己基二甲基磷酸酯 | 82753-88-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 己基二甲基磷酸酯
• 英文名称: dimethyl hexyl phosphate
• 英文别名: phosphoric acid hexyl ester-dimethyl ester；Phosphorsaeure-hexylester-dimethylester；Hexyl dimethyl phosphate
• CAS: 82753-88-6
• 化学式: C₈H₁₉O₄P
• 分子量: 210.21
• InChiKey: VDRBDINALVEVEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  己基二甲基磷酸酯 在 甲烷磺酸 、 二甲基硫 作用下， 以 乙醚 为溶剂， 反应 22.0h， 生成 Phosphoric acid monohexyl ester; compound with phenylamine
  参考文献：
  名称：

  Selective Demethylation of Mixed Alkyl Methyl Phosphates

  摘要：

  DOI：

  10.1055/s-1983-30373
• 作为产物：
  描述：

  正己醇 在 乙醚 、 N,N-二甲基苯胺 、 三氯氧磷 作用下， 生成 己基二甲基磷酸酯
  参考文献：
  名称：

  Pyrolysis of Alkyl Phosphates

  摘要：

  DOI：

  10.1021/ja01567a066

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Visible-Light-Mediated Access to Phosphate Esters
  作者：Alya Inial、Fabrice Morlet-Savary、Jacques Lalevée、Annie−Claude Gaumont、Sami Lakhdar

  DOI：10.1021/acs.orglett.0c01409

  日期：2020.6.5

  We report herein a practically simple visible-light photocatalytic approach for the synthesis of a large variety of phosphate esters through the combination of N-alkoxypyridinium salts and phosphites under mild conditions. The scope of the reaction is broad and the protocol was successfully applied to the synthesis of biologically relevant structures. Quantum yield measurements, as well as EPR experiments

  我们在此报告了在温和条件下通过N-烷氧基吡啶鎓盐和亚磷酸酯的组合合成多种磷酸酯的一种实用的可见光光催化方法。反应的范围很广，该方案已成功地应用于生物学相关结构的合成。量子产率的测量以及EPR实验，提示了合理的反应机理。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• Composite membrane and method for making the same
  申请人：——

  公开号：US20010050252A1

  公开（公告）日：2001-12-13

  A composite membrane and method for making the same, comprising a porous support and a polyamide surface. The subject membrane provides improved flux and/or rejection rates. The subject membrane is further capable of operating at lower operating pressures. The subject method includes reacting a polyfunctional amine with a polyfunctional acyl halide to form a polyamide. The method includes the step of contacting a complexing agent with the polyfunctional acyl halide prior substantial reaction between the polyfunctional acyl halide and a polyfunctional amine. The subject process is easily adapted to commercial scale manufacturing processes and is particularly suited for making nanofiltration and reverse osmosis composite membranes.

  一种复合膜及其制造方法，包括多孔支架和聚酰胺表面。该膜提高了通量和/或排斥率。该膜还能在较低的工作压力下工作。该方法包括将多官能团胺与多官能团酰基卤反应生成聚酰胺。该方法包括在多官能酰基卤与多官能胺发生实质性反应之前，将络合剂与多官能酰基卤接触。该主题工艺很容易适用于商业规模的制造工艺，尤其适用于制造纳滤和反渗透复合膜。
• Takaku, Hiroshi; Kamaike, Kazuo; Mori, Hisashi, Chemical and pharmaceutical bulletin, 1983, vol. 31, # 6, p. 2157 - 2159
  作者：Takaku, Hiroshi、Kamaike, Kazuo、Mori, Hisashi、Ishido, Yoshiharu

  DOI：——

  日期：——