1-丙-2-烯基-1-铵双环[2.2.2]辛烷-8-醇 | 113480-17-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 奎宁环
• 中文名称: 1-丙-2-烯基-1-铵双环[2.2.2]辛烷-8-醇
• 英文名称: N-Allyl-3-quinuclidinol
• 英文别名: 1-prop-2-enyl-1-azoniabicyclo[2.2.2]octan-3-ol
• CAS: 113480-17-4
• 化学式: C10H18NO+
• 分子量: 168.26
• InChiKey: USNHRGULVPUURO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
  申请人：Cao Guang

  公开号：US20070100185A1

  公开（公告）日：2007-05-03

  The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R 1 R 2 R 3 N—R 4 ] + Q − wherein R 1 and R 2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R 1 and R 2 may be joined to form a nitrogen-containing heterocyclic structure, R 3 is an alkyl group having 2 to 4 carbon atoms and R 4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R 3 and R 4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q − is a anion.

  在有机引导剂的存在下进行晶体材料的合成，特别是高硅沸石，包括一个以Chabazite类型骨架分子筛为主的结构。该有机引导剂的化学式为：[R1R2R3N—R4]+Q−，其中R1和R2分别选择具有1至3个碳原子的烃基和羟基取代的烃基，前提是R1和R2可以结合形成含氮的杂环结构，R3是具有2至4个碳原子的烷基，而R4则选择一个4至8个成员的环烷基，可选地，由1至3个每个具有1至3个碳原子的烷基取代;和一个具有1至3个杂原子的4至8个成员的杂环基，该杂环基可选地由1至3个每个具有1至3个碳原子的烷基取代，而且该杂环基中的每个杂原子来自于O、N和S的群组，或者R3和R4是具有1至3个碳原子的烃基，结合形成含氮的杂环结构；Q−是一个阴离子。
• Process For The Preparation Of Zeolites Having CHA Structure
  申请人：Bull Ivor

  公开号：US20120244066A1

  公开（公告）日：2012-09-27

  The present invention relates to a process for the preparation of zeolites having CHA framework structure and a composition comprising the molar ratio (n SiO 2 ):X2O 3 , wherein X is a trivalent element, and wherein n is at least 10, the process comprising (i) preparation of an aqueous solution containing at least one source for X 2 O 3 , wherein X is selected from Al, B, Ga, and a mixture of two or more, and at least one source for SiO 2 , at least one organic structure directing agent (SDA) other than Tetrame-thylammonium hydroxide (TMAOH), acting as a template for the CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA:TMAOH of 0.01 to 5; (ii) hydrothermal crystallization of the aqueous solution according to (i); wherein the aqueous solution of (i) contains copper in an amount less than 0.005 Cu:((n YO 2 )+X 2 O 3 ) where n is in the range of 10 to 50. The present invention also relates to the zeolitic materials obtainable and/or obtained by this process as well as to a zeolitic material as such, having framework structure CHA, having a composition comprising the molar ratio (n SiO 2 ):X 2 O 3 , wherein X is a trivalent element and n is at least 10, and wherein the crystal size, as determined from Scanning Electron Microscopy, is greater than 1 micrometer and wherein the chabazite framework is phase-pure having an impurity of other zeolitic frameworks, such as RUT as determined by X-ray Diffraction, of less than 5%.

  本发明涉及一种制备具有CHA骨架结构的沸石和组成物的过程，包括摩尔比（n SiO2）：X2O3，其中X是三价元素，n至少为10，该过程包括：（i）制备含有至少一种X2O3源的水溶液，其中X选自Al、B、Ga和两种或更多混合物，以及至少一种SiO2源、至少一种有机结构导向剂（SDA）作为CHA结构的模板，除四甲基铵氢氧化物（TMAOH）外，还包括四甲基铵氢氧化物（TMAOH），其中SDA或其混合物的用量使得（i）中的水溶液呈现出SDA：TMAOH的摩尔比为0.01至5；（ii）根据（i）的水溶液进行水热晶化；其中（i）的水溶液中含有铜的量小于0.005 Cu：（（n YO2）+X2O3），其中n在10至50的范围内。本发明还涉及通过该过程获得和/或获得的沸石材料，以及具有CHA骨架结构的沸石材料，其组成物包括摩尔比（n SiO2）：X2O3，其中X是三价元素，n至少为10，晶体尺寸从扫描电子显微镜确定，大于1微米，且方解石骨架是相纯的，其他沸石骨架的杂质，例如RUT，由X射线衍射确定小于5%。
• Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins
  申请人：Cao Guang

  公开号：US20050154244A1

  公开（公告）日：2005-07-14

  A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X 2 O 3 :YO 2 , wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.

