5-chlorosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone | 91398-46-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 5-chlorosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone
• 英文别名: 2-[2-[(5-chloro-2-hydroxyphenyl)methylidene]hydrazinyl]-4-methyl-1H-pyrimidin-6-one
• CAS: 91398-46-8
• 化学式: C₁₂H₁₁ClN₄O₂
• 分子量: 278.698
• InChiKey: KSZSITNXAWNXFX-UHFFFAOYSA-N

物化性质

• 沸点：
  451.8±55.0 °C(Predicted)
• 密度：
  1.46±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  86.1
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-chlorosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone 、 五氯化铌 以 氯仿 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF NIOBIUM(V) COMPLEXES WITH 6-METHYL-4-HYDROXYPYRIMIDINYL HYDRAZONES

  摘要：

  Niobium(V) complexes with 6-methyl-4-hydroxypyrimidinyl hydrazones have been synthesised and characterised by elemental analyses, conductivity measurements, spectral (IR, UV-Vis,H-1 NMR) and TG studies. The complexes have the composition [NbCl3L]. The ligand behaves as dibasic tridentate ONN donor.

  DOI：

  10.1081/sim-100002051

文献信息

• SYNTHESIS AND CHARACTERIZATION OF NIOBIUM(V) COMPLEXES WITH 6-METHYL-4-HYDROXYPYRIMIDINYL HYDRAZONES
  作者：H. S. Chabanur、V. K. Revankar、V. B. Mahale

  DOI：10.1081/sim-100002051

  日期：2001.2.28

  Niobium(V) complexes with 6-methyl-4-hydroxypyrimidinyl hydrazones have been synthesised and characterised by elemental analyses, conductivity measurements, spectral (IR, UV-Vis,H-1 NMR) and TG studies. The complexes have the composition [NbCl3L]. The ligand behaves as dibasic tridentate ONN donor.