1-[(3-氨基丙基)-(2-羟基丙基)-氨基]-2-丙醇 | 77355-06-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 1-[(3-氨基丙基)-(2-羟基丙基)-氨基]-2-丙醇
• 英文名称: 1-[(3-aminopropyl)-(2-hydroxypropyl)-amino]-2-propanol
• 英文别名: (3-aminopropyl)-di-(2-hydroxopropyl)amine；1-[(3-Aminopropyl)-(2-hydroxypropyl)-amino]propan-2-OL；1-[3-aminopropyl(2-hydroxypropyl)amino]propan-2-ol
• CAS: 77355-06-7
• 化学式: C₉H₂₂N₂O₂
• mdl: MFCD08166289
• 分子量: 190.286
• InChiKey: FYYUTGDAKCRTMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.7
• 氢给体数：
  3
• 氢受体数：
  4

安全信息

• 海关编码：
  2922199090

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 1-[(3-氨基丙基)-(2-羟基丙基)-氨基]-2-丙醇 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Polymorphism in dinuclear Cu(II) compounds – polymorphism caused by different degrees of hydration: the structures of [Cu(HL)]2Cl24H2O (I), [Cu(HL)]2Cl2·2H2O (II), [Cu(HL)]2)(NO3)2·4H2O (III), [Cu(HL)]2)(NO3)2·2H2O (IV) and [Cu(HL)]2)(ClO4)2·2H2O (V) (HL=[(3-aminopropyl)-di-(2-hydroxopropyl)]amine anion). Counterion control of the crystallization pathway. Part 11

  摘要：

  Compounds of composition [CiuHL)](2)Cl-2 (.) 4H(2)O (I), [Cu(HL)](2)Cl-2H(2)O (II), [Cu(HL)](2))(NO3)(2) (.) 4H(2)O (III), [Cu(HL)](2))(NO3)(2) (.) 2H(2)O (IV) and [Cu(HL)](2))(ClO4)(2) (.) 2H(2)O (V) (HL = [(3-aminopropyl)-di-(2-hydroxopropyl)]-amine anion) were prepared and their crystal structures determined. Compounds I. IV and V crystallize in the same space group, P2(1)/(n), and are very close to being isomorphous and isostructural. II Crystallizes in space group Peab, while III crystallizes in C21c. The pairs of compounds I-II and III-IV are examples of hydration polymorphism. Efforts to obtain polymorphic forms of V have, thus far, been negative.All five compounds contain a central bi-metallic core consisting of two Cu(II) cations bridged by two oxygens. The resulting species are antiferromagnetically coupled and can nicely be fitted to a Bleany-Bowers model with great precision. Electron spin resonance studies were carried out in solid powders and in frozen solutions, at 77 K in both instances. The g-factors obtained from the latter studies were used in the fitting of the magnetism measurements, which were made between 5 and 295 K.Counter anions were changed on purpose in order to ascertain the manner in which counter ions exert ail effect in the selection of the crystallization pathway chosen. Also, solvent changes were made which resulted in the polymorphism observed, and which was due to variations in the ratios of the solvent components (e.g., methanol-water).All five cations contain one Cu(II)-OH2 bond: and. the length of this bond is the primary difference in the stereochemistry of the cations. They range from 2.731 to 3.959 Angstrom. A discussion is given of the arguments for and against considering the two longest distances (3.827 and 3.959 Angstrom) as true bonds. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.037

文献信息

• Softener composition
  申请人：——

  公开号：US20030036499A1

  公开（公告）日：2003-02-20

  A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. 1 (wherein, R 1 , R 2 and R 3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R 4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X − represents an anionic group.)

