1,4,5-萘三羧酸 | 28445-09-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 1,4,5-萘三羧酸
• 英文名称: Naphthalin-1,4,5-tricarbonsaeure
• 英文别名: Naphthalene-1,4,5-tricarboxylic acid
• CAS: 28445-09-2
• 化学式: C₁₃H₈O₆
• 分子量: 260.203
• InChiKey: DDHQTWZKAJOZQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

安全信息

• 海关编码：
  2917399090

反应信息

• 作为反应物：
  描述：

  1,4,5-萘三羧酸 在 ammonium hydroxide 作用下， 生成 1,3-dioxo-2,3-dihydro-1H-benz[de]isoquinoline-6-carboxylic acid
  参考文献：
  名称：

  Naphthalene polycarboxylic acid derivative and process for preparing the same

  摘要：

  公开号：

  US02063286A1
• 作为产物：
  描述：

  5-乙酰-1,2-二氢苊烯 在 permanganate(VII) ion 作用下， 生成 1,4,5-萘三羧酸
  参考文献：
  名称：

  Graebe; Haas, Justus Liebigs Annalen der Chemie, 1903, vol. 327, p. 94

  摘要：

  DOI：

文献信息

• Syntheses of All Isomers of Naphthalenetricarboxylic Acids
  作者：Yasuhiko Dozen

  DOI：10.1246/bcsj.45.519

  日期：1972.2

  isomers of naphthalenetricarboxylic acids have been synthesized by the oxidation of trimethylnaphthalenes, dimethylacetonaphthones, dimethylnaphthoic acids, methylnaphthalenedicarboxylic acids, β-(dimethylnaphthoyl)propionic acid, or β-(acenaphthoyl)propionic acids with aqueous sodium bichromate or potassium ferricyanide. Most of these naphthalenetricarboxylic acids, acid anhydrides, and trimethyl esters

  萘三甲酸的所有 14 种异构体都是通过三甲基萘、二甲基丙酮酮、二甲基萘甲酸、甲基萘二甲酸、β-（二甲基萘甲酰基）丙酸或β-（苊酰基）丙酸与重铬酸钠或铁氰化钾水溶液氧化合成的。这些萘三甲酸、酸酐和三甲酯大部分是新化合物。
• Cosmetic composition comprising fibres
  申请人：L'OREAL

  公开号：US20040096473A1

  公开（公告）日：2004-05-20

  Cosmetic composition comprising rigid, substantially rectilinear fibres of a synthetic polymer in a physiologically acceptable medium, in which the polymer is chosen from polyurethanes, polyesters, acrylic polymers, polyolefins, non-aromatic polyamides and aromatic polyimide-amides. The composition may be a makeup composition, a makeup base, a composition to be applied over a makeup, also known as a “top coat”, or a cosmetic treatment or care composition for keratin fibres. The invention relates more particularly to a mascara. The invention also relates to the use of this composition for making up keratin materials, especially the eyelashes, the eyebrows and the hair, and also to a cosmetic makeup or care process for these materials.

  化妆品组合物包括一种生理上可接受的介质中的刚性、基本直线的合成聚合物纤维，其中聚合物选自聚氨酯、聚酯、丙烯酸聚合物、聚烯烃、非芳香族聚酰胺和芳香族聚酰胺酰胺。该组合物可以是化妆品组合物、化妆底霜、用于化妆品上的涂层，也称为“面层”，或者是用于角蛋白纤维的化妆品处理或护理组合物。本发明更特别地涉及一种睫毛膏。本发明还涉及使用该组合物来化妆角蛋白材料，特别是睫毛、眉毛和头发，以及这些材料的化妆品化妆或护理过程。
• PROCESS FOR PRODUCING TRICARBOXYLIC ACID TRIS (ALKYL-SUBSTITUTED CYCLOHEXYLAMIDE)
  申请人：Kitagawa Sachio

  公开号：US20090069599A1

  公开（公告）日：2009-03-12

  Disclosed are, for example, a process for producing a tricarboxylic acid tris(alkyl-substituted cyclohexylamide), the process comprising subjecting a tricarboxylic acid and an alkyl-substituted cyclohexylamine to an amidation reaction, either (a) in the presence of a boric acid compound and a phenol compound or (b) in the presence of a boric acid ester obtained by the dehydration condensation of a boric acid compound and a phenol compound, and optionally purifying the resulting crude reaction product.

  例如，本发明公开了一种生产三羧酸三（烷基取代的环己基）酰胺的方法，该方法包括将三羧酸和烷基取代的环己基胺置于酰胺反应中，（a）在硼酸化合物和酚化合物的存在下或（b）在通过脱水缩合一种硼酸化合物和一种酚化合物所得的硼酸酯的存在下进行反应，并可选择性地纯化所得的粗反应产物。
• Preparation process of heat-resistant polymers
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0235388A2

  公开（公告）日：1987-09-09

  Disclosed herein is a process for preparing heat-resistant polymers by reacting an organic polyisocyanate with one or more compounds selected from the group consisting of organic polycarboxylic acids and organic polycarboxylic acid anhydrides in the presence of an alkali metal fluoride or an alkali metal fluoride combined with a quaternary onium salt as a catalyst.

  本文公开了一种制备耐热聚合物的工艺，该工艺是在碱金属氟化物或碱金属氟化物与季铵盐结合作为催化剂的存在下，使有机多异氰酸酯与一种或多种选自有机多羧酸和有机多羧酸酸酐组成的组的化合物发生反应。
• Amphiphatic polymerizable vinyl monomers, vinyl resin particles derived from said monomers and preparation thereof
  申请人：Nippon Paint Co., Ltd.

  公开号：EP0269187A2

  公开（公告）日：1988-06-01

  A novel amphiphatic polymerizable vinyl monomer of the formula: having surface active function and crosslinking catalytic function, as well as increased amphiphatic nature. The invention also provides a preparation method of said amphiphatic polymerizable vinyl monomer, resin particles obtained by using said vinyl monomer, aqueous and organic solvent dispersion of said resin particles which are specifically useful in coating compositions.

  一种新型脂肪族可聚合乙烯基单体，其化学式为：具有表面活性功能和交联催化功能，并具有增强的脂肪族性质。 本发明还提供了所述脂肪族可聚合乙烯基单体的制备方法、使用所述乙烯基单体获得的树脂颗粒、所述树脂颗粒的水性和有机溶剂分散体，特别适用于涂料组合物。