TWO-PACK TYPE EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, AND FIBER-REINFORCED COMPOSITE MATERIAL
申请人:Toray Industries, Inc.
公开号:EP3275924A1
公开(公告)日:2018-01-31
A task of the invention is to provide a two-component type epoxy resin composition that is excellent in the viscosity stability at low temperature (e.g., 40°C) of an epoxy resin composition after the mixing preparation, and that retains low viscosity at the time of injection into reinforcing fiber and is excellent in impregnating property, and that controls resin flow due to the resin viscosity appropriately increasing after impregnation so that, for example, burrs on a molded product can be reduced, and that cures in a short time during molding, and that gives a fiber reinforced composite material high in the transparency of a cured product and excellent in molded product quality, and a fiber reinforced composite material made by using the two-component epoxy resin composition. The two-component type epoxy resin composition for a fiber reinforced composite material of the invention is a two-component type epoxy resin composition for a fiber reinforced composite material that includes the following components [A] to [C], wherein the content of the component [C] is 6 to 25 mass parts relative to 100 mass parts of the component [A]. The fiber reinforced composite material of the invention is a fiber reinforced composite material made by combining and curing the two-component type epoxy resin composition for the fiber reinforced composite material and a reinforcing fiber.
[A]: an epoxy resin
[B]: an acid anhydride
[C]: a quaternary ammonium salt or a quaternary phosphonium halide or an imidazolium salt
本发明的任务是提供一种双组分型环氧树脂组合物,该组合物在混合制备后的环氧树脂组合物在低温(例如40°C)下的粘度稳定性优异的双组分型环氧树脂组合物,该组合物在注入增强纤维时能保持低粘度,浸渍性能优异,并能控制因浸渍后树脂粘度适当增加而导致的树脂流动,从而减少模塑产品上的毛刺等、使用双组分环氧树脂组合物制造的纤维增强复合材料。本发明的纤维增强复合材料用双组分型环氧树脂组合物是一种纤维增强复合材料用双组分型环氧树脂组合物,它包括以下组分[A]至[C],其中相对于 100 质量份的组分[A],组分[C]的含量为 6 至 25 质量份。本发明的纤维增强复合材料是一种纤维增强复合材料,由纤维增强复合材料用双组分型环氧树脂组合物和增强纤维混合固化而成。
[A]:环氧树脂
[B]:一种酸酐
[C]:季铵盐、季鏻卤化物或咪唑盐