2,3,3-trimethyl-3H-pyrrole

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,3,3-trimethyl-3H-pyrrole
• 英文别名: 2,3,3-Trimethyl-3H-pyrrol；2,3,3-Trimethylpyrrole
• 化学式: C₇H₁₁N
• 分子量: 109.171
• InChiKey: CHPNQPFNCPBFDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-methyl-butan-2-one oxime 、 乙炔 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 90.0~100.0 ℃ 、1.22 MPa 条件下， 生成 3-ethyl-2-methylpyrrole 、 2,3,3-trimethyl-3H-pyrrole 、 1-乙烯基-3-乙基-2-甲基吡咯
  参考文献：
  名称：

  Formation of 3-ethylpyrroles in the synthesis of 3H-pyrroles from isopropyl ketoximes in the trofimov reaction

  摘要：

  DOI：

  10.1007/bf00958870

文献信息

• CYANINE COMPOUNDS AND THEIR USE IN STAINING BIOLOGICAL SAMPLES
  申请人：Shao Jianhui

  公开号：US20100112584A1

  公开（公告）日：2010-05-06

  Cyanine compounds having the general formula I for staining biological samples, wherein R 1 , R 2 , X, Y, A 1 and A 2 are as defined in the specification. These kinds of compounds may show good light illumination stability, have a maximum absorption peak around 640 nm that may not change as a function of ambient temperature, have rapidly increased fluorescence intensity upon binding to nucleic acids to form compound/nucleic acid complexes, and have a light spectrum in the near-infrared region, thereby effectively reducing interference from background fluorescence and increasing the accuracy of the detection when used as a staining agent for nucleic acids in a flow cytometer. The compounds provided can be used as a staining agent for erythroblasts in the blood.
• US8383830B2
  申请人：——

  公开号：US8383830B2

  公开（公告）日：2013-02-26
• Formation of 3-ethylpyrroles in the synthesis of 3H-pyrroles from isopropyl ketoximes in the trofimov reaction
  作者：S. E. Korostova、S. G. Shevchenko、M. V. Sigalov、L. N. Sobenina

  DOI：10.1007/bf00958870

  日期：1990.11