linolenylamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: linolenylamine
• 英文别名: 9,12,15-octadecatrien-1-amine；(9E,12E,15E)-octadeca-9,12,15-trien-1-amine
• 化学式: C₁₈H₃₃N
• 分子量: 263.467
• InChiKey: PKZOCMZJRHDECH-IUQGRGSQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  19
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9,12,15-十八碳三烯酰氯 在 lithium aluminium tetrahydride 、 氨 作用下， 以 乙醚 、 苯 为溶剂， 反应 7.0h， 生成 linolenylamine
  参考文献：
  名称：

  Nematicidal activity of N-substituted and N,N-disubstituted alkylamines against the pine wood nematode, Bursaphelenchus xylophilus.

  摘要：

  在随机筛选对松木线虫（Bursaphelenchus xylophilus）具有灭虫作用的化合物时，通过浸泡测试检测了一系列N-烷基和N,N-二烷基油酸胺、二烷基胺及其相关化合物。经过测试，二十二烷胺被确定为最具潜力的灭虫化合物（LC50；4.19μM，1.24ppm）。在总共23种烷基胺中，包括油酸胺在内的六种N-和N,N-二烷基油酸胺，以及三种二烷基胺在浓度基础上表现出比十八烷胺（LC50；8.61μM，2.08ppm）更高的活性。总共有9种测试化合物在摩尔基础上显示出比十八烷胺更高的活性。

  DOI：

  10.1271/bbb1961.47.53

文献信息

• PROCESS FOR PREPARING DOUBLE METAL CYANIDE CATALYSTS AND THEIR USE IN POLYMERIZATION REACTIONS
  申请人：Universitat Hamburg

  公开号：US20180179334A1

  公开（公告）日：2018-06-28

  The present invention is directed to a process for preparing a double metal cyanide catalyst of Formula I (M a [M′(CN) c Z w ] b .zA), wherein M is a main group or transition metal cation, M′ is a main group or transition metal cation, which can be the same or different from M, Z is an anion or ligand other than cyanide, A is an amphiphilic agent selected from heteroatom-containing organic compounds having at least one polar head group and an aliphatic, aromatic or partially aromatic moiety having a number of 6 to 42 carbon atoms, w is an integer greater than or equal to 0, but lower than c; a, b and c are integers greater than or equal to 1 so that catalyst (I) is electrically neutral, and z is a number from 0 to 12, which process comprises (a) reacting a metal salt of Formula II (M e X f ), wherein X is an anion and e and f are integers greater than or equal to 1 so that metal salt (II) is electrically neutral, with a cyanometallate complex of Formula III (D g [M′(CN) c ] b ), wherein D is a cation and g is an integer greater than or equal to 1 so that complex (III) is electrically neutral, and M′, Z, c, w and b are defined as described above, in the presence of the amphiphilic agent A and optionally a solvent L to obtain a double metal cyanide adduct of Formula IV (M a [M′(CN) c ] b .xA.yL), wherein x is a number greater than or equal to 1 and y is a number greater than or equal to 0; and (b) thermally treating the adduct (IV) to obtain the double metal cyanide catalyst of Formula (I).

  本发明涉及一种制备公式I的双金属氰化物催化剂的过程（Ma[M′(CN)cZw]b.zA），其中M是主族或过渡金属阳离子，M′是主族或过渡金属阳离子，可以与M相同或不同，Z是除氰离子外的阴离子或配体，A是选择自具有至少一个极性头基和具有6到42个碳原子的脂肪，芳香或部分芳香基团的杂原子含有机化合物的两性分子，w是大于或等于0但小于c的整数; a，b和c是大于或等于1的整数，使得催化剂（I）是电中性的，z是0到12的数字，该过程包括（a）在两性分子剂A和可选的溶剂L的存在下，将公式II的金属盐（MeXf），其中X是阴离子，e和f是大于或等于1的整数，以使金属盐（II）是电中性的，与公式III的氰金属酸盐配合物（Dg[M′(CN)c]b）反应，其中D是阳离子，g是大于或等于1的整数，以使复合物（III）是电中性的，并且M'，Z，c，w和b如上所述定义，以获得公式IV的双金属氰化物加合物（Ma[M′(CN)c]b.xA.yL），其中x大于或等于1，y大于或等于0;以及（b）热处理加合物（IV）以获得公式（I）的双金属氰化物催化剂。
• Composite clay material and method for producing the same, blend material and composite clay rubber using the same and production method thereof
  申请人：KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO

  公开号：EP0747322A1

  公开（公告）日：1996-12-11

  A composite clay material with the interlayer distance sufficiently expanded by dispersing clay mineral in a low polar polymer on a molecular level and the method for producing the same, blend material and composite clay rubber material using the same and the production method thereof. The composite clay material is formed of a clay mineral rendered compatible with an organic material through ionic bonding to an organic onium ion having 6 or more carbon number and a main guest molecule having a polar group in its main chain and side chain and molecular length equal to or larger than that of said organic onium ion. The main guest molecule is incorporated at least partially into an interlayer section of the clay mineral which has a hydrogen bonding with the polar group of the main guest molecule. The main guest molecule preferably has a molecular weight ranging from about 100 to 100000. Alternatively a first guest molecule having a polar group and molecular length equal to or smaller than that of the organic onium ion and a second guest molecule having no polar group therein and molecular length larger than that of the organic onium ion are incorporated into the interlayer section of the clay mineral instead of the main guest molecule. The above obtained clay composite material may be mixed with the rubber material.