  提供了一种软化剂组合物，其中包含三种长链烷基季铵盐，这些季铵盐被认为难以用作软化剂基础剂，并且可以提供具有足够软化性能的软化剂组合物，其包括(A)阳离子表面活性剂，包括从式(I)、(II)或(III)表示的季铵盐中选择的至少一种，其中式(I)表示的季铵盐的比例占这些盐的总量超过50重量％，其中式(III)的比例被设定为不超过10％，以及(B)至少一种非离子表面活性剂。在这种情况下，(A)可能包括三级胺。(其中，R1、R2和R3表示具有8至40个总碳原子的长链烷基，等等，这些烷基可以被醚基，酯基或酰胺基所交叉；R4表示具有1至6个碳原子的烷基等，X-表示阴离子基团。)
• Durable coating compositions containing novel aspartic amine compounds
  申请人：Lenges Peter Christian

  公开号：US20060155054A1

  公开（公告）日：2006-07-13

  A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X, R 1 , R 2 , p, m and n are described in the specification, or isomer or mixture of isomers thereof, two component compositions, articles coated with the novel composition and novel hydroxy amines are also part of the invention.

  一种涂层组合物，包括以下成分：a.聚异氰酸酯交联剂；b.至少含有一个化合物的异氰酸酯反应组分，该化合物具有以下公式：其中X，R1，R2，p，m和n在规范中有描述，或其同分异构体或混合物。该发明还包括两种组分组成的组合物、涂有新型组合物的物品以及新型羟基胺。
• Method for preparing quaternary ammonium salts
  申请人：Kao Corporation

  公开号：EP1884560A2

  公开（公告）日：2008-02-06

  The present invention relates to a method of producing quaternary ammonium salts represented by the formulae (I), (II) or (III). (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X- represents an anionic group), by reacting a tertiary amine of a specified formula with a quaternizing agent in at least one aprotic solvent selected from specified solvents.

  本发明涉及一种生产式 (I)、(II) 或 (III) 所代表的季铵盐的方法。 (其中，R1、R2 和 R3 代表总碳原子数为 8 至 40 的长链烷基等，可由醚基、酯基或酰胺基相交；R4 代表碳原子数为 1 至 6 的烷基等，X- 代表阴离子基团)，通过在至少一种选自指定溶剂的非沸腾溶剂中使指定式的叔胺与季铵化剂反应。
• Laundry detergent compositions containing a polymer for fabric appearance improvement
  申请人：The Procter & Gamble Company

  公开号：US20010056058A1

  公开（公告）日：2001-12-27

  Detergent compositions and fabric conditioning compositions which include from about 0.01% to about 5.0%, by weight, of polyelectolyte complexes having a compatible charge-balancing polymeric anion with at least 3 anionic groups and a total net charge of at least 4 negative charges.

  洗涤剂组合物和织物护理剂组合物，其中包括约 0.01%至约 5.0%（按重量计）的聚电解质复合物，该复合物具有相容的电荷平衡聚合物阴离子，其阴离子基团至少有 3 个，总净电荷至少有 4 个负电荷。
• Polyelectrolyte complexes and a method for production thereof
  申请人：——

  公开号：US20030078185A1

  公开（公告）日：2003-04-24

  Polyelectrolyte complexes of cationic and anionic polymers which consist of (a) cationic condensates of (i) at least one amine and (ii) a crosslinking agent from the group consisting of epihalohydrins, bishalohydrins of diols, bishalohydrins of polyalkylene glycols, bishalohydrins of polytetrahydrofurans, alkylene dihalides, alkylene trihalides, bisepoxides, trisepoxides, tetraepoxides and/or mixtures of said compounds, and/or quaternized cationic condensates of (i) and (ii), and (b) anionic compounds containing at least three anionic groups and have a charge ratio between anionic and cationic polymers of from 0.01 to 20, and a process for the preparation of the polylectrolyte complexes by mixing the cationic condensates (a) with anionic compounds (b).

  阳离子和阴离子聚合物的聚电解质复合物，由以下物质组成 (a) (i)至少一种胺和(ii)一种交联剂的阳离子缩合物，交联剂包括表卤代烃、二元醇的双卤代烃、聚亚烷基二醇的双卤代烃聚四氢呋喃的双卤水酐、亚烷基二卤化物、亚烷基三卤化物、双环氧化物、三环氧化物、 四环氧化物和/或上述化合物的混合物，和/或(i)和(ii)的季铵化阳离子缩合物，以及 (b) 至少含有三个阴离子基团的阴离子化合物 以及将阳离子缩合物（a）与阴离子化合物（b）混合制备聚电解质复合物的工艺。