2-Methyl-4-propargyl-phenol | 1807-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-Methyl-4-propargyl-phenol
• 英文别名: 2-Methyl-4-prop-2-ynylphenol
• CAS: 1807-45-0
• 化学式: C₁₀H₁₀O
• 分子量: 146.189
• InChiKey: RUJADCHKJWPPMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Ethyl<2-methylphenylcarbonat> 在 氯化锑(V) 、 氨 作用下， 以 苯 为溶剂， 生成 2-Methyl-4-propargyl-phenol
  参考文献：
  名称：

  Claisen Rearrangement of Allyl 2-Alkylphenyl Ethers¹

  摘要：

  DOI：

  10.1021/jo01015a019

文献信息

• Thermoplastic silicone-polyphenylene ether block copolymers
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0540273A1

  公开（公告）日：1993-05-05

  An oxidative coupling method is provided using a diorganophenol such as 2,6-xylenol and a silicone macromer having terminal phenol groups such as the hydrosilylation reaction product of eugenol. Thermoplastic polymeric products such as silicone-polyphenylene ether block copolymers, which can be flame retardant, as well as blends thereof with thermoplastic polymers, such as polyphenylene ether, also are provided.

  提供了一种氧化偶联方法，使用 2,6-二羟基苯酚（如 2,6-二甲基苯酚）和具有末端苯酚基团（如丁香酚的氢硅烷化反应产物）的有机硅大分子。此外，还提供了可阻燃的有机硅-聚苯醚嵌段共聚物等热塑性聚合物产品，以及它们与聚苯醚等热塑性聚合物的混合物。
• Transparent and high-heat polycarbonate-polysiloxane copolymers and transparent blends with polycarbonate and a process for preparing same
  申请人：——

  公开号：US20040220330A1

  公开（公告）日：2004-11-04

  A method is provided for making siloxane polycarbonate copolymers and blends of other polycarbonates with such copolymers wherein the copolymers and blends have excellent transparency and physical characteristic.

  提供了一种制造硅氧烷聚碳酸酯共聚物和其他聚碳酸酯与这种共聚物的混合物的方法，其中共聚物和混合物具有优异的透明度和物理特性。
• Highly ductile polycarbonate composition having a metallic-flake appearance
  申请人：Ermi D. Brett

  公开号：US20050261396A1

  公开（公告）日：2005-11-24

  A polycarbonate composition comprising a polycarbonate-polysiloxane copolymer resin and a glass flake additive wherein the polycarbonate-polysiloxane copolymer resin has a silicone content in the range of from 3.5 weight % to 7 weight % based on the total weight of the polycarbonate composition and wherein the polycarbonate-polysiloxane copolymer has a haze of less than 10% and wherein the glass flake additive is present in the range of 0.025 weight % to 0.70 weight % based on the total weight of the polycarbonate composition.

  一种聚碳酸酯组合物，包括聚碳酸酯-聚硅氧烷共聚物树脂和玻璃鳞片添加剂，其中聚碳酸酯-聚硅氧烷共聚物树脂的硅含量范围为 3.5 重量％至 7 重量％（以聚碳酸酯组合物的总重量为基准），聚碳酸酯-聚硅氧烷共聚物的雾度小于 10％，玻璃鳞片添加剂的含量范围为 0.025 重量％至 0.70 重量％（以聚碳酸酯组合物的总重量为基准）。
• Polycarbonates with fluoroalkylene carbonate end groups
  申请人：Davis Charles Gary

  公开号：US20060135737A1

  公开（公告）日：2006-06-22

  Polycarbonate compositions having an aromatic polycarbonate resin with 90% or greater fluoroalkylene carbonate end-groups are formed from a partially fluorinated alcohol or a partially fluorinated polymeric alcohol, and a bisphenol and a carbonate source using melt or interfacial polymerization methods. Copolymers and blends with a variety of other bisphenols and other thermoplastics are also described. The polycarbonate compositions show high water contact angles, fluorine enrichment on the surface layer of molded articles, and good flame retardant properties and are useful in a variety of applications including medical, automotive, telecommunication and weatherable applications.

  聚碳酸酯组合物具有 90% 或以上氟亚烃碳酸酯端基的芳香族聚碳酸酯树脂，由部分氟化醇或部分氟化聚合醇、双酚和碳酸酯源通过熔融或界面聚合方法形成。此外，还介绍了与其他各种双酚和其他热塑性塑料的共聚物和共混物。这些聚碳酸酯组合物具有较高的水接触角，在模塑制品的表层富含氟，以及良好的阻燃性能，可用于多种用途，包括医疗、汽车、电信和耐候性应用。
• METHOD FOR MAKING SILOXANE COPOLYCARBONATES
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1272543A1

  公开（公告）日：2003-01-08