  一种通过在分子水平上将粘土矿物分散在低极性聚合物中来充分扩大层间距离的复合粘土材料及其生产方法、使用该材料的共混材料和复合粘土橡胶材料及其生产方法。 复合粘土材料是由粘土矿物通过与具有 6 个或更多碳原子数的有机鎓离子和主客分子的离子键结合而与有机材料相容，主客分子的主链和侧链中具有极性基团，分子长度等于或大于所述有机鎓离子的分子长度。主客体分子至少部分地与粘土矿物的层间部分结合，该层间部分与主客体分子的极性基团有氢键结合。主客体分子的分子量最好在 100 到 100000 之间。或者，将具有极性基团且分子长度等于或小于有机鎓离子分子长度的第一客体分子和不含极性基团且分子长度大于有机鎓离子分子长度的第二客体分子代替主客体分子加入粘土矿物的层间部分。上述粘土复合材料可与橡胶材料混合。
• Composite clay rubber material, composite clay material and processes for producing same
  申请人：KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO

  公开号：EP1029823A2

  公开（公告）日：2000-08-23

  A composite clay material with the interlayer distance sufficiently expanded by dispersing clay mineral in a low polar polymer on a molecular level and the method for producing the same, blend material and composite clay rubber material using the same and the production method thereof. The composite clay material is formed of a clay mineral rendered compatible with an organic material through ionic bonding to an organic onium ion having 6 or more carbon number and a main guest molecule having a polar group in its main chain and side chain and molecular length equal to or larger than that of said organic onium ion. The main guest molecule is incorporated at least partially into an interlayer section of the clay mineral which has a hydrogen bonding with the polar group of the main guest molecule. The main guest molecule preferably has a molecular weight ranging from about 100 to 100000. Alternatively a first guest molecule having a polar group and molecular length equal to or smaller than that of the organic onium ion and a second guest molecule having no polar group therein and molecular length larger than that of the organic onium ion are incorporated into the interlayer section of the clay mineral instead of the main guest molecule. The above obtained clay composite material may be mixed with the rubber material.

  一种通过在分子水平上将粘土矿物分散在低极性聚合物中来充分扩大层间距离的复合粘土材料及其生产方法、使用该材料的共混材料和复合粘土橡胶材料及其生产方法。 复合粘土材料是由粘土矿物通过与具有 6 个或更多碳原子数的有机鎓离子和主客分子的离子键结合而与有机材料相容，主客分子的主链和侧链中具有极性基团，分子长度等于或大于所述有机鎓离子的分子长度。主客体分子至少部分地与粘土矿物的层间部分结合，该层间部分与主客体分子的极性基团有氢键结合。主客体分子的分子量最好在 100 到 100000 之间。或者，将具有极性基团且分子长度等于或小于有机鎓离子分子长度的第一客体分子和不含极性基团且分子长度大于有机鎓离子分子长度的第二客体分子代替主客体分子加入粘土矿物的层间部分。上述粘土复合材料可与橡胶材料混合。
• RUBBER COMPOSITION FOR INNER LINER AND TIRE
  申请人：Bridgestone Corporation

  公开号：EP1500678A1

  公开（公告）日：2005-01-26

  A rubber composition for inner liners which comprises at least one rubber selected from diene-based synthetic rubbers and natural rubber having a glass transition temperature of -55°C or lower and an organized lamellar clay mineral, an inner liner comprising the rubber composition and a tire in which the rubber composition is used as the inner liner are provided. The rubber composition for inner liners exhibits improved durability at low temperatures in combination with excellent resistance to permeation of the air, and the tire has the inner liner exhibiting this advantageous property.

  提供了一种用于内衬的橡胶组合物，该组合物包含至少一种选自玻璃化转变温度为 -55°C 或更低的二烯基合成橡胶和天然橡胶的橡胶以及一种有组织片状粘土矿物；还提供了一种包含该橡胶组合物的内衬以及一种使用该橡胶组合物作为内衬的轮胎。用于内衬的橡胶组合物在低温下具有更好的耐久性和优异的抗空气渗透性，轮胎的内衬也具有这一有利特性。
• MODIFIED CELLULOSE NANOFIBERS AND RUBBER COMPOSITION CONTAINING SAME
  申请人：Nippon Paper Industries Co., Ltd.

  公开号：EP3483186A1

  公开（公告）日：2019-05-15

  The present invention aims to provide a rubber composition having sufficient reinforcement and fatigue resistance even when a large strain is applied thereto, and the present invention is to provide a substituted carboxy group-containing modified cellulose nanofiber wherein at least part thereof has at least any one of a substituent represented by Formula (a): -CONH-R1 and a substituent represented by Formula (b): -COO-R1 (in Formulae (a) and (b), R1 is independently a C3-30 hydrocarbon having at least one unsaturated bond), and a rubber composition including the same.

  本发明旨在提供一种橡胶组合物，该组合物即使在施加较大应变时也具有足够的补强性和抗疲劳性，本发明提供一种含取代羧基的改性纤维素纳米纤维，其中至少一部分具有式(a)所代表的取代基中的至少任一种：-CONH-R1和式(b)代表的取代基：-COO-R1（在式(a)和(b)中，R1独立地是具有至少一个不饱和键的C3-30烃），以及包括其在内的橡胶组合物。