  一种晶体材料，基本不含框架磷，包括一种CHA框架类型的分子筛，具有堆垛故障或至少一种CHA框架类型的分子筛和AEI框架类型的分子筛的交织相。该材料在其焙烧、无水形式下，具有以下摩尔比关系的组成：（n）X2O3：YO2，其中X是三价元素，Y是四价元素，n为0到约0.5。该材料在甲醇转化为低碳烯烃，特别是乙烯和丙烯方面表现出活性和选择性。
• Production of light olefins
  申请人：Hall Richard B.

  公开号：US20080033225A1

  公开（公告）日：2008-02-07

  This invention is directed to a process for producing olefin product from an oxygenate feed that includes dimethyl ether (DME). The process uses an olefin forming catalyst that contains a porous crystalline material, preferably a porous crystalline aluminosilicate molecular sieve material. The process produces high quantities of light olefin (i.e., ethylene, propylene, and mixtures thereof).

  本发明涉及一种从含有二甲醚（DME）的氧化物进料中生产烯烃产品的方法。该方法使用一种含有多孔晶体材料催化剂的烯烃形成催化剂，优选为多孔晶体硅铝酸盐分子筛材料。该方法生产大量轻质烯烃（即乙烯、丙烯和其混合物）。
• Process for the preparation of zeolites having B-CHA structure
  申请人：BASF SE

  公开号：EP2325143A2

  公开（公告）日：2011-05-25

  The present invention relates to a process for the preparation of zeolites having B-CHA framework structure and a composition comprising the molar ratio (n SiO2) : B2O3, wherein n is at least 10, the process comprising (i) preparation of an aqueous solution containing at least one source for B2O3, at least one source for SiO2, at least one source of seeding crystals of chabazite structure, at least one organic structure directing agent (SDA) other than Tetramethylammonium hydroxide (TMAOH), acting as a template for the B-CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA : TMAOH of 0.01 to 5; (ii) hydrothermal crystallization of the aqueous solution according to (i); wherein the ratio of the [molar ratio (SiO2 : B2O3)] of the gel composition : [molar ratio (SiO2 : B2O3)] of the crystalline product having the chabazite structure is greater than 0.5. The present invention also relates to the zeolitic materials obtainable and/or obtained by this process as well as to a zeolitic material as such, having framework structure B-CHA, having a composition comprising the molar ratio (n SiO2) : B2O3, wherein n is at least 10, and wherein the ratio of the [molar ratio (SiO2 : B2O3)] of the gel composition: [molar ratio (SiO2 : B2O3)] of the crystalline product having the chabazite structure is greater than 0.5.

  本发明涉及一种制备具有 B-CHA 框架结构的沸石的工艺，其组成包括摩尔比 (n SiO2) : B2O3，其中 n 至少为 10，该工艺包括 (i) 制备一种水溶液，其中含有至少一种 B2O3 原料、至少一种 SiO2 原料、 至少一种 Chabazite 结构的种子晶体原料、至少一种除氢氧化四甲基铵 （TMAOH）以外的有机结构引导剂（SDA）、四甲基氢氧化铵（TMAOH），其中 SDA 或其混合物的用量应使 (i) 中的水溶液显示出 SDA ：TMAOH 的摩尔比为 0.01 至 5； (ii) 根据(i)所述水溶液的水热结晶； 其中凝胶组合物的[摩尔比(SiO2 : B2O3)]∶具有夏巴齐石结构的结晶产物的[摩尔比(SiO2 : B2O3)]之比大于0.5。 本发明还涉及可通过该工艺获得和/或得到的沸石材料，以及具有框架结构 B-CHA 的沸石材料，其组成包括摩尔比 (n SiO2) : B2O3，其中 n 至少为 10，其中凝胶组成的[摩尔比（SiO2 : B2O3）]之比为：[摩尔比（SiO2 : B2O3）]大于 0.5：具有茶苯矿结构的结晶产品的[摩尔比（SiO2 : B2O3）]之比大于 0.5。