1-N,3-N-二甲基丁烷-1,3-二胺 | 57757-16-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-N,3-N-二甲基丁烷-1,3-二胺
• 英文名称: N,N'-dimethyl-butane-1,3-diamine
• 英文别名: 1,N¹,N³-trimethyl-propanediyldiamine；1,N¹,N³-Trimethyl-propandiyldiamin；N,N'-Dimethyl-1,3-butandiamin；1.3-Bis-(methylamino)-butan；N~1~,N~3~-Dimethylbutane-1,3-diamine；1-N,3-N-dimethylbutane-1,3-diamine
• CAS: 57757-16-1
• 化学式: C₆H₁₆N₂
• mdl: MFCD19217492
• 分子量: 116.206
• InChiKey: DKZBLXUAJDHZQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-N,3-N-二甲基丁烷-1,3-二胺 在 三乙胺 、 三氯化磷 作用下， 以 苯 为溶剂， 生成 2-aziridin-1-yl-1,3,4-trimethyl-[1,3,2]diazaphosphinane
  参考文献：
  名称：

  Nifant'ev,E.E. et al., Journal of general chemistry of the USSR, 1979, vol. 49, p. 53 - 61

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4,5-Trimethyl-1,5-diaza-pentadien-(2,4) 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 为溶剂， 生成 1-N,3-N-二甲基丁烷-1,3-二胺
  参考文献：
  名称：

  Schroth,W. et al., Zeitschrift fur Chemie, 1969, vol. 9, # 3, p. 110 - 111

  摘要：

  DOI：

文献信息

• Amino alcohol derivatives
  申请人：SANKYO COMPANY, LIMITED

  公开号：US20030236297A1

  公开（公告）日：2003-12-25

  Compounds of formula (I) which exhibit excellent immune suppression activity, pharmacologically acceptable salts thereof, esters thereof or other derivatives: 1 wherein R 1 and R 2 are a hydrogen atom, an amino protecting group; R 3 is a hydrogen atom, a hydroxy protecting group; R 4 is a lower alkyl group; n is an integer from 1 to 6; X is an ethylene group; Y is a C 1 -C 10 alkylene group, a C 1 -C 10 alkylene group substituted with 1 to 3 substituents selected from substituent group a and b; R 5 is an aryl group; R 6 and R 7 are a hydrogen atom, a group selected from substituent group a; with the proviso when R 5 is a hydrogen atom, Y is not a single bond or a straight chain C 1 -C 10 alkylene group.

  式（I）的化合物表现出优异的免疫抑制活性，其药理学上可接受的盐，酯或其他衍生物：其中R1和R2是氢原子，氨基保护基；R3是氢原子，羟基保护基；R4是较低的烷基基团；n是1到6之间的整数；X是乙烯基团；Y是C1-C10烷基基团，带有1到3个从取代基a和b中选择的取代基的C1-C10烷基基团；R5是芳基基团；R6和R7是氢原子，从取代基a中选择的基团；但是当R5是氢原子时，Y不是单键或直链的C1-C10烷基基团。
• Internal release agent, composition including internal release agent, and process for producing a plastic lens using same composition
  申请人：MITSUI CHEMICALS, INC.

  公开号：US10239239B2

  公开（公告）日：2019-03-26

  An internal release agent includes at least one phosphodiester represented by the following general formula (1). In the formula, R1 and R2 independently represent a hydrocarbon group having 1 to 30 carbon atoms, which is optionally substituted with at least one hydroxyl group, and R3 represents an alkylene group having 2 to 4 carbon atoms. A plurality of R3's may be the same as or different from each other. M represents a hydrogen atom, an ammonium ion, an alkali metal ion, or a monovalent/divalent alkali earth metal ion, and n is an integer of 1 to 60.

  内部释放剂至少包括一个由以下一般式（1）表示的磷酸二酯。在该式中，R1和R2分别表示具有1至30个碳原子的烃基，该烃基可以选择性地取代至少一个羟基，而R3表示具有2至4个碳原子的烷基基团。多个R3可以相同或者彼此不同。M代表氢原子、铵离子、碱金属离子或者一价/二价碱土金属离子，n为1至60的整数。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Amino alcohol derivatives or phosphonic acid derivatives and pharmaceutical compositions containing these
  申请人：Nishi Takahide

  公开号：US20050043386A1

  公开（公告）日：2005-02-24

  Amino alcohol compounds and phosphonic acid compounds having excellent immunosuppressive activity, pharmacologically acceptable salts thereof and pharmacologically acceptable esters thereof, and pharmaceutical compositions comprising such compounds, the compounds having the following formula: wherein R 1 and R 2 each represent hydrogen, or a protecting group of the amino group; R 3 represents hydrogen, or a protecting group of the hydroxyl group; R 4 represents a lower alkyl group; n is 1 to 6; X represents oxygen or nitrogen, which is unsubstituted or substituted with a lower alkyl group; Y represents ethylene; Z represents a C 1 -C 10 alkylene; R 5 represents an aryl group; and R 6 and R 7 each represents hydrogen; provided that when R 5 represents hydrogen, then Z represents a group other than a single bond or a straight chain C 1 -C 10 alkylene group.

  具有出色的免疫抑制活性的氨基醇化合物和膦酸化合物，其药理学上可接受的盐和药理学上可接受的酯，以及包含这些化合物的制药组合物，其中化合物具有以下式子：其中R1和R2各代表氢，或氨基保护基；R3代表氢，或羟基保护基；R4代表较低的烷基；n为1至6；X代表氧或氮，未取代或取代为较低的烷基；Y代表乙烯；Z代表C1-C10烷基；R5代表芳基；R6和R7各代表氢；但是当R5代表氢时，Z代表除单键或直链C1-C10烷基组以外的一种基团。
• Episulfide compound and process for producing the same
  申请人：——

  公开号：US20030149231A1

  公开（公告）日：2003-08-07

  The episulfide compound of the present invention has, in one molecule, one or more epithio structures represented by the following Formula 1: 1 wherein R 1 is C 1 -C 10 hydrocarbylene group; R 2 , R 3 and R 4 are each independently C 1 -C 10 hydrocarbyl group or hydrogen; Y is S, O, Se or Te; n is an integer of from 0 to 5; and m is 0 or 1, and further characterized by having a nitrogen content of 5000 ppm or less. The optical material produced by curing the episulfide compound by polymerization has a high refractive index and a large Abbe's number with little coloring and haze. The optical material is useful, particularly, as spectacle plastic lenses.

  本发明的环氧丙烷化合物在一个分子中具有一个或多个如下式1所表示的环硫结构：其中，R1是C1-C10烃基链；R2、R3和R4各自独立地是C1-C10烃基或氢；Y是S、O、Se或Te；n为0至5的整数；m为0或1，并且具有5000ppm或以下的氮含量。通过聚合固化环氧丙烷化合物制备的光学材料具有高折射率和大的阿贝数，且具有很少的色差和浑浊度。该光学材料特别适用于制作眼镜塑料镜片。