A modified polymer containing a cyclic molecular structure unit represented by general formula (I) and having a number-average molecular weight of 10,000 to 5,000,000, wherein A to F represent monomer units constituting the main chain of the polymer and they may be arranged in an arbitrary order; l to q represent each of the content (wt.-%) of the respective monomer unit A to F based on the total weight of the units A to F; A represents a cycloolefin monomer unit; B represents a conjugated cyclodiene monomer unit; C and D represent each a monomer unit copolymerizable with A and B; S to X represent modifying groups and each independently comprises a functional group bearing at least one of oxygen, nitrogen, sulfur, silicon, phosphorus and halogen, or an organic acid residue containing the above functional group; and s to x represent each the content (wt.-%) of the respective group S to X. The polymer has excellent thermal characteristics and various types of modified polymer can be provided by copolymerizing various monomers in arbitrary proportions and forms in accordance with required thermal and mechanical characteristics.
一种改性聚合物,含有通式(I)代表的环状分子结构单元,其数均分子量为 10,000 至 5,000,000 ,其中 A 至 F 代表构成聚合物主链的单体单元,它们可以任意顺序排列;l 至 q 代表 A 至 F 各单体单元在 A 至 F 单元总重量中的含量(重量百分比);A 代表环烯烃单体单元;B 代表共轭环二 烯单体单元;C 代表共轭环烯单体单元;D 代表共轭环烯单体单元。A代表环烯烃单体单元;B代表共轭环二 烯单体单元;C和D分别代表可与A和B共聚的单体单元; S至X代表改性基团,各自独立地包括含有氧、氮、
硫、
硅、
磷和卤素中至少一种的官能团,或含有上述官能团的有机酸残基;S至X分别代表S至F各基团的含量(重量-%)。该聚合物具有极佳的热特性,可根据所需的热特性和机械特性,以任意比例和形式共聚各种单体,制成各种类型的改性聚合物。