cyclohexyl cyclohexenylamine | 172288-49-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: cyclohexyl cyclohexenylamine
• 英文别名: N-cyclohexylcyclohexen-1-amine
• CAS: 172288-49-2
• 化学式: C₁₂H₂₁N
• 分子量: 179.305
• InChiKey: YXTKJSIWWJBAKZ-UHFFFAOYSA-N

物化性质

• 沸点：
  294.1±10.0 °C(Predicted)
• 密度：
  0.93±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cyclohexyl cyclohexenylamine 、 alkaline earth salt of/the/ methylsulfuric acid 在 1.) EtMgX, 作用下， 生成 2-丙基环己酮
  参考文献：
  名称：

  Resolution of racemic ε-lactones

  摘要：

  Kinetic resolution of racemic epsilon-lactones by Pig Liver Esterase give optically active R (+) epsilon-lactones. When alkyl group is higher than propyl, Horse Liver Esterase leads to the destruction of the opposite enantiomer. Enantiomeric excess is easily evaluated by G.C. on a chiral stationary phase.

  DOI：

  10.1016/s0957-4166(00)86202-3

文献信息

• [EN] PROCESS FOR THE PRODUCTION OF HIGHLY PURE DICYCLOHEXYLAMINE FROM BY-PRODUCTS RESULTING FROM THE PRODUCTON OF CYCLOHEXYLAMINE<br/>[FR] PROCESSUS DE FABRICATION D'UNE DICYCLOHEXYLAMINE D'UNE GRANDE PURETÉ À PARTIR DE SOUS-PRODUITS DE LA FABRICATION DE CYCLOHEXYLAMINES
  申请人：DUSLO AS

  公开号：WO2012018310A1

  公开（公告）日：2012-02-09

  Title: Process for the production of highly pure dicyclohexylamine from by- products resulting from the production of cyclohexylamine Process for the production of highly pure dicyclohexylamine during the production of cyclohexylaminefrom aniline in a liquid phase on ruthenium catalyst on thealuminium carrier or coalconsists in that the concentrated dicyclohexylamine obtained by amultiple rectification of the reaction mixture is again catalytically hydrogenated on the metal Ru,Pd,Ptor Rhcatalyston the carrier, at the temperature between 80 and 240°Cand pressure between 0.1 and 9.0 MPa,in the same or in other hydrogenation device, whereby above 99.0% w/wconcentrated dicyclohexylamine is obtained.

  生产高纯度二环己胺的方法，从生产环己胺的副产物中得到。在液相中，通过在铝载体或煤上的钌催化剂上，从苯胺中生产环己胺的过程中生产高纯度二环己胺的方法包括以下步骤：通过对反应混合物进行多次精馏获得浓缩的二环己胺，然后再次在金属钌、钯、铂或铑催化剂载体上进行催化氢化，温度在80至240°C之间，压力在0.1至9.0 MPa之间，在相同或其他氢化装置中进行，从而得到超过99.0%的重量浓缩的二环己胺。
• Synthesis and some properties of phosphorus-substituted azomethines
  作者：M. M. Kabachnik、Z. S. Novikova、I. A. Chadnaya、A. A. Borisenko、I. P. Beletskaya

  DOI：10.1007/bf02498961

  日期：1998.2

  A series of phosphorus(III)-substituted azomethines and enamines were synthesized by the reaction of lithium salts of aldimines and ketimines with derivatives of phosphorus(III) acids. Some properties of the compounds synthesized were studied.
• Verfahren zur Herstellung von Polychloropren mit hohem Molekulargewicht und dessen Verwendung als Klebstoffrohstoff
  申请人：BAYER AG

  公开号：EP0043041B1

  公开（公告）日：1984-05-23
• PROCESS FOR THE PRODUCTION OF HIGHLY PURE DICYCLOHEXYLAMINE FROM BY-PRODUCTS RESULTING FROM THE PRODUCTON OF CYCLOHEXYLAMINE
  申请人：Duslo, A.S.

  公开号：EP2601170A1

  公开（公告）日：2013-06-12
• COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENTS, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160343950A1

  公开（公告）日：2016-11-24

  An organic electroluminescence device having higher performance, in particular exhibiting a better driving voltage and a better external quantum efficiency, while having an extended lifetime; and an electronic equipment provided with the organic electroluminescence device are provided. In addition, a compound for realizing the same device and equipment is provided. Specifically, a compound having a specific structure having a triphenylene skeleton; an organic electroluminescence device using the compound; and an electronic equipment provided with the organic electroluminescence device were provided.