2-(4-甲氧基苯基)-3,3-二苯基丙烯腈 | 16143-89-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 2-(4-甲氧基苯基)-3,3-二苯基丙烯腈
• 英文名称: 1-cyano-1-(p-methoxyphenyl)-2,2-diphenylethylene
• 英文别名: 2-(4-methoxy-phenyl)-3,3-diphenyl-acrylonitrile；3.3-Diphenyl-2-(4-methoxy-phenyl)-acrylsaeure-nitril；2-(4-Methoxy-phenyl)-3,3-diphenyl-acrylonitril；3,3-Diphenyl-2-(4-methoxyphenyl)-acrylnitril；3,3-Diphenyl-2(4-methoxyphenyl)acrylnitril；ACRYLONITRILE, 2-(p-METHOXYPHENYL)-3,3-DIPHENYL-；2-(4-methoxyphenyl)-3,3-diphenylprop-2-enenitrile
• CAS: 16143-89-8
• 化学式: C₂₂H₁₇NO
• 分子量: 311.383
• InChiKey: KPCGDUZWYDQIFG-UHFFFAOYSA-N

物化性质

• 熔点：
  149 °C
• 沸点：
  451.42°C (rough estimate)
• 密度：
  1.1292 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2926909090

反应信息

• 作为反应物：
  描述：

  2-(4-甲氧基苯基)-3,3-二苯基丙烯腈 生成 2-(4-methoxy-phenyl)-3,3-diphenyl-acrylic acid amide
  参考文献：
  名称：

  120.一些αββ -triarylacrylonitriles，αββ -triarylacrylic酸及其衍生物

  摘要：

  DOI：

  10.1039/jr9470000641
• 作为产物：
  描述：

  二苯甲酮 、 对甲氧基苯乙腈 在 乙醚 、 sodium amide 作用下， 生成 2-(4-甲氧基苯基)-3,3-二苯基丙烯腈
  参考文献：
  名称：

  120.一些αββ -triarylacrylonitriles，αββ -triarylacrylic酸及其衍生物

  摘要：

  DOI：

  10.1039/jr9470000641

文献信息

• ipso Substitution by cyanide anion in photolysis of 1-(p-methoxyphenyl)vinyl bromides
  作者：Tsugio Kitamura、Mahito Murakami、Shinjiro Kobayashi、Hiroshi Taniguchi

  DOI：10.1016/s0040-4039(00)83906-4

  日期：1986.1

  Photolysis of 1-(p-methoxyphenyl)vinyl bromides in the presence of cyanide anion provided 1-cyano-1-(p-cyanophenyl)ethylenes and 3,10-dicyanophenanthrenes . These were proven to be formed via a vinyl cation.

  1-（对甲氧基苯基）乙烯基溴化物在氰化物阴离子存在下的光解提供了1-氰基-1-（对氰基苯基）乙烯和3,10-二氰基菲。这些被证明是通过乙烯基阳离子形成的。
• Polymer poly (triphenylacrylonitrite) and synthesis thereof
  申请人：THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US10941243B2

  公开（公告）日：2021-03-09

  A method is directed to synthesis of poly(triphenylacrylonitrite)s (PTPANs) comprising polycoupling dibromoarenes, internal diynes, and potassium ferrocyanide, resulting in polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide; and producing poly(triphenylacrylonitrite)s (PTPANs) by catalysis of the polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide with palladium acetate and sodium bicarbonate, wherein the catalysis is allowed to proceed in dimethylacetamide under nitrogen at a prescribed temperature for a prescribed time. Further, poly(triphenylacrylonitrite)s (PTPANs) is a polymer and comprises a backbone structure of wherein x and y are integers; wherein each R is independently selected from the group consisting of and wherein each R′ is independently selected from the group consisting of

  一种合成聚(三苯基丙烯腈)(PTPANs)的方法，包括将二溴烯烃、内二炔烃和亚铁氰化钾进行聚偶联，得到聚偶联二溴烯烃、内二炔烃和亚铁氰化钾；用乙酸钯和碳酸氢钠催化多偶联二溴烯烃、内二炔烃和亚铁氰化钾，生成聚(三苯基丙烯酰亚胺)(PTPANs)，其中催化在二甲基乙酰胺中，在氮气下，在规定的温度下进行，在规定的时间内完成。此外，聚(三苯基丙烯腈)s (PTPANs)是一种聚合物，其骨架结构为 其中 x 和 y 为整数； 其中每个 R 独立选自以下组成的组 和 其中每个 R′都独立选自以下组成的组
• POLYMER POLY (TRIPHENYLACRYLONITRITE) AND SYNTHESIS THEREOF
  申请人：THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US20190233575A1

  公开（公告）日：2019-08-01

  A method is directed to synthesis of poly(triphenylacrylonitrite)s (PTPANs) comprising polycoupling dibromoarenes, internal diynes, and potassium ferrocyanide, resulting in polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide; and producing poly(triphenylacrylonitrite)s (PTPANs) by catalysis of the polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide with palladium acetate and sodium bicarbonate, wherein the catalysis is allowed to proceed in dimethylacetamide under nitrogen at a prescribed temperature for a prescribed time. Further, poly(triphenylacrylonitrite)s (PTPANs) is a polymer and comprises a backbone structure of wherein x and y are integers; wherein each R is independently selected from the group consisting of and wherein each R′ is independently selected from the group consisting of
• [EN] POLYMER POLY (TRIPHENYLACRYLONITRITE) AND SYNTHESIS THEREOF<br/>[FR] POLY(TRIPHÉNYLACRYLONITRITE) POLYMÈRE ET SYNTHÈSE CORRESPONDANTE
  申请人：UNIV HONG KONG SCI & TECH

  公开号：WO2018068688A1

  公开（公告）日：2018-04-19

  A method is directed to synthesis of poly (triphenylacrylonitrite) s (PTPANs) comprisingpolycoupling dibromoarenes, internal diynes, and potassium ferrocyanide, resulting in polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide； and producing poly (triphenylacrylonitrite) s (PTPANs) by catalysis of the polycoupled dibromoarenes, internal diynes, and potassium ferrocyanide with palladium acetate and sodium bicarbonate, wherein the catalysis is allowed to proceed in dimethylacetamide under nitrogen at a prescribed temperature for a prescribed time. Further, poly (triphenylacrylonitrite) s (PTPANs) is a polymer and comprises a backbone structure of P1a-d/2a-b/3, wherein x and y are integers; wherein each R is independently selected from the group consisting of 1a, 1b, 1c, and 1d; and wherein each R' is independently selected from the group consisting of 2a and 2b
• 120. Some αββ-triarylacrylonitriles, αββ-triarylacrylic acids, and their derivatives
  作者：Ng. Ph. Buu-hoï、Jean Lecocq

  DOI：10.1039/jr9470000641

  日期：——