1,4,6,11-四丙基并四苯-2,3-二羧酸二甲酯 | 323585-63-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 中文名称: 1,4,6,11-四丙基并四苯-2,3-二羧酸二甲酯
• 中文别名: 二(1-(5-氯-1-羟基苯偶氮基)-2-萘醇酸根)铬酸(1-)十四烷基铵
• 英文名称: dimethyl 1,4,6,11-tetrapropylnaphthacene-2,3-dicarboxylate
• 英文别名: 2,3-bis(methoxycarbonyl)-1,4,6,11-tetrapropylnaphthacene；dimethyl 1,4,6,11-tetrapropyltetracene-2,3-dicarboxylate
• CAS: 323585-63-3
• 化学式: C₃₄H₄₀O₄
• 分子量: 512.689
• InChiKey: YIOLBGRRNPUFTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  38
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4,6,11-四丙基并四苯-2,3-二羧酸二甲酯 在 氧气 作用下， 以80%的产率得到Dimethyl 1,5,8,12-tetrapropyl-19,20-dioxapentacyclo[10.6.2.02,11.04,9.013,18]icosa-2(11),3,5,7,9,13,15,17-octaene-6,7-dicarboxylate
  参考文献：
  名称：

  取代基对多取代并苯氧化中区域选择性的影响

  摘要：

  取代并苯如蒽、并四苯和并五苯衍生物与O 2 的反应取决于取代基及其位置。在并四苯和并五苯衍生物的情况下，该方向与 DDQ 的 Diels-Alder 反应相反。1,2,3,4,5,6,7,8-八甲基蒽与O 2 反应以在两个端环处提供双氧化化合物（二内过氧化物）。

  DOI：

  10.1246/cl.2004.410
• 作为产物：
  描述：

  dimethyl 5,12-dihydro-1,4,6,11-tetrapropylnaphthacene-2,3-dicarboxylate 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以71%的产率得到1,4,6,11-四丙基并四苯-2,3-二羧酸二甲酯
  参考文献：
  名称：

  Functional thin film

  摘要：

  本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。

  公开号：

  US20050240061A1

文献信息

• Polyacene derivatives and production thereof
  申请人：——

  公开号：US20030116755A1

  公开（公告）日：2003-06-26

  The present invention relates to polyacene derivatives represented by general formula (I) below: 1 (wherein R 1 to R 10 , etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A 1 and A 2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R 6 and R 7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

  本发明涉及以下通式（I）所代表的聚芳烃衍生物：1（其中R1至R10等分别代表氢原子、烃基或烷氧基；A1和A2分别代表氢原子、卤素原子、烃基、烷氧基、氰基等；n为不小于1的整数；R6和R7可以连接在一起形成环）；以及从聚羟基化合物制备聚芳烃衍生物的方法，以及包括所述聚芳烃衍生物的电导材料。根据本发明的制备聚芳烃衍生物的方法，可以在聚芳烃的任何碳原子上引入可选取代基团，并且可以增加芳香环的数量。
• Functional thin film
  申请人：Takahashi Tamotsu

  公开号：US20050240061A1

  公开（公告）日：2005-10-27

  The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , A 1 and A 2 , which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

  本发明提供了选择自下述一般式（I）所代表的聚芳烃衍生物的有机电致发光元件：[其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2，它们相同或不同，分别代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供用于有机电致发光元件和有机电致发光元件的材料，这些元件在稳定性、耐久性、亮度和发光效率方面都表现出优异的特性。
• POLYACENE DERIVATIVES AND PRODUCTION THEREOF
  申请人：JAPAN SCIENCE AND TECHNOLOGY CORPORATION

  公开号：EP1262469A1

  公开（公告）日：2002-12-04

  The present invention relates to polyacene derivatives represented by general formula (I) below: (wherein R1 to R10, etc. each represents hydrogen atom, hydrocarbon group, or an alkoxy group; A1 and A2 are hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxy group, cyano group, etc.; n is an integer of not less than 1; R6 and R7 may be linked to each other to form a ring); and a process for preparing the polyacene derivatives from polyhydro compounds as well as electrically conductive materials comprising the polyacene derivatives. According to the process for preparing the polyacene derivatives of the present invention, optional substituents can be introduced into any carbon atoms of the polyacene, and the number of aromatic rings can be increased.

  本发明涉及如下通式(I)所代表的聚乙炔衍生物： (其中R1至R10等各自代表氢原子、烃基或烷氧基；A1和A2为氢原子、卤素原子、烃基、烷氧基、氰基等；n为不小于1的整数；R6和R7可相互连接形成环）；以及从多氢化合物制备该聚乙炔衍生物的工艺和包含该聚乙炔衍生物的导电材料。根据本发明制备聚乙炔衍生物的工艺，可在聚乙炔的任意碳原子上引入任选取代基，并可增加芳香环的数量。
• FUNCTIONAL THIN FILM
  申请人：Japan Science and Technology Agency

  公开号：EP1493796A1

  公开（公告）日：2005-01-05

  The present invention provides organic electroluminescent elements selected from polyacene derivatives represented by general formula (I) below: [wherein, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, A1 and A2, which are the same or different, each represents hydrogen atom, a hydrocarbon group, etc., and n denotes an integer of not less than 1]. The organic electroluminescent elements of the present invention can provide materials for organic electroluminescent elements and organic electroluminescent elements, which are excellent in stability, durability, luminance and luminance efficiency.

  本发明提供的有机电致发光元件选自以下通式 (I) 所代表的聚乙炔衍生物： [其中，R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、A1和A2相同或不同，各自代表氢原子、烃基等，n表示不小于1的整数]。本发明的有机电致发光元件可以提供稳定性、耐久性、亮度和发光效率都非常优异的有机电致发光元件材料和有机电致发光元件。
• ORGANIC SEMICONDUCTOR MATERIAL, ORGANIC SEMICONDUCTOR THIN FILM AND ORGANIC SEMICONDUCTOR DEVICE
  申请人：Ohe Takahiro

  公开号：US20090140241A1

  公开（公告）日：2009-06-04

  An organic semiconductor material is provided. The organic semiconductor material includes a polyacene derivative expressed by the following general formula (1): where each of R 1 to R 10 may be independently the same substituents or different substituents but all of R 1 , R 4 , R 5 , R 6 , R 9 and R 10 may never be hydrogen atoms at the same time, and where each of R 1 to R 10 is at least one kind of substituent selected from the group consisting of an aliphatic hydrocarbon group having a substituent and of which number of carbon atoms ranges of from 1 to 20, an aromatic hydrocarbon group having a substituent, a complex aromatic group having a substituent, a carboxyl group, a hydride, an ester group, a cyano group, a hydroxyl group, a halogen atom and a hydrogen atom. The organic semiconductor material can be dissolved into an organic solvent at low temperature (for example, room temperature) and is suitable for use with a coating process.