1-羟基-3,5,6,7,8-五甲氧基氧杂蒽酮 | 63504-29-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 中文名称: 1-羟基-3,5,6,7,8-五甲氧基氧杂蒽酮
• 英文名称: 1-hydroxy-3,5,6,7,8-pentamethoxyxanthone
• 英文别名: eustomin；8-hydroxy-1,2,3,4,6-pentamethoxyxanthen-9-one
• CAS: 63504-29-0
• 化学式: C₁₈H₁₈O₈
• 分子量: 362.336
• InChiKey: SVEPSJMWTARFFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  92.7
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1-羟基-3,5,6,7,8-五甲氧基氧杂蒽酮 、 乙酸酐 在 吡啶 作用下， 生成 Acetic acid 3,5,6,7,8-pentamethoxy-9-oxo-9H-xanthen-1-yl ester
  参考文献：
  名称：

  Centaurium littorale 的多氧化氧杂蒽酮

  摘要：

  摘要 两种非极性四氧化氧杂蒽酮（1,8-二羟基-3,5-二甲氧基氧杂蒽酮和 1-羟基-3,5,8-三甲氧基氧杂蒽酮）和两种六氧合氧杂蒽酮（1,8-二羟基-3,5,6,7 -四甲氧基氧杂蒽酮和 1-羟基-3,5,6,7,8-五甲氧基氧杂蒽酮）已从 Centaurium littorale 的根中分离出来。报告了这些氧杂蒽酮的分离和结构，并给出了 TLC 分析的详细信息。报告了两种六氧化氧杂蒽酮的 13 C NMR 和高分辨率 EIMS 光谱。审查了在 Centaurium Hill 属中发现的氧杂蒽酮。

  DOI：

  10.1016/s0031-9422(00)80677-9
• 作为产物：
  描述：

  1,2,3,4,6-pentamethoxy-8-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2S,3R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl]oxyxanthen-9-one 生成 1-羟基-3,5,6,7,8-五甲氧基氧杂蒽酮
  参考文献：
  名称：

  AGRAWAL, AMULAYA;SINGH, J., PHYTOCHEMISTRY, 27,(1988) N 11, C. 3692-3694

  摘要：

  DOI：

文献信息

• Xanthones fromChironia krebsii
  作者：Jean-luc Wolfender、Matthias Hamburger、Jerome D. Msonthi、Kurt Hostettmann

  DOI：10.1016/0031-9422(91)80080-k

  日期：1991.1

  From a dichloromethane extract of the aerial parts and from a methanolic root extract of Chironia krebsii, 11 1-hydroxyxanthones and six xanthone glycosides have been isolated. The glycosides 5-hydroxy-3-methoxy-1-O-primeverosylxanthone, 1-hydroxy-3-methoxy-5-O-primeverosylxanthone, 5-hydroxy-3-methoxy-1-O-beta-D-glucosylxanthone, 3,5,6,7,8-pentamethoxy-1-O-primeverosylxanthone are new natural products. Their structures were established by spectroscopic (UV, EIMS, D/CIMS, H-1 and C-13 NMR) and chemical methods.
• COATING FOR SUBSTRATE
  申请人：W. L. Gore & Associates, Inc.

  公开号：EP2950832A1

  公开（公告）日：2015-12-09
• US9272075B2
  申请人：——

  公开号：US9272075B2

  公开（公告）日：2016-03-01
• [EN] COATING FOR SUBSTRATE<br/>[FR] REVÊTEMENT POUR SUBSTRAT
  申请人：GORE & ASS

  公开号：WO2014118382A1

  公开（公告）日：2014-08-07

  There is provided inter alia a substrate with a surface having a hydrophilic coating comprising a cross-linked copolymer of components A and B, and optional components C and D; wherein component A comprises one or more C2-C16 hydrophilic monomers each bearing one or more alkene and/or alkyne groups; component B comprises one or more hydrophilic polymers each bearing two or more alkene and/or alkyne groups; component C, if present, comprises one or more beneficial agents each bearing one or more alkene or alkyne groups; and component D, if present, comprises one or more low molecular weight cross-linking agents each bearing two or more functional groups independently selected from thiol, alkene and alkyne groups; wherein the cross-linked copolymer is formed by radical polymerisation involving the alkene and/or alkyne groups of components A, B and C (if present) and involving the functional groups of component D (if present); wherein the hydrophilic coating optionally comprises component E which comprises one or more beneficial agents, wherein component E does not form a copolymer with components A, B, C (if present) and D (if present); and wherein the hydrophilic coating is covalently attached to the surface of the substrate.
• AGRAWAL, AMULAYA;SINGH, J., PHYTOCHEMISTRY, 27,(1988) N 11, C. 3692-3694
  作者：AGRAWAL, AMULAYA、SINGH, J.

  DOI：——

  日期：——