1-氯三十烷 | 62016-82-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 1-氯三十烷
• 中文别名: 1-氯代三十烷
• 英文名称: 1-chlorotriacontane
• 英文别名: Myricylchlorid；triacontyl chloride
• CAS: 62016-82-4
• 化学式: C₃₀H₆₁Cl
• 分子量: 457.267
• InChiKey: NSPRLRIWTSAZOP-UHFFFAOYSA-N

物化性质

• 熔点：
  64.0 to 67.0 °C
• 沸点：
  538.11°C (rough estimate)
• 密度：
  0.8835 (rough estimate)
• 溶解度：
  溶于甲苯
• 稳定性/保质期：
  远离氧化物。

计算性质

• 辛醇/水分配系数(LogP)：
  16.6
• 重原子数：
  31
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903199000

SDS

1-Chlorotriacontane Revision number: 5
SAFETY DATA SHEET

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Section 1. IDENTIFICATION
Product name: 1-Chlorotriacontane

Revision number: 5

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Section 2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Not classified
Not classified
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS Not classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols None
No signal word
Signal word
Hazard statements None
None
Precautionary statements:

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture: Substance
Components: 1-Chlorotriacontane
Percent: >85.0%(GC)
CAS Number: 62016-82-4
Synonyms: Triacontyl Chloride
Chemical Formula: C30H61Cl

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Section 4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact: Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion: Get medical advice/attention if you feel unwell. Rinse mouth.
Protection of first-aiders: A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

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Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical: generate poisonous fume.
1-Chlorotriacontane

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Section 5. FIRE-FIGHTING MEASURES
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

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Section 6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Handling is performed in a well ventilated place. Wear suitable protective equipment.
Technical measures:
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material: Comply with laws.

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Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust as possible so that workers should not be
Engineering controls:
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection: Protective gloves.
Eye protection: Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Solid
Form: Crystal- Powder
Colour: White - Almost white
Odour: No data available
pH: No data available
Melting point/freezing point:No data available
No data available
Boiling point/range:
Flash point: No data available
Flammability or explosive
limits:
No data available
Lower:
Upper: No data available
No data available
Relative density:
Solubility(ies):
No data available
[Water]
[Other solvents]
Toluene
Soluble:
1-Chlorotriacontane

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Section 10. STABILITY AND REACTIVITY
Chemical stability: Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride
products:

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Section 11. TOXICOLOGICAL INFORMATION
No data available
Acute Toxicity:
Skin corrosion/irritation: No data available
No data available
Serious eye
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC = No data available
NTP = No data available
No data available
Reproductive toxicity:

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Section 12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea: No data available
Algae: No data available
Persistence / degradability: No data available
Bioaccumulative No data available
potential(BCF):
Mobility in soil
Log Pow: No data available
No data available
Soil adsorption (Koc):
Henry's Law No data available
constant(PaM3/mol):

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Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

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Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
Not listed
UN-No:

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Section 15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.
1-Chlorotriacontane

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  1-氯三十烷 、 3-(吡啶-2-基)苯酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-(3-triacontyloxyphenyl)pyridine
  参考文献：
  名称：

  在石墨上具有长烷基链的有机金属铱配合物的有序阵列。

  摘要：

  制备配备长烷基链的铱（III）fac-三（2-苯基吡啶）fac- [Ir（ppy）3]络合物，以检查其在高度取向的热解石墨（HOPG）表面上形成有序阵列的能力。分子在1-苯基辛烷/ HOPG界面形成层状阵列。通过对STM图像的分析，可以得出结论，分子与被叉指的烷基链对齐。在滴入甲苯溶液后，在空气/ HOPG界面处也获得了类似的层状阵列。在分子水平上的层状结构导致长为几百纳米长的矩形二维晶域（纳米晶）。红外外反射光谱表明，吸附的烷基链在纳米级滑片中采用反之字形构象，尽管烷基的Z字形平面的方向是混合的。循环伏安法表明吸附的分子与底物之间的快速电子转移以及明显的分子间电子相互作用。已经发现，高温退火是制备大于几微米规模（微片）的有序组件的有效方法。由外消旋混合物制备的纳米级玻片的取向表现出明显的12倍对称性，而其旋光对映异构体则形成了具有6倍对称性的更多不规则结构域，这表明手性在分子水平和分子堆

  DOI：

  10.1002/chem.200600972
• 作为产物：
  描述：

  三十烷醇 在 五氯化磷 作用下， 生成 1-氯三十烷
  参考文献：
  名称：

  Chakravarti,D. et al., Journal of the Indian Chemical Society, 1964, vol. 41, p. 83 - 84

