1,2-二苯基环戊烷 | 93436-35-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 1,2-二苯基环戊烷
• 英文名称: 1,2-diphenyl-cyclopentane
• 英文别名: 1,2-Diphenyl-cyclopentan；cis 1,2-diphenyl cyclopentane；1,1'-Cyclopentane-1,2-diyldibenzene；(2-phenylcyclopentyl)benzene
• CAS: 93436-35-2
• 化学式: C₁₇H₁₈
• 分子量: 222.33
• InChiKey: IFSVFGWMGAXREN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-二苯基环戊烷 在 chromium(VI) oxide 、 溶剂黄146 作用下， 生成 1,5-二苯基-1,5-戊二酮
  参考文献：
  名称：

  Japp; Michie, Journal of the Chemical Society, 1901, vol. 79, p. 1015

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氢碘酸 作用下， 生成 1,2-二苯基环戊烷
  参考文献：
  名称：

  Kishner, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910, vol. 42, p. 1213

  摘要：

  DOI：

文献信息

• Kishner, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1915, vol. 47, p. 1839
  作者：Kishner

  DOI：——

  日期：——
• THE DREAM'S NAVEL BETWEEN CHAOS AND THOUGHT
  作者：Franco Scalzone、Gemma Zontini

  DOI：10.1516/0020757011600812

  日期：2001.4.1

  The authors begin by drawing attention to the problem of the transition from the biological to the psychic, noting that Freud himself, with his background in the neurosciences, grappled with it throughout his career. Certain recent paradigms more commonly applied to the natural sciences, such as in particular chaos and complexity theory, can in their view prove fruitful in psychoanalysis too, and it is shown how these notions are inherent in some of Freud's conceptions. The unconscious is stated to operate like a neural network, performing the kind of parallel processing used in the computing of highly complex situations, whereas the conscious mind is sequential. Dreams, in the authors' opinion, are organisers of the mind, imparting order to the turbulence of the underlying wishes and unconscious fantasies and structuring them through the dream work. Through dreams, the structured linearity of conscious thought can emerge out of the non-linear chaos of the drives. The dream's navel can be seen as the chaotic link, or interface, between the unconscious wish, which constitutes an attractor, and the conscious thought. The attractor may be visualised as having an hourglass or clepsydra shape, the narrow section being the dream's navel, and, being the same at any scale of observation, has the property of fractality.
• Nickel-Catalyzed Reductive Cyclization of Alkyl Dihalides
  作者：Weichao Xue、Hailiang Xu、Zhuye Liang、Qun Qian、Hegui Gong

  DOI：10.1021/ol502207z

  日期：2014.10.3

  The reductive coupling protocol to intra-molecular cyclization of dihaloalkanes is presented. It leads to five- and six-membered rings, with the former being more efficient. The incorporation of secondary alkyl halides generally promotes coupling, efficiency. To the best of our know ledge this is the first catalytic ring closure reaction arising form dihaloalkanes under chemical reductive conditions.
• Japp; Lander, Journal of the Chemical Society, 1897, vol. 71, p. 132
  作者：Japp、Lander

  DOI：——

  日期：——
• Japp; Burton, Journal of the Chemical Society, 1887, vol. 51, p. 430
  作者：Japp、Burton

  DOI：——

  日期：——