铂(2+)1,2-环己烷二基二亚胺-硝酸(1:1:2) | 66900-68-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 铂(2+)1,2-环己烷二基二亚胺-硝酸(1:1:2)
• 英文名称: cis-dinitrato(1,2-diaminocyclohexane)platinum(II)
• 英文别名: 1,2-Cyclohexanediamine dinitratoplatinum；cyclohexane-1,2-diamine;platinum(2+);dinitrate
• CAS: 66900-68-3；66900-69-4；66900-67-2；60732-70-9；125515-54-0
• 化学式: C₆H₁₄N₄O₆Pt
• 分子量: 433.28
• InChiKey: UQKCTBFPACVZSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.27
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  178
• 氢给体数：
  2
• 氢受体数：
  8

安全信息

• WGK Germany：
  3

反应信息

• 作为反应物：
  描述：

  铂(2+)1,2-环己烷二基二亚胺-硝酸(1:1:2) 生成 cyclohexane-1,2-diamine;platinum(2+);dihydroxide
  参考文献：
  名称：

  FUDZIKAVA, KADZUXIRO;IMAMURA, SINDZO;MUTO, MASADZU;SAVAXATA, MASASI

  摘要：

  DOI：
• 作为产物：
  描述：

  (1,2-二氨基环己烷)二氯化铂 生成 铂(2+)1,2-环己烷二基二亚胺-硝酸(1:1:2)
  参考文献：
  名称：

  WYRICK, STEVEN D.;CHANEY, STEPHEN G., J. LABELL. COMPOUNDS AND RADIOPHARM., 25,(1988) N 4, 349-357

  摘要：

  DOI：

文献信息

• Coordination-Driven Self-Assembly of Discrete Molecular Nanotubular Architectures
  作者：Imtiyaz Ahmad Bhat、Ennio Zangrando、Partha Sarathi Mukherjee

  DOI：10.1021/acs.inorgchem.9b01763

  日期：2019.8.19

  Two new M8L4 tetrafacial nanotubes (T1 and T3) of different lengths have been synthesized in water using ligands L1 and L2, respectively, with acceptor cis-[(dch)Pt(NO3)(2)] (M) using coordination-driven self-assembly [where dch is 1,2-diaminocyclohexane, L1 is 1,4-di(pyrimidin-5-yl)benzene, and L2 is 4,4'- di(pyrimidin-5-yl)-1,1'-biphenyl]. In addition to complex T1, a tetrahedral cage of composition [M-12(L1)(6)] (T2) was also formed in the self-assembly reaction of ligand L1 with cis-[(dch)Pt(NO3)(2)]. The precise composition of the products (T1 and T2) in solution was confirmed by H-1 NMR and ESI-MS. Pure tube T1 was separated out by a crystallization technique and fully characterized by 1H NMR and X-ray diffraction. Temperature- and concentration-dependent NMR studies indicated no equilibrium between T1 and T2 in the solution phase, and the proportion of T1 and T2 in the mixture depends on the temperature of the reaction. In contrast to ligand L1, the self-assembly of the longer ligand, L2, with cis-[(dch)Pt(NO3)(2)] gave only tetrafacial tube [M-8(L-2)(4)] (T3) without any tetrahedral cage.
• The thermal degradation characteristics of selected organoplatinum antitumor agents
  作者：B. A. Howell、L. G. Beholz、B. B. S. Sastry

  DOI：10.1007/bf02546607

  日期：1993.8

  The thermal decomposition characteristics of representatives of three classes of organoplatinum compounds have been examined by thermogravimetry. Substituted salicylato(1,2-diaminocyclohexane)platinum(II) compounds undergo thermal decomposition by sequential loss of first the salicylato ligand and then the amine ligand to afford a residue corresponding to the platinum content of the compound. The thermal decomposition of N-arylsalicylaldimino(1,2-diaminocyclohexane)platinum(II) nitrate is more complex, but is also characterized by two major weight losses. Thermal decomposition of bis-(2-thiophenecarboxylato)platinum(II) is characterized by ligand fragmentation to generate a residual mass corresponding to the platinum content of the compound.
• Substitutedcatecholato(1,2-diaminocyclohexane)-platinum(II) compounds
  作者：B.A. Howell、R. Rashidianfar、J.R. Glass、B.J. Hutchinson、D.A. Johnson

  DOI：10.1016/s0020-1693(00)81554-6

  日期：1988.2
• MUTO, MASANORI;FUDZIKAVA, KADZUXARO;IMAMURA, SINDZO;XASIMOTO, XIDEHYUKI
  作者：MUTO, MASANORI、FUDZIKAVA, KADZUXARO、IMAMURA, SINDZO、XASIMOTO, XIDEHYUKI

  DOI：——

  日期：——
• MUTO, MASANORI;FUDZIKAVA, KADZUXIRO;IMAMURA, SINDZO;XASIMOTO, XIDEHYUKI
  作者：MUTO, MASANORI、FUDZIKAVA, KADZUXIRO、IMAMURA, SINDZO、XASIMOTO, XIDEHYUKI

  DOI：——

  日期：——