铂(2+)氯化N,N'-二(3-氨基丙基)丁烷-1,4-二胺(2:4:1) | 187224-61-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 铂(2+)氯化N,N'-二(3-氨基丙基)丁烷-1,4-二胺(2:4:1)
• 英文名称: μ-4,9-diazadodecane-1,12-diamine κ(2)N(1),N(4):κ(2)N(9),N(12)-bis[dichloroplatinum(II)]
• 英文别名: μ-spermine κ(2)N(1),N(4):κ(2)N(9),N(12)-bis[dichloroplatinum(II)]；N,N'-bis(3-aminopropyl)butane-1,4-diamine;platinum(2+);tetrachloride
• CAS: 187224-61-9
• 化学式: C₁₀H₂₆Cl₄N₄Pt₂
• 分子量: 734.315
• InChiKey: RIPHPLOAGHYGAU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -12.35
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.1
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 Spermine phosphate 在 NaCl 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 铂(2+)氯化N,N'-二(3-氨基丙基)丁烷-1,4-二胺(2:4:1)
  参考文献：
  名称：

  Dichloro(propane-1,3-diamine-κ²N,N′)platinum(II), dichloro(propane-1,3-diamine-κ²N,N′)palladium(II) and μ-4,9-diazadodecane-1,12-diamine-κ²N¹,N⁴:κ²N⁹,N¹²-bis[dichloroplatinum(II)]

  摘要：

  In the title compounds, [PtCl2(C3H10N2)], (I), [PdCl2(C3H10N2)], (II), and [Pt2Cl4(C10H26N4)], (III), each metal atom lies in a distorted cis-square coordination geometry. Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear Complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N-H center dot center dot center dot Cl hydrogen bonds.

  DOI：

  10.1107/s010827010600610x

文献信息

• Dichloro(propane-1,3-diamine-κ²<i>N</i>,<i>N</i>′)platinum(II), dichloro(propane-1,3-diamine-κ²<i>N</i>,<i>N</i>′)palladium(II) and μ-4,9-diazadodecane-1,12-diamine-κ²<i>N</i>¹,<i>N</i>⁴:κ²<i>N</i>⁹,<i>N</i>¹²-bis[dichloroplatinum(II)]
  作者：Mamiko Odoko、Nobuo Okabe

  DOI：10.1107/s010827010600610x

  日期：2006.3.18

  In the title compounds, [PtCl2(C3H10N2)], (I), [PdCl2(C3H10N2)], (II), and [Pt2Cl4(C10H26N4)], (III), each metal atom lies in a distorted cis-square coordination geometry. Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear Complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N-H center dot center dot center dot Cl hydrogen bonds.