N,N-diallyl-1-(4-nitronaphthyl)amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N-diallyl-1-(4-nitronaphthyl)amine
• 英文别名: 4-nitro-N,N-bis(prop-2-enyl)naphthalen-1-amine
• 化学式: C₁₆H₁₆N₂O₂
• 分子量: 268.315
• InChiKey: XQPREBFRNYWMMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  49.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  乙酸烯丙酯 、 1-氨基-4-硝基萘 在 platinum(II) acetylacetonate 4 A molecular sieve 、 三苯基膦 作用下， 以 苯 为溶剂， 反应 24.0h， 以51%的产率得到N-allyl-1-(4-nitronaphthyl)amine
  参考文献：
  名称：

  Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates

  摘要：

  The activation of C-O bonds in allylic acetates has been accelerated by carrying out the reactions in the presence of platinum complexes associated with ligands. Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates leads to N-allylic aminonaphthalenes in good yields. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.01.023

文献信息

• Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates
  作者：Shyh-Chyun Yang、Wei-Hao Feng、Kim-Hong Gan

  DOI：10.1016/j.tet.2006.01.023

  日期：2006.4

  The activation of C-O bonds in allylic acetates has been accelerated by carrying out the reactions in the presence of platinum complexes associated with ligands. Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates leads to N-allylic aminonaphthalenes in good yields. (c) 2006 Elsevier Ltd. All rights reserved.