[2-(acryloyloxy)ethyl]trimethylammonium trifluoromethanesulfonate

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [2-(acryloyloxy)ethyl]trimethylammonium trifluoromethanesulfonate
• 英文别名: Trifluoromethanesulfonate;trimethyl(2-prop-2-enoyloxyethyl)azanium；trifluoromethanesulfonate;trimethyl(2-prop-2-enoyloxyethyl)azanium
• 化学式: CF₃O₃S*C₈H₁₆NO₂
• 分子量: 307.291
• InChiKey: KCSJHONTTHOJTA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.47
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  91.9
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  三氟甲磺酸钠 、 丙烯酰氧乙基三甲基氯化铵 以 乙腈 为溶剂， 反应 48.0h， 以55%的产率得到[2-(acryloyloxy)ethyl]trimethylammonium trifluoromethanesulfonate
  参考文献：
  名称：

  Hyperbranched Polyethylene Ionomers Containing Cationic Tetralkylammonium Ions Synthesized by Pd–Diimine-Catalyzed Direct Ethylene Copolymerization with Ionic Liquid Comonomers

  摘要：

  Synthesis of polyolefin-based ionomers through direct catalytic copolymerization of olefin with ionic comonomers has been challenging with no prior reports. We demonstrate in this article the first direct synthesis of a class of hyperbranched polyethylene ionomers containing positively charged tetralkylammonium ions and different counteranions (tetrafluoroborate, hexafluorophosphate, bis-(trifluoromethane)sulfonimide, or hexafluoroantimonate) by copolymerization of ethylene with tetralkylammonium-containing acrylate-type ionic liquid comonomers (3-5, 7). The use of a Pd-diimine catalyst (1), which shows excellent stability toward the highly polar ionic group, is key to the direct synthesis. A detailed study on the catalytic copolymerization and the effects of the polymerization condition on the macromolecular chain parameters of the resulting ionomers has been performed. A range of ionomers differing in ion content and counteranion has been synthesized and characterized. Meanwhile, systematic studies on the structural, thermal, and melt rheological properties of the ionomers have been undertaken. The dramatic effects of ion incorporation on these properties, particularly on the rheological properties, are demonstrated.

  DOI：

  10.1021/acs.macromol.5b01224

文献信息

• OPTICAL DEVICE WITH ANTISTATIC PROPERTY
  申请人：Klun Thomas P.

  公开号：US20120288675A1

  公开（公告）日：2012-11-15

  An optical device having a first optical member, a second optical member, and an antistatic layer disposed between the first optical member and the second optical member wherein the antistatic layer contains the reaction product of a mixture comprising at least one polymerizable onium salt having an anion and at least one non-onium polymerizable monomer, oligomer, or polymer.

  一种光学装置，包括第一光学元件、第二光学元件和位于第一光学元件和第二光学元件之间的抗静电层，其中抗静电层包含至少一个可聚合的离子型盐及至少一个非离子型可聚合单体、低聚物或聚合物的混合物的反应产物。
• Optical device with antistatic property
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US11111392B2

  公开（公告）日：2021-09-07

  An optical device having a first optical member, a second optical member, and an antistatic layer disposed between the first optical member and the second optical member wherein the antistatic layer contains the reaction product of a mixture comprising at least one polymerizable onium salt having an anion and at least one non-onium polymerizable monomer, oligomer, or polymer.

  一种光学设备，具有一个第一光学部件、一个第二光学部件和一个位于第一光学部件和第二光学部件之间的抗静电层，其中抗静电层含有一种混合物的反应产物，该混合物包括至少一种具有阴离子的可聚合鎓盐和至少一种不可聚合鎓的单体、低聚物或聚合物。
• ANTISTATIC PRESSURE-SENSITIVE ADHESIVE SHEET AND OPTICAL FILM
  申请人：NITTO DENKO CORPORATION

  公开号：US20140295180A1

  公开（公告）日：2014-10-02

  Provided is an antistatic pressure-sensitive adhesive sheet and an optical film, excellent in antistatic properties, adhesive properties, heat resistance, and low staining properties, and capable of preventing adhesion of dirt and dust in particular and destruction of electronic components due to static electricity. Disclosed is an antistatic pressure-sensitive adhesive sheet having an antistatic substrate film; and a pressure-sensitive adhesive layer on at least one side of the antistatic substrate film, wherein the pressure-sensitive adhesive layer is formed of an antistatic pressure-sensitive adhesive composition containing a (meth)acrylic-based polymer containing a reactive ionic liquid as a monomer unit.
• PRESSURE-SENSITIVE ADHESIVE COMPOSITION, PRESSURE-SENSITIVE ADHESIVE SHEET AND OPTICAL FILM
  申请人：NITTO DENKO CORPORATION

  公开号：US20140295183A1

  公开（公告）日：2014-10-02

  Provided are a pressure-sensitive adhesive sheet that has an antistatic property; suppresses a peeling electrification voltage when a non-antistatic treated adherend is peeled off; has a small adhesive strength occurring at high-speed peeling; has an adhesive strength occurring at low-speed peeling so large as not to cause a problem, such as lifting and peeling off; and has an excellent transparency; and a pressure-sensitive adhesive composition capable of obtaining an optical film to which the pressure-sensitive adhesive sheet is bonded. Disclosed is a pressure-sensitive adhesive composition containing a polymer (A) having a glass transition temperature of lower than 0° C. and a polymer (B) containing a reactive ionic liquid as a monomer unit and having an intrinsic viscosity (dL/g) of 0.01 or more and less than 0.5.
• [EN] OPTICAL DEVICE WITH ANTISTATIC PROPERTY<br/>[FR] DISPOSITIF OPTIQUE À PROPRIÉTÉ ANTISTATIQUE
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2011053709A2

  公开（公告）日：2011-05-05

  An optical device having a first optical member, a second optical member, and an antistatic layer disposed between the first optical member and the second optical member wherein the antistatic layer contains the reaction product of a mixture comprising at least one polymerizable onium salt having an anion and at least one non-onium polymerizable monomer, oligomer, or polymer.