N9,N10-bis(3-methylphenyl)-N9,N10-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]anthracene-9,10-diamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N9,N10-bis(3-methylphenyl)-N9,N10-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]anthracene-9,10-diamine
• 英文别名: 9-N,10-N-bis(3-methylphenyl)-9-N,10-N-bis[3-(9-phenylfluoren-9-yl)phenyl]anthracene-9,10-diamine
• 化学式: C₇₈H₅₆N₂
• 分子量: 1021.32
• InChiKey: CAZXTIBIUNAHJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  21.1
• 重原子数：
  80
• 可旋转键数：
  10
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,10-二溴蒽 、 3-methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 11.8h， 以66%的产率得到N9,N10-bis(3-methylphenyl)-N9,N10-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]anthracene-9,10-diamine
  参考文献：
  名称：

  有机化合物、发光元件、发光装置、电子设备和照明装置

  摘要：

  本发明提供一种发光成分中的基于TTA的延迟荧光成分的比例高的新颖化合物。本发明是一种有机化合物，其具有蒽骨架、亚芳基及包含咔唑骨架的取代或未取代的杂环基，其中，蒽骨架和包含咔唑骨架的取代或未取代的杂环基通过亚芳基键合，并且，蒽骨架的2位或3位具有芳基。

  公开号：

  CN107129459A

文献信息

• FLUORENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Ogita Kaori

  公开号：US20110095678A1

  公开（公告）日：2011-04-28

  An object is to provide a new fluorene derivative as a good light-emitting material for organic EL elements. A fluorene derivative represented by General Formula (G1) is provided. In the formula, R 1 to R 8 separately represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α 1 to α 4 separately represent a substituted or unsubstituted phenylene group. Ar 1 represents a substituted or unsubstituted condensed aromatic hydrocarbon having 14 to 18 carbon atoms forming a ring. Ar 2 represents a substituted or unsubstituted aryl group having 6 to 13 carbon atoms forming a ring. Ar 3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. Further, j, m, and n separately represent 0 or 1, and p represents 1 or 2.

  提供一种新的萘衍生物作为有机EL元件的良好发光材料的目的。提供了一种由通用式（G1）表示的萘衍生物。在该式中，R1至R8分别表示氢原子、具有1至6个碳原子的烷基基团、取代或未取代的苯基团，或取代或未取代的联苯基团。此外，α1至α4分别表示取代或未取代的苯基亚基团。Ar1表示具有14至18个碳原子形成环的取代或未取代的紧凑芳香烃。Ar2表示具有6至13个碳原子形成环的取代或未取代的芳基基团。Ar3表示具有1至6个碳原子的烷基基团或具有6至12个碳原子的取代或未取代的芳基基团。此外，j、m和n分别表示0或1，p表示1或2。
• Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, Display Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20220123231A1

  公开（公告）日：2022-04-21

  A novel light-emitting device that is highly convenient, useful, or reliable is provided. An organic compound in which a substituted or unsubstituted naphtho[2,3-c]carbazolyl group or a substituted or unsubstituted benzo[c]naphtho[2,3-g]carbazolyl group is bonded to a substituted or unsubstituted 9H-carbazolyl group or a substituted or unsubstituted anthryl group through a substituted or unsubstituted arylene group. The arylene group has 6 to 13, inclusive, carbon atoms.

  提供了一种非常方便、有用或可靠的新型发光装置。其中，通过取代或未取代的萘[2,3-c]咔唑基团或取代或未取代的苯并[c]萘[2,3-g]咔唑基团与通过取代或未取代的芘基团或取代或未取代的蒽基团通过取代或未取代的芳基烃基团结合。芳基烃基团含有6到13个碳原子。
• Light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10270051B2

  公开（公告）日：2019-04-23

  A light-emitting element is provided. The light-emitting element includes first and second electrodes and an EL layer therebetween. The EL layer includes a light-emitting layer containing first and second substances. The amount of the first substance is larger than that of the second substance. The second substance emits light. Average transition dipole moments of the second substance are divided into three components in x-, y-, and z-directions which are orthogonal to each other. Components parallel to the first or second electrode are assumed to be the components in the x- and y-directions, and a component perpendicular to the first or second electrode is assumed to be the component in the z-direction. The proportion of the component in the z-direction is represented by a, which is less than or equal to 0.2.

  提供一种发光元件。该发光元件包括第一和第二电极以及其间的 EL 层。EL 层包括含有第一和第二种物质的发光层。第一种物质的含量大于第二种物质的含量。第二种物质发光。第二种物质的平均过渡偶极矩在 x、y 和 z 方向上被分为三个分量，它们相互正交。与第一或第二电极平行的分量被假定为 x 和 y 方向上的分量，与第一或第二电极垂直的分量被假定为 z 方向上的分量。z 方向的分量比例用 a 表示，a 小于或等于 0.2。
• Organic compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10559762B2

  公开（公告）日：2020-02-11

  To provide a novel fluorescent organic compound (a fluorescent compound). The organic compound is a substance that emits fluorescence and an organic compound (a host material) in which TTA can occur efficiently. In the organic compound, triplet excitons, which do not contribute to light emission, can be efficiently converted into singlet excitons. The use of such an organic compound can increase emission efficiency of a light-emitting element.

  提供一种新型荧光有机化合物（荧光化合物）。该有机化合物是一种能发射荧光的物质和一种能有效发生 TTA 的有机化合物（宿主材料）。在有机化合物中，无助于发光的三重激子可以有效地转化为单重激子。使用这种有机化合物可以提高发光元件的发射效率。
• Fluorene Derivative, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP2314565B1

  公开（公告）日：2013-07-24