5.5 V. In addition, the dialkoxy OAc ILs were found to have excellent solvent power for cellulose under mild conditions, e.g. a solution of 18 wt% microcrystalline cellulose in [N11,2O2,2O2]OAc at 80 °C. By precipitation with water, the dissolved cellulose (I crystal structure) was regenerated as nanosized cellulose II particles with increased surface area and decreased crystallinity, determined by FE-SEM and XRD.

  一系列新型离子液体，基于二烷氧基功能化季铵阳离子侧链：1=CH3、1O1=CH3OCH2、1O2=CH3OC2H4、2O2=C2H5OC2H4；阳离子：[N11,1O1,1O2]、[N11,1O1,2O2]、[N11,1O2,1O2]、[N11,1O2,2O2] 和 [N11,2O2,2O2]}，含 BF4−、(CF3SO2)已制备并表征了 2N− (NTf2) 和 CH3CO2− (OAc) 作为抗衡阴离子。对它们的光谱特性、熔点、玻璃化转变温度、热稳定性、电化学窗口、密度、折射率、粘度和电导率等基本性能进行了测量和比较研究。两条柔性烷氧基链的引入使得季铵盐非常适合作为低粘度和高导电性的室温离子液体，甚至其中一些季铵盐的流动性明显优于相似分子量的流行咪唑离子液体，例如[N11] ,1O1,2O2]BF4（151 cP 和 2.11 mS cm−1，Mw：249）与 [HMIm]BF4（220 cP 和 1.2 mS cm−1，Mw：256），25 °C。这些离子液体的电化学窗口高达 5.5 V。此外，发现二烷氧基 OAc 离子液体在温和条件下（例如在室温下）对纤维素具有优异的溶解能力。 80 °C 下 18 wt% 微晶纤维素的 [N11,2O2,2O2]OAc 溶液。通过用水沉淀，溶解的纤维素（I 晶体结构）再生为纳米纤维素 II 颗粒，其表面积增加，结晶度降低（由 FE-SEM 和 XRD 测定）。