(2-py)-CH=N-C10H6-COOH

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (2-py)-CH=N-C10H6-COOH
• 英文别名: 6-(Pyridin-2-ylmethylideneamino)naphthalene-2-carboxylic acid；6-(pyridin-2-ylmethylideneamino)naphthalene-2-carboxylic acid
• 化学式: C₁₇H₁₂N₂O₂
• 分子量: 276.294
• InChiKey: SUPRBQLNQRPZLP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 (2-py)-CH=N-C10H6-COOH 以 甲醇 为溶剂， 反应 24.0h， 以69%的产率得到[Ag((2-py)-CH=N-C10H6-COOH)2][PF6]
  参考文献：
  名称：

  Ligands containing pyridyl-carboxylate terminals and their discrete silver and polymeric cadmium compounds: (n-py)–CH N–C10H6–COOH (n= 2 (HL1), 3 (HL2)), [Ag(HL1)2](PF6), [Ag(HL1)2](NO3)(H2O), and [Cd(L2)2]

  摘要：

  Two potential linking ligands containing pyridyl-carboxylate terminals [(n-py)-CH = N-C10H6-COOH (n = 2 (HL1), 3 (HL2)) were synthesized by Schiff-base condensation under solvothermal conditions in methanol. Molecules of ligand HL1 are connected by the intermolecular O-H center dot center dot center dot N hydrogen bonds to create a 1D zigzag network. Ligand HL1 reacted with AgPF6 and AgNO3 to produce discrete Ag(l) complexes [Ag(HL1)(2)](PF6) (1) and [Ag(HL1)(2)](NO3)(H2O) (2), respectively. Compounds 1 and 2 form a dimeric structure formed by the intermolecular O-H center dot center dot center dot O hydrogen bonds between two carboxylate terminals of two djacent molecules. A 3D cadmium coordination polymer, [Cd(L-2)(2)](infinity) (3), was prepared from ligand HL2 and Cd(CH3COO)(2)center dot 2H(2)O under solvothermal conditions. Ligand HL1 exhibited a red-shift on complex formation in its photoluminescence emission spectrum. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.019
• 作为产物：
  描述：

  吡啶-2-甲醛 、 6-氨基-2-萘酸 以 甲醇 为溶剂， 反应 12.0h， 以67%的产率得到(2-py)-CH=N-C10H6-COOH
  参考文献：
  名称：

  Ligands containing pyridyl-carboxylate terminals and their discrete silver and polymeric cadmium compounds: (n-py)–CH N–C10H6–COOH (n= 2 (HL1), 3 (HL2)), [Ag(HL1)2](PF6), [Ag(HL1)2](NO3)(H2O), and [Cd(L2)2]

  摘要：

  Two potential linking ligands containing pyridyl-carboxylate terminals [(n-py)-CH = N-C10H6-COOH (n = 2 (HL1), 3 (HL2)) were synthesized by Schiff-base condensation under solvothermal conditions in methanol. Molecules of ligand HL1 are connected by the intermolecular O-H center dot center dot center dot N hydrogen bonds to create a 1D zigzag network. Ligand HL1 reacted with AgPF6 and AgNO3 to produce discrete Ag(l) complexes [Ag(HL1)(2)](PF6) (1) and [Ag(HL1)(2)](NO3)(H2O) (2), respectively. Compounds 1 and 2 form a dimeric structure formed by the intermolecular O-H center dot center dot center dot O hydrogen bonds between two carboxylate terminals of two djacent molecules. A 3D cadmium coordination polymer, [Cd(L-2)(2)](infinity) (3), was prepared from ligand HL2 and Cd(CH3COO)(2)center dot 2H(2)O under solvothermal conditions. Ligand HL1 exhibited a red-shift on complex formation in its photoluminescence emission spectrum. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.019

文献信息

• Ligands containing pyridyl-carboxylate terminals and their discrete silver and polymeric cadmium compounds: (n-py)–CH N–C10H6–COOH (n= 2 (HL1), 3 (HL2)), [Ag(HL1)2](PF6), [Ag(HL1)2](NO3)(H2O), and [Cd(L2)2]
  作者：Young Jae Lee、Soon W. Lee

  DOI：10.1016/j.poly.2013.01.019

  日期：2013.4

  Two potential linking ligands containing pyridyl-carboxylate terminals [(n-py)-CH = N-C10H6-COOH (n = 2 (HL1), 3 (HL2)) were synthesized by Schiff-base condensation under solvothermal conditions in methanol. Molecules of ligand HL1 are connected by the intermolecular O-H center dot center dot center dot N hydrogen bonds to create a 1D zigzag network. Ligand HL1 reacted with AgPF6 and AgNO3 to produce discrete Ag(l) complexes [Ag(HL1)(2)](PF6) (1) and [Ag(HL1)(2)](NO3)(H2O) (2), respectively. Compounds 1 and 2 form a dimeric structure formed by the intermolecular O-H center dot center dot center dot O hydrogen bonds between two carboxylate terminals of two djacent molecules. A 3D cadmium coordination polymer, [Cd(L-2)(2)](infinity) (3), was prepared from ligand HL2 and Cd(CH3COO)(2)center dot 2H(2)O under solvothermal conditions. Ligand HL1 exhibited a red-shift on complex formation in its photoluminescence emission spectrum. (C) 2013 Elsevier Ltd. All rights reserved.