1-氯-4-(三氯甲基)环辛烷 | 16844-39-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1-氯-4-(三氯甲基)环辛烷
• 英文名称: 1-chloro-4-trichloromethyl-cyclooctane
• 英文别名: 4-(trichloromethyl)-1-chlorocyclooctane；1-chloro-4-trichloromethylcylooctane；1-Trichlormethyl-4-chlorcyclooctan；1-Chloro-4-(trichloromethyl)cyclooctane；1-chloro-4-(trichloromethyl)cyclooctane
• CAS: 16844-39-6
• 化学式: C₉H₁₄Cl₄
• 分子量: 264.022
• InChiKey: IASNRDZDJMWPIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  四氯化碳 、 顺-环辛烯 在 过氧化苯甲酰 作用下， 反应 15.0h， 生成 1-氯-4-(三氯甲基)环辛烷
  参考文献：
  名称：

  Addition of Bromotrichloromethane and Tetrachloromethane tocis-Cyclooctene, Cyclohexene, and Norbornadiene in the Presence of Palladium(II) Complexes

  摘要：

  Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.

  DOI：

  10.1023/b:rujo.0000003181.02370.cf

文献信息

• Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs
  作者：Niklas Zwettler、Antoine Dupé、Sumea Klokić、Angela Milinković、Dado Rodić、Simon Walg、Dmytro Neshchadin、Ferdinand Belaj、Nadia C. Mösch‐Zanetti

  DOI：10.1002/adsc.202000425

  日期：2020.8.4

  Three molybdenum(VI) dioxido complexes [MoO2(L)2] bearing Schiff base ligands were reacted with B(C6F5)3 to afford the corresponding adducts [MoOOB(C6F5)3}(L)2], which were fully characterized. They exhibit Frustrated Lewis‐Pairs reactivity when reacting with silanes. Especially, the [MoOOB(C6F5)3}(L)2] complex with L=2,4‐dimethyl‐6‐((phenylimino)methyl)phenol proved to be active as catalyst for

  三个带有席夫碱配体的二氧化钼(VI)络合物[MoO 2 (L) 2 ]与B(C 6 F 5 ) 3反应，得到相应的加合物[MoOOB(C 6 F 5 ) 3 }(L) 2 ]，其特征得到充分表征。当与硅烷反应时，它们表现出受阻路易斯对反应性。特别是，[MoOOB(C 6 F 5 ) 3 }(L) 2 ]与L=2,4-二甲基-6-((苯基亚氨基)甲基)苯酚的络合物被证明具有作为芳基加氢烷基化催化剂的活性。烯烃与有机卤化物以及有机卤化物与脂肪族烯烃的原子转移自由基加成 (ATRA)。使用低催化剂负载量，由简单的烯烃和有机卤化物（如氯仿或溴仿）合成了一系列具有进一步衍生化潜力的偕二氯化物和偕二溴化物化合物。
• Application of copper(I) halides to modifying reactivity of polyhalomethanes and arenesulfonyl chlorides in free-radical addition. “Cross-halogenation” reaction
  作者：A. S. Dneprovskii、A. N. Kasatochkin、V. P. Boyarskii、A. A. Ermoshkin、A. A. Yakovlev

  DOI：10.1134/s1070428006080033

  日期：2006.8

  In the free-radical addition of a number of organohalogen reagents to cyclic alkenes and dienes in the presence of copper(I) halides the composition of the reaction products is governed by the stage of a fast halogen transfer from the copper derivative to the alkyl radical. Under these conditions in contrast to the free-radical addition reactions initiated by UV light or peroxide initiators the intramolecular rearrangements are suppressed, the stereoselectivity of the reaction changes, and also some adducts contain halogen atoms different from those present in the organohalogen reagent employed.
• The Fe⁰Promoted Addition of CCI₄, and CCI₃Br to Olefins
  作者：Franco Bellesia、Luca Forti、Franco Ghelfi、Ugo M. Pagnoni

  DOI：10.1080/00397919708003040

  日期：1997.3

  The radical addition of CCL(4) or CCl3Br to olefins is efficiently promoted by iron filings in N,N-dimethylformamide under mild conditions.
• Addition of Bromotrichloromethane and Tetrachloromethane to<i>cis</i>-Cyclooctene, Cyclohexene, and Norbornadiene in the Presence of Palladium(II) Complexes
  作者：A. S. Dneprovskii†、A. A. Ermoshkin、A. N. Kasatochkin、V. P. Boyarskii

  DOI：10.1023/b:rujo.0000003181.02370.cf

  日期：2003.7

  Addition of bromotrichloromethane and tetrachloromethane to alkenes in the presence of palladium(II) complexes begins with single-electron transfer from the palladium atom to polyhalomethane molecule, followed by fragmentation of the radical anion thus formed and generation of trichloromethyl radical. Halogen transfer to a carbon-centered radical arising from addition of trichloromethyl radical at the double bond occurs both from the polyhalomethane molecule and from halide palladium complex.