zirconium bis(triethanolaminate) | 151767-62-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: zirconium bis(triethanolaminate)
• 英文别名: Zirconium(4+) bis{2,2'-[(2-hydroxyethyl)azanediyl]di(ethan-1-olate)}；2-[2-hydroxyethyl(2-oxidoethyl)amino]ethanolate;zirconium(4+)
• CAS: 151767-62-3
• 化学式: C₁₂H₂₆N₂O₆Zr
• 分子量: 385.572
• InChiKey: KNJMMQVYGXOKFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -6.0
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  139
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  zirconium bis(triethanolaminate) 以 苯 为溶剂， 生成
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF HETEROBIMETALLIC ALKOXIDE TRIETHANOLAMINATE DERIVATIVES OF ZIRCONIUM

  摘要：

  Novel heterobimetallic isopropoxide derivatives have been prepared by the 1:2 molar reactions of Zr{(OCH2CH2)(2) N(CH2CH2OH)}(2) zwith Al(OPr-i)(3) or Nb(OPr-i)(5) in benzene under refluxing conditions. The reactions of heterobimetallic alkoxide-triethanolaminate derivatives with chelating ligands such as acetylacetone or methoxyethanol have been investigated. All of these derivatives have been characterized by elemental analyses, molecular weight measurements and spectroscopic [IR, NMR (H-1, Al-27)] studies.

  DOI：

  10.1081/sim-100002225
• 作为产物：
  描述：

  异丙醇锆(IV) 、 三乙醇胺 以 苯 为溶剂， 以97%的产率得到zirconium bis(triethanolaminate)
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF HETEROBIMETALLIC ALKOXIDE TRIETHANOLAMINATE DERIVATIVES OF ZIRCONIUM

  摘要：

  Novel heterobimetallic isopropoxide derivatives have been prepared by the 1:2 molar reactions of Zr{(OCH2CH2)(2) N(CH2CH2OH)}(2) zwith Al(OPr-i)(3) or Nb(OPr-i)(5) in benzene under refluxing conditions. The reactions of heterobimetallic alkoxide-triethanolaminate derivatives with chelating ligands such as acetylacetone or methoxyethanol have been investigated. All of these derivatives have been characterized by elemental analyses, molecular weight measurements and spectroscopic [IR, NMR (H-1, Al-27)] studies.

  DOI：

  10.1081/sim-100002225

文献信息

• SYNTHESIS AND CHARACTERIZATION OF HETEROBIMETALLIC ALKOXIDE TRIETHANOLAMINATE DERIVATIVES OF ZIRCONIUM
  作者：Maneesh K. Sharma、Anirudh Singh、Ram C. Mehrotra

  DOI：10.1081/sim-100002225

  日期：2001.3.31

  Novel heterobimetallic isopropoxide derivatives have been prepared by the 1:2 molar reactions of Zr(OCH2CH2)(2) N(CH2CH2OH)}(2) zwith Al(OPr-i)(3) or Nb(OPr-i)(5) in benzene under refluxing conditions. The reactions of heterobimetallic alkoxide-triethanolaminate derivatives with chelating ligands such as acetylacetone or methoxyethanol have been investigated. All of these derivatives have been characterized by elemental analyses, molecular weight measurements and spectroscopic [IR, NMR (H-1, Al-27)] studies.