1,3,5-三氯戊烷 | 74216-76-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1,3,5-三氯戊烷
• 英文名称: 1,3,5-trichloropentane
• CAS: 74216-76-5
• 化学式: C₅H₉Cl₃
• 分子量: 175.485
• InChiKey: CRHPYMKSJMSTMT-UHFFFAOYSA-N

物化性质

• 沸点：
  207.7±8.0 °C(Predicted)
• 密度：
  1.205±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,3,3,5-tetrachloropentane 在 Re(CO)10 三乙基硅烷 作用下， 反应 5.0h， 以78%的产率得到1,3,5-三氯戊烷
  参考文献：
  名称：

  Kinetics and mechanism of the reduction of polychloroalkanes by triethylsilane, catalyzed by binuclear manganese and rhenium carbonyls

  摘要：

  DOI：

  10.1007/bf00961992

文献信息

• Method of surface-treating water-absorbent resin
  申请人：Nippon Shokubai Kagaku Kogyo Co., Ltd

  公开号：EP0317106A2

  公开（公告）日：1989-05-24

  A method of treating the surface of a water-absorbent resin is disclosed which comprises adding a hydrophilic crosslinking agent capable of reacting with at least two functional groups of the water-absorbent resin in a hydrophobic organic solvent to crosslink resin at or near its surface. The hydrophilic crosslinking agent is added in the form of a dispersion which is obtained by dispersing it in a hydrophobic organic solvent in the presence of a surface-active agent.

  本发明公开了一种处理吸水性树脂表面的方法，包括在疏水性有机溶剂中加入一种能与吸水性树脂的至少两个官能团发生反应的亲水交联剂，使树脂在其表面或表面附近发生交联。亲水交联剂以分散体的形式加入，分散体是在表面活性剂存在的情况下将其分散在疏水性有机溶剂中得到的。
• Coated superabsorbent polymer particles and processes therefore
  申请人：The Procter and Gamble Company

  公开号：EP2277557A1

  公开（公告）日：2011-01-26

  Superabsorbent material, comprising first superabsorbent polymers, coated with second clay-crosslinked superabsorbent polymers, said second clay-crosslinked superabsorbent polymers being obtainable by the step of polymerization of a solution/ dispersion of polymerizable compounds and clay particles, to obtain said second superabsorbent polymers, crosslinked by said clay particles, of a weight average largest particle dimension of less than 800 nm; process for making such material; absorbent articles comprising such material.

  超吸收材料，包括第一种超吸收聚合物，涂有第二种粘土交联超吸收聚合物，所述第二种粘土交联超吸收聚合物可通过对可聚合化合物和粘土颗粒的溶液/分散液进行聚合的步骤获得，以获得由所述粘土颗粒交联的重量平均最大颗粒尺寸小于 800 nm 的所述第二种超吸收聚合物；制造这种材料的工艺；包括这种材料的吸收制品。
• Nucleic acid adsorbent; methods for adsorbing, removing, dissociating, and recovering nucleic acids using the same; and method for regenerating the same
  申请人：Hirayama Chuichi

  公开号：US20060073499A1

  公开（公告）日：2006-04-06

  A nucleic acid adsorbent in which a polymer having a constitutional unit represented by the following formula (I) is immobilized on a water-insoluble carrier is used as a nucleic acid adsorbent capable of selectively and efficiently adsorbing nucleic acids from complex mixtures, such as cell extract, wherein R 1 represents hydrogen, fluoride, or methyl; R 2 and R 3 each independently represent alkyl of 1 to 6 carbon atoms; A is —NH— or —O—; and B represents alkylene of 2 to 18 carbon atoms. Nucleic acids are recovered from cell extract by allowing them to be adsorbed to the nucleic acid adsorbent by mixing this nucleic acid adsorbent with cell extract, removing the nucleic acids from the cell extract by separating the adsorbent therefrom, and dissociating the nucleic acids from the nucleic acid adsorbent by treating the separated nucleic acid adsorbent with alkali.

  一种核酸吸附剂将具有下式 (I) 所代表的构型单元的聚合物固定在不溶于水的载体上，用作核酸吸附剂，能够选择性地、高效地吸附复杂混合物（如细胞提取物）中的核酸、 其中 R 1 代表氢、氟或甲基；R 2 和 R 3 各自独立地代表 1 至 6 个碳原子的烷基；A 是-NH- 或-O-；B 代表 2 至 18 个碳原子的亚烷基。从细胞提取物中回收核酸的方法是：将核酸吸附剂与细胞提取物混合，使核酸吸附在核酸吸附剂上；将吸附剂与细胞提取物分离，从细胞提取物中去除核酸；用碱处理分离后的核酸吸附剂，使核酸从核酸吸附剂中解离。
• Determination of the rate constant of hydrogen abstraction from triethylsilane by Re(CO)5 Radicals and use of the Re2(CO)10-Et3SiH system for the reduction of polychloroalkanes
  作者：R. G. Gasanov、L. V. Ivanova、N. A. Kuz'mina、E. Ts. Chukovskaya

  DOI：10.1007/bf00953933

  日期：1985.9
• Chlorine and hydrogen transfer by metal carbonyl intermediates
  作者：L. V. Il'inskaya、V. F. Kuznetsov、R. G. Gasanov

  DOI：10.1007/bf00958581

  日期：1991.4

  The reduction of 1,1,1,5-tetrachloropentane by toluene in the presence of the Fe(CO)5 or M(CO)6 (M = Cr, Mo, W) in conjunction with triphenylphosphine was investigated. It was shown that the chlorine-containing metal carbonyl intermediates formed in the process take part in the transfer of the chlorine atom to the benzyl radicals. It was shown that HMn(CO)5 is not the main intermediate responsible for the transfer of hydrogen by the chloroalkyl radicals, which are formed during the reduction of 1,3,3,5-tetrachloropentane by triethylsilane in the presence of Mn2(CO)10.