3-mercaptobenzene-1,2-diol

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3-mercaptobenzene-1,2-diol
• 英文别名: Monothiocatechol；3-sulfanylbenzene-1,2-diol
• 化学式: C₆H₆O₂S
• 分子量: 142.178
• InChiKey: CXMBJBCPGQIVET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.5
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-苯醌 在 H₂S(x) 作用下， 以3%的产率得到5,6,7,8,9-penthathiabenzocycloheptane-1,2-diol
  参考文献：
  名称：

  Regioselective (Biomimetic) Synthesis of a Pentasulfane from ortho-Benzoquinone

  摘要：

  A mechanism is proposed for the formation of cyclic 5,6,7,8,9-pentathiabenzocycloheptene-1,2-diol, 4, from the reaction of o-benzoquinone with reduced elemental sulfur, H2Sx. 1,6-Conjugate addition to the quinone is favored over 1,4-conjugate addition. Hydrogen bonding to the quinone oxygen enhances the nucleophilicity of H2Sx by facilitating the removal of the S-H proton. We propose that initially formed 3-polysulfidobenzene-diol intermediates are oxidized to their corresponding quinones and closure of the polysulfur ring subsequently takes place at the C3-C4 bond leading to 4. A possible mechanism for the formation of the pentasulfur linkage in 4 is discussed, which is the key moiety found in a number of natural products.

  DOI：

  10.1021/jo062677w

文献信息

• [EN] MODIFIED THIOXANTHONE PHOTOINITIATORS<br/>[FR] PHOTO-INITIATEURS À THIOXANTHONE MODIFIÉS
  申请人：LINTFIELD LTD

  公开号：WO2021144582A1

  公开（公告）日：2021-07-22

  Latent photoinitiator compounds are described, as well as compositions containing such compounds and their uses in photoinitated methods for producing photoresist structured.

  潜在的光引发剂化合物被描述，以及含有这种化合物的组合物，以及它们在生产光阻结构的光引发方法中的用途。
• Polymer stabilising compositions, polymers stabilised therewith and shaped articles formed from such polymers
  申请人：MORTON THIOKOL, INC.

  公开号：EP0062406A1

  公开（公告）日：1982-10-13

  Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic tin compound or mixture of organic tin compounds, (2) an organic compound having an aromatic ring which is substituted with a hydroxyl (-OH) group and a mercapto (-SH) group ortho to each other, and, optionally, (3) an organotin mercaptide or mixture of organotin mercaptides. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.

  本发明提供了可有效稳定聚合物以防止受热变质的组合物，该组合物包含：(1) 有机锡化合物或有机锡化合物混合物；(2) 具有被羟基（-OH）和巯基（-SH）相互正交取代的芳香环的有机化合物；以及 (3) 有机锡巯化物或有机锡巯化物混合物。此外，还提供了含有所述稳定剂的聚合物组合物和由所述稳定化聚合物组合物制成的制成品。
• Verfahren zur Herstellung von Polycarbonaten mit Sulfonanilid-Endgruppen
  申请人：BAYER AG

  公开号：EP0082383A1

  公开（公告）日：1983-06-29

  Die vorliegende Anmeldung beschreibt die Herstellung von aromatischen Polycarbonaten nach den bekannten Zweiphasen-Grenzflächenverfahren, ausgehend von Diphenolen dadurch gekennzeichnet, daß aromatische Sulfonanilide als Kettenabbrecher gebraucht werden uns zwar in Konzentrationen von 2 Mol% bis 20 Mol%, vorzugsweise in Konzentrationen von 2,5 Mol% bis 10 Mol%, bezogen auf die Mole der verwendeten Diphenolen. Zusätzlich bezieht sich die vorliegende Anmeldung auf aromatische Polycarbonate, die nach dem erfindungsgemäßen Herstellprozeß erhältlich sind. Die Produkte der vorliegenden Erfindung haben bessere selbstlöschende Eigenschaften im Vergleich zu Polycarbonaten ohne Sulfonamid-Endgruppen.

  本申请描述了根据已知的两相界面工艺，从二酚开始制备芳香族聚碳酸酯，其特征在于芳香族磺酰苯胺被用作链终止剂，即根据所用二酚的摩尔数，浓度为 2 摩尔%至 20 摩尔%，最好为 2.5 摩尔%至 10 摩尔%。此外，本申请还涉及可通过本发明的生产工艺获得的芳香族聚碳酸酯。与不含磺酰胺端基的聚碳酸酯相比，本发明的产品具有更好的自熄灭性能。
• Halogen-containing polymers stabilized with organic antimony compound and an ortho mercapto phenol compound
  申请人：MORTON THIOKOL, INC.

  公开号：EP0134348A1

  公开（公告）日：1985-03-20

  Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising 1) an organic antimony compound or mixture of organic antimony compounds and 2) an organic compound or mixture of organic compounds having an aromatic ring which is substituted with hydroxy (-OH) and mercapto (-SH) groups ortho to each other. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.

  本发明提供了可有效稳定聚合物以防止受热变质的组合物，该组合物包含：1）有机锑化合物或有机锑化合物混合物；2）有机化合物或有机化合物混合物，其芳香环被彼此正交的羟基（-OH）和巯基（-SH）取代。此外，还提供了含有上述稳定剂的聚合物组合物和由上述稳定化聚合物组合物制成的制成品。
• Polyol resins and coating compositions containing same
  申请人：MITSUI SEKIYU KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0211600A2

  公开（公告）日：1987-02-25

  Polyol resins are prepared from bisphenol type resins by at least two of the following processes: 1) chain extension 2) ring opening 3) esterification The resulting resins are useful in the preparation of coating compositions with good water and corrosion resistance, good solvent compatability and a reduced tendency to foam.

  多元醇树脂由双酚型树脂通过以下至少两种工艺制备而成： 1) 链延伸 2) 开环 3) 酯化 所得树脂可用于制备具有良好耐水性和耐腐蚀性、良好溶剂相容性和较低泡沫倾向的涂料组合物。