1-氯-2-甲基戊-2-烯 | 137255-95-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1-氯-2-甲基戊-2-烯
• 中文别名: 2-戊烯,1-氯-2-甲基-,(E)-
• 英文名称: 1-chloro-2-methylpent-2-ene
• 英文别名: (E)-1-chloro-2-methyl-pent-2-ene；seqtrans-1-Chlor-2-methyl-pent-2-en；(E)-1-chloro-2-methylpent-2-ene
• CAS: 137255-95-9
• 化学式: C₆H₁₁Cl
• 分子量: 118.606
• InChiKey: ZUCGUJGZNWUYOE-GQCTYLIASA-N

物化性质

• 沸点：
  130.2±9.0 °C(Predicted)
• 密度：
  0.895±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-氯-2-甲基戊-2-烯 在 sodium sulfide 作用下， 以 乙醇 为溶剂， 生成 (E,E)-bis-(2-methyl-pent-2-enyl)-sulfane
  参考文献：
  名称：

  977.异构体二（甲基戊烯基）硫化物和二硫化物的合成与表征

  摘要：

  DOI：

  10.1039/jr9620005045
• 作为产物：
  描述：

  2-甲基-2-戊烯醛 在 lithium aluminium tetrahydride 、 三氯化磷 作用下， 以 吡啶 、 乙醚 为溶剂， 生成 1-氯-2-甲基戊-2-烯
  参考文献：
  名称：

  977.异构体二（甲基戊烯基）硫化物和二硫化物的合成与表征

  摘要：

  DOI：

  10.1039/jr9620005045

文献信息

• Synthesis of 4- and 5-benzothiazol-2-yldithio-2,6-dimethylocta-2,6-diene and other models for pendent groups in the sulphur vulcanisation of natural rubber
  作者：Norman J. Morrison

  DOI：10.1039/p19840000101

  日期：——

  thioacetates afforded the thiols (16c) and (18c), which were converted into the title disulphides (21) and (22) by treatment with N-(benzothiazol-2-ylthio)phthalimide. Monosulphidic and other disulphidic model pendent groups were prepared by nucleophilic displacement reactions of the benzothiazole-2-thiolate anion with the appropriate chloro compound or Bunte salt, respectively.

  2,6-和3,7-二甲基辛基-2,6-二烯-4-醇（14）和（15）与硫代乙酸和偶氮二羧酸二异丙酯-三苯基膦反应，除其他以外，得到硫代乙酸酯（16b）和（18b）。还原硫代乙酸盐得到硫醇（16c）和（18c），通过用N-（苯并噻唑-2-基硫基）邻苯二甲酰亚胺处理将其转化为标题二硫化物（21）和（22）。通过分别使苯并噻唑-2-硫代硫酸根阴离子与适当的氯代化合物或邦特盐进行亲核取代反应，制备单硫基和其他二硫基模型侧基。
• CONJUGATED DIENE POLYMER AND METHOD FOR PRODUCING SAME
  申请人：Bando Fumiaki

  公开号：US20140350201A1

  公开（公告）日：2014-11-27

  Conjugated diene polymer comprising at least a conjugated diene monomer unit, the conjugated diene polymer has a number-average molecular weight (Mn) in terms of polystyrene of 1,000 to 1,000,000, a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to the number-average molecular weight (Mn) of lower than 2.0 and the polymer bears a halogen atom at a terminal of the polymer chain. Method for producing the conjugated diene polymer comprises subjecting a monomer containing at least a conjugated diene to living radical polymerization using a polymerization initiator comprising a halogenocyclopentadienyl triorganophosphine η 2 -olefin ruthenium complex represented by formula (6) (and an organic halide.

  共轭二烯聚合物包括至少一个共轭二烯单体单元，该共轭二烯聚合物的聚合度数平均分子量（Mn）以聚苯乙烯为单位为1,000至1,000,000，重均分子量（Mw）与数均分子量（Mn）之比小于2.0，并且该聚合物在聚合物链的末端带有卤素原子。制备该共轭二烯聚合物的方法包括使用聚合引发剂将至少含有一个共轭二烯的单体进行活性自由基聚合，所述聚合引发剂包括一个卤代环戊二烯基三有机膦η2-烯烃钌配合物，其化学式为（6）（和一个有机卤化物）。
• Allylbarium Reagents: Unprecedented Regio- and Stereoselective Allylation Reactions of Carbonyl Compounds
  作者：Akira Yanagisawa、Shigeki Habaue、Katsutaka Yasue、Hisashi Yamamoto

  DOI：10.1021/ja00093a010

  日期：1994.7

  The first direct preparation of allylbarium reagents by reaction of insitu generated reactive barium with various allylic chlorides and their new and unexpected selective allylation reactions with carbonyl compounds are disclosed. Highly reactive barium was readily prepared by the reduction of barium iodide with 2 equiv of lithium biphenylide in dry THF at room temperature. A variety of carbonyl compounds reacted with barium reagents generated from (E)- or (Z)-allylic chlorides in THF at -78 degrees C. All reactions resulted in high yields with remarkable alpha-selectivities not only with aldehydes but also with ketones. The double bond geometry of the starting allylic chloride was completely retained in each case. Stereochemically homogeneous (E)- and (Z)beta,gamma-unsaturated carboxylic acids were easily prepared in good yields by highly alpha-selective carboxylation of allylic barium reagents with carbon dioxide. A selective Michael addition reaction with alpha,beta-unsaturated cycloalkanone was also achieved using an allylbarium reagent. Treatment of 2-cyclopentenone (1 equiv) with allylbarium chloride (2 equiv) in THF at -78 degrees C for 20 min afforded 3-allylcyclopentanone in 94% yield with a 1,4/1,2 ratio of >99/1. Furthermore, the in situ generated barium enolate was efficiently trapped with various kinds of electrophiles (Me(2)C=CHCH2Br, (C5H11CHO)-C-n, and CH3COCl).
• Allylbarium in organic synthesis: unprecedented .alpha.-selective and stereospecific allylation of carbonyl compounds
  作者：Akira Yanagisawa、Shigeki Habaue、Hisashi Yamamoto

  DOI：10.1021/ja00023a058

  日期：1991.11
• REGIO- AND STEREOSELECTIVE CARBOXYLATION OF ALLYLIC BARIUM REAGENTS: (E)-4,8-DIMETHYL-3,7-NONADIENOIC ACID
  作者：Yanagisawa, Akira、Yasue, Katsutaka、Yamamoto, Hisashi

  DOI：10.15227/orgsyn.074.0178

  日期：——