diallyl butane-1,4-diyl bis(carbonate)

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: diallyl butane-1,4-diyl bis(carbonate)
• 英文别名: 4-Prop-2-enoxycarbonyloxybutyl prop-2-enyl carbonate
• 化学式: C₁₂H₁₈O₆
• 分子量: 258.271
• InChiKey: IBLXZPORFCKKDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,4-丁二醇 、 二氧化碳 、 3-溴丙烯 在 四甲基胍 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 30.0 ℃ 、1.0 MPa 条件下， 反应 49.0h， 以58%的产率得到diallyl butane-1,4-diyl bis(carbonate)
  参考文献：
  名称：

  Introducing the reversible chemistry of CO₂ with diols mediated by organic superbases into polycarbonate synthesis

  摘要：

  CO2与醇类通过有机超碱介导的可逆反应首次被开发成为一个工具箱，用于将CO2捕获到可聚合的碳酸酯单体中，适用于硫醇-烯烃点击和ADMET聚合，以生产新的聚碳酸酯库。

  DOI：

  10.1039/d0gc01197e

文献信息

• Compositions for producing polymers of high refractive index and low yellowness
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0224123A2

  公开（公告）日：1987-06-03

  The yellowness of polymerizates formed from polymerizable compositions containing bisphenol bis(allylic carbonate)-functional material is reduced by inclusion of one or more cyclohexenic compounds in the polymerizable compositions.

  在含有双酚双（烯丙基碳酸酯）官能团材料的可聚合组合物中加入一种或多种环己烯化合物，可降低由可聚合组合物形成的聚合物的黄度。
• 2-Cyanoacrylate composition
  申请人：Kabushiki Kaisha Alpha Giken

  公开号：EP0229367A1

  公开（公告）日：1987-07-22

  A 2-cyanoacrylate composition which comprises (A) a 2-cyanoacrylate compound and (B) a carbonate compound selected from the group consisting of dialkyl carbonates, alkylene carbonates, alkyne carbonates, alkylene glycol bisalkyl carbonates and trihydric alcohol trisalkyl carbonates.

  一种 2-氰基丙烯酸酯组合物，它包括(A)2-氰基丙烯酸酯化合物和(B)选自二烷基碳酸酯、亚烷基碳酸酯、炔基碳酸酯、亚烷基二醇双烷基碳酸酯和三水醇三烷基碳酸酯所组成的组的碳酸酯化合物。
• Method for producing layers
  申请人：——

  公开号：US20040253383A1

  公开（公告）日：2004-12-16

  The invention relates to a method for coating a surface. According to said method, a coating substance having a viscosity of <100 Pa.s, measured at 25° C., is applied to a surface to be coated and left to harden. The inventive method is characterised in that, during the application of the coating substance, a gas flow is guided over the surface to be coated by means of at least one mobile overpressure ventilation device.

  本发明涉及一种表面涂层方法。根据上述方法，将一种在 25° C 下测量粘度小于 100 Pa.s 的涂层物质涂抹在待涂抹表面上，并使其硬化。本发明方法的特点是，在涂抹涂层物质的过程中，通过至少一个移动式超压通风装置引导气流流过待涂抹表面。
• Hail-resistant acrylic sheet laminate glass and method for producing the same
  申请人：Hasskerl Thomas

  公开号：US20050016213A1

  公开（公告）日：2005-01-27

  The invention relates to polymerisable compositions obtained as follows: a) reaction of A) between 0.5 and 5 parts by weight of at least one silicon compound of formula (I): SimR1nR2oOrXs with B) between 0.01 and 2.0 parts by weight of water C) between 0 and 4.0 parts by weight of at least one acid; and b) subsequent addition of D) between 0.5 and 5 parts by weight of at least one (meth)acrylate of formula (II), E) between 98.99 and 55 parts by weight of at least one polymerisable, ethylenically unsaturated monomer, different from D) and F) between 0 and 30 parts by weight of at least one polymer and/or copolymer, which is obtained by the polymerisation or copolymerisation of at least one ethylenically unsaturated monomer E). The groups R1, R2, R3, R4 and X, in addition to the indices m, n, o, r and s are defined as cited in the description. The invention also relates to polymers and laminate glass obtained from the composition, to a method for producing laminate glass and to the use thereof.

  本发明涉及按以下方法获得的可聚合组合物： a) 至少一种式(I)硅化合物重量份数在 0.5 至 5 份之间的 A)与重量份数在 0.01 至 2.0 份之间的 B)水 C)重量份数在 0 至 4.0 份之间的至少一种酸反应：SimR1nR2oOrXs 与 B) 0.01 至 2.0 份（重量）的水 C) 0 至 4.0 份（重量）的至少一种酸反应；以及 b) 随后加入 D) 0.5 至 5 份（重量）的至少一种式(II)的(甲基)丙烯酸酯，E) 98.99至55份（重量）的至少一种不同于D)的可聚合的乙烯基不饱和单体，以及F)0至30份（重量）的至少一种聚合物和/或共聚物，该聚合物和/或共聚物由至少一种乙烯基不饱和单体E)聚合或共聚得到。基团 R1、R2、R3、R4 和 X 以及指数 m、n、o、r 和 s 的定义如说明中所引述。本发明还涉及由该组合物得到的聚合物和夹层玻璃、生产夹层玻璃的方法及其用途。
• Method and apparatus for fingerprint detection
  申请人：Nichols A. Walter

  公开号：US20050252444A1

  公开（公告）日：2005-11-17

  A portable apparatus for detecting latent fingerprints that discharges a vapor of a cyanoacrylate-containing solution. The apparatus comprises a reservoir for holding a liquid solution comprising cyanoacrylate, a valve for controlling the release of the solution through a capillary flow passage, and a power supply for heating the capillary flow passage and vaporizing the solution. When the cyanoacrylate vapor contacts latent fingerprints, the fingerprints are rendered visible.

  一种用于检测潜藏指纹的便携式仪器，可释放出含氰基丙烯酸酯溶液的蒸汽。该装置包括一个用于容纳含氰基丙烯酸酯的液体溶液的储液器，一个用于控制溶液通过毛细管流道释放的阀门，以及一个用于加热毛细管流道并使溶液汽化的电源。当氰基丙烯酸酯蒸气接触到潜在指纹时，指纹就会显现出来。