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING MODIFIED CELLULOSE FIBER, AND MODIFIED CELLULOSE FIBER
  申请人：Kao Corporation

  公开号：EP3808782A1

  公开（公告）日：2021-04-21

  The present invention relates to a method for producing modified cellulose fibers having cellulose I crystal structure, comprising: step A: introducing Substituent Group A to cellulose fibers via an ether bond in a solvent comprising water in the presence of a base, and step B: introducing Substituent Group B to cellulose fibers via an ether bond in a solvent comprising water in the presence of a base, wherein the method includes the steps A and B concurrently, or in the order of the step A and then the step B. The cellulose fibers of the present invention obtained by the method for production of the present invention have favorable dispersibility in a hydrophobic medium and a controlled increase in viscosity.

  本发明涉及一种生产具有纤维素I晶体结构的改性纤维素纤维的方法，包括：步骤A：在碱存在的情况下，在由水组成的溶剂中，通过醚键将取代基A引入纤维素纤维；步骤B：在碱存在的情况下，在由水组成的溶剂中，通过醚键将取代基B引入纤维素纤维，其中该方法包括同时进行的步骤A和步骤B，或按照先步骤A后步骤B的顺序进行的步骤A和步骤B。通过本发明的生产方法获得的本发明纤维素纤维在疏水介质中具有良好的分散性，粘度的增加也是可控的。
• PRECURSOR FOR CATALYST, PROCESS FOR PREPARING THE SAME AND ITS USE THEREOF
  申请人：Indian Oil Corporation Ltd

  公开号：EP2897965B1

  公开（公告）日：2020-10-07
• METHOD FOR PRODUCING MODIFIED CELLULOSE FIBER, AND MODIFIED CELLULOSE FIBER
  申请人：KAO CORPORATION

  公开号：US20210230795A1

  公开（公告）日：2021-07-29

  The present invention relates to a method for producing modified cellulose fibers having cellulose I crystal structure, comprising: step A: introducing Substituent Group A to cellulose fibers via an ether bond in a solvent comprising water in the presence of a base, and step B: introducing Substituent Group B to cellulose fibers via an ether bond in a solvent comprising water in the presence of a base, wherein the method includes the steps A and B concurrently, or in the order of the step A and then the step B. The cellulose fibers of the present invention obtained by the method for production of the present invention have favorable dispersibility in a hydrophobic medium and a controlled increase in viscosity.
• Ordered Arrays of Organometallic Iridium Complexes with Long Alkyl Chains on Graphite
  作者：Joe Otsuki、Tsubasa Tokimoto、Yuki Noda、Tomohiro Yano、Takeshi Hasegawa、Xiaoming Chen、Yoshio Okamoto

  DOI：10.1002/chem.200600972

  日期：2007.3.5

  Iridium(III) fac-tris(2-phenylpyridine) fac-[Ir(ppy)3] complexes equipped with long alkyl chains were prepared to examine their capability to form organized arrays on the surface of highly oriented pyrolytic graphite (HOPG). The molecules form lamellar arrays at the 1-phenyloctane/HOPG interface. From the analysis of the STM images, it was concluded that the molecules align with alkyl chains being

  制备配备长烷基链的铱（III）fac-三（2-苯基吡啶）fac- [Ir（ppy）3]络合物，以检查其在高度取向的热解石墨（HOPG）表面上形成有序阵列的能力。分子在1-苯基辛烷/ HOPG界面形成层状阵列。通过对STM图像的分析，可以得出结论，分子与被叉指的烷基链对齐。在滴入甲苯溶液后，在空气/ HOPG界面处也获得了类似的层状阵列。在分子水平上的层状结构导致长为几百纳米长的矩形二维晶域（纳米晶）。红外外反射光谱表明，吸附的烷基链在纳米级滑片中采用反之字形构象，尽管烷基的Z字形平面的方向是混合的。循环伏安法表明吸附的分子与底物之间的快速电子转移以及明显的分子间电子相互作用。已经发现，高温退火是制备大于几微米规模（微片）的有序组件的有效方法。由外消旋混合物制备的纳米级玻片的取向表现出明显的12倍对称性，而其旋光对映异构体则形成了具有6倍对称性的更多不规则结构域，这表明手性在分子水平和分子堆
• Chakravarti,D. et al., Journal of the Indian Chemical Society, 1964, vol. 41, p. 83 - 84
  作者：Chakravarti,D. et al.

  DOI：——

  日期：——