[n-BuSn(methylthiomethyl)3] | 375842-85-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: [n-BuSn(methylthiomethyl)3]
• CAS: 375842-85-6
• 化学式: C₁₀H₂₄S₃Sn
• 分子量: 359.209
• InChiKey: RJFLJRUXNHGQLT-UHFFFAOYSA-N

物化性质

• 沸点：
  340.2±52.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.66
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tris(acetonitrile)tricarbonylmolybdenum(0) 、 [n-BuSn(methylthiomethyl)3] 以 四氢呋喃 为溶剂， 以66%的产率得到[(n-BuSn(methylthiomethyl)3)Mo(CO)3]
  参考文献：
  名称：

  Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands [ⁿBuSn(2-pyridyl)₃] and [RSn(methylthiomethyl)₃]

  摘要：

  The ligands [(BuSn)-Bu-n(2-pyridyl)(3)] and [RSn(methylthiomethyl)(3)] (R = Bu-n, Me) have been prepared in a one-pot, two-step procedure from the corresponding alkyltin trichloride and 2-pyridyl or methylthiomethyl carbanions. The reaction of these ligands with [M(CO)(3)(NCR)(3)] (M = Mo, W) afforded the tricarbonyl compounds [{(BuSn)-Bu-n(2-pyridyl)(3)}M(CO)(3)] and [{RSn(methylthiomethyl)(3)}M(CO)(3)]. In addition to IR and NMR characterization, the structure of three of these new complexes was determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om0104722
• 作为产物：
  描述：

  二甲基硫 、 丁基三氯化锡 在 n-BuLi 、 NaO-t-Bu 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 生成 [n-BuSn(methylthiomethyl)3]
  参考文献：
  名称：

  Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands [ⁿBuSn(2-pyridyl)₃] and [RSn(methylthiomethyl)₃]

  摘要：

  The ligands [(BuSn)-Bu-n(2-pyridyl)(3)] and [RSn(methylthiomethyl)(3)] (R = Bu-n, Me) have been prepared in a one-pot, two-step procedure from the corresponding alkyltin trichloride and 2-pyridyl or methylthiomethyl carbanions. The reaction of these ligands with [M(CO)(3)(NCR)(3)] (M = Mo, W) afforded the tricarbonyl compounds [{(BuSn)-Bu-n(2-pyridyl)(3)}M(CO)(3)] and [{RSn(methylthiomethyl)(3)}M(CO)(3)]. In addition to IR and NMR characterization, the structure of three of these new complexes was determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om0104722