1,2-diphenyl ethanediimine

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,2-diphenyl ethanediimine
• 英文别名: Benzildiimine；1,2-diphenylethane-1,2-diimine
• 化学式: C₁₄H₁₂N₂
• 分子量: 208.263
• InChiKey: MKZIBTHMNDHCIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.7
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-diphenyl ethanediimine 、 二氯化硫 以67%的产率得到
  参考文献：
  名称：

  BUCHWALD H.; RUEHLMANN K., J. ORGANOMETAL. CHEM., 1979, 166, NO 1, 25-30

  摘要：

  DOI：
• 作为产物：
  描述：

  以 一氟三氯甲烷 、 丙酮 为溶剂， 生成 二氧化碳-13C 、 1,2-diphenyl ethanediimine
  参考文献：
  名称：

  Synthesis of a 13C,15N labeled imidazole and characterization of the 2,5-endoperoxide and its decomposition

  摘要：

  A synthesis of C-13, N-15 labeled imidazoles was developed which allows the direct detection of a transient 2,5-endoperoxide at -100 degreesC. The endoperoxide was thoroughly characterized by H-1,C-13 and N-15 NMR. Upon warming, the endoperoxide decomposes via a series of transient intermediates to (CO2)-C-13 and 1,2-diphenyl-ethanediimine. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01731-7

文献信息

• METHOD AND CATALYST FOR SYNTHESISING AZIRIDINE
  申请人：University of East Anglia

  公开号：US20150166478A1

  公开（公告）日：2015-06-18

  The present invention relates to methods of synthesising aziridines including isotopically labelled aziridines, said methods comprising contacting an imine or one or more precursors thereof with a diazo compound in the presence of a phosphoramide or a phosphoramide-derived catalyst. The present invention also relates to aziridines, modified aziridines and aziridine-derived compounds preparable by the aforementioned methods, and to phosphoramide or phosphoramide-derived catalysts suitable for use in such methods.

  本发明涉及合成环氧乙烷的方法，包括同位素标记的环氧乙烷，所述方法包括将亚胺或其一个或多个前体与重氮化合物在磷酰胺或磷酰胺衍生的催化剂存在下接触。本发明还涉及通过上述方法制备的环氧乙烷、改性环氧乙烷和环氧乙烷衍生化合物，以及适用于这种方法的磷酰胺或磷酰胺衍生的催化剂。
• [EN] LUMINOGENS FOR BIOLOGICAL APPLICATIONS<br/>[FR] LUMINOGÈNES POUR APPLICATIONS BIOLOGIQUES
  申请人：UNIV HONG KONG SCI & TECH

  公开号：WO2018108070A1

  公开（公告）日：2018-06-21

  A compound comprises a donor and an acceptor, wherein at least one donor ( "D" ) and at least one acceptor ( "A" ) may be arranged in an order of D-A; D-A-D; A-D-A; D-D-A-D-D; A-A-D-A-A; D-A-D-A-D; and A-D-A-D-A. The compound may be selected from the group consisting of: MTPE-TP, MTPE-TT, TPE-TPA-TT, PTZ-BT-TPA, NPB-TQ, TPE-TQ-A, MTPE-BTSe, DCDPP-2TPA, DCDPP-2TPA4M, DCDP-2TPA, DCDP-2TPA4M, TTS, ROpen-DTE-TPECM, and RClosed-DTE-TPECM. The compound may be used as a probe and may be functionalized with special targeted groups to image biological species. As non-limiting examples, the compound may be used in cellular cytoplasms or tissue imaging, blood vessel imaging, in vivo fluorescence imaging, brain vascular imaging, sentinel lymph node mapping, and tumor imaging, and the compound may be used as a photoacoustic agent.

  一种化合物包括一个给体和一个受体，其中至少一个给体（"D"）和至少一个受体（"A"）可以按照D-A；D-A-D；A-D-A；D-D-A-D-D；A-A-D-A-A；D-A-D-A-D；和A-D-A-D-A的顺序排列。该化合物可从以下组中选择：MTPE-TP，MTPE-TT，TPE-TPA-TT，PTZ-BT-TPA，NPB-TQ，TPE-TQ-A，MTPE-BTSe，DCDPP-2TPA，DCDPP-2TPA4M，DCDP-2TPA，DCDP-2TPA4M，TTS，ROpen-DTE-TPECM和RClosed-DTE-TPECM。该化合物可以用作探针，并且可以与特定的靶向基团功能化以成像生物物种。作为非限制性示例，该化合物可以用于细胞质或组织成像、血管成像、体内荧光成像、脑血管成像、前哨淋巴结映射和肿瘤成像，并且该化合物可以用作光声剂。
• Method and catalyst for synthesising aziridine
  申请人：University of East Anglia

  公开号：US10259784B2

  公开（公告）日：2019-04-16

  The present invention relates to methods of synthesizing aziridines including isotopically labelled aziridines, said methods comprising contacting an imine or one or more precursors thereof with a diazo compound in the presence of a phosphoramide or a phosphoramide-derived catalyst. The present invention also relates to aziridines, modified aziridines and aziridine-derived compounds preparable by the aforementioned methods, and to phosphoramide or phosphoramide-derived catalysts suitable for use in such methods.

  本发明涉及合成包括同位素标记的氮丙啶在内的氮丙啶的方法，所述方法包括在磷 酰胺或磷酰胺衍生催化剂存在下，将亚胺或其一种或多种前体与重氮化合物接触。本发明还涉及可通过上述方法制备的氮丙啶、改性氮丙啶和氮丙啶衍生化合物，以及适用于此类方法的磷酰胺或磷酰胺衍生催化剂。
• Highly-fluorescent and photo-stable chromophores for wavelength conversion
  申请人：NITTO DENKO CORPORATION

  公开号：US10461201B2

  公开（公告）日：2019-10-29

  The invention provides highly fluorescent materials comprising a heterocyclic systems represented by formula (I): wherein i is 0 and Het is wherein X is selected from the group consisting of —N(A0)-. The chromophores are particularly useful for absorption and emission of photons in the visible and near infrared wavelength range. The photo-stable highly luminescent chromophores are useful in various applications, including in wavelength conversion films. Wavelength conversion films have the potential to significantly enhance the solar harvesting efficiency of photovoltaic or solar cell devices.

  本发明提供了由式 (I) 所代表的杂环系统组成的高荧光材料： 其中 i 为 0，Het 为 其中 X 选自 -N(A0)-。这些发色团特别适用于吸收和发射可见光和近红外波长范围内的光子。光稳定的高发光发色团可用于各种应用，包括波长转换薄膜。波长转换薄膜有可能显著提高光伏或太阳能电池装置的太阳能收集效率。
• US9732034B2
  申请人：——

  公开号：US9732034B2

  公开（公告）日：2017-08-15