(Z)-3,3,5-trimethylcyclohexanone oxime | 110828-84-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Z)-3,3,5-trimethylcyclohexanone oxime
• 英文别名: Isophoron-oxim；3,3,5-Trimethylcyclohexanon-oxim；(NZ)-N-(3,3,5-trimethylcyclohexylidene)hydroxylamine
• CAS: 110828-84-7
• 化学式: C₉H₁₇NO
• 分子量: 155.24
• InChiKey: SBIKADHZIPDOHC-NTMALXAHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 (Z)-3,3,5-trimethylcyclohexanone oxime 、 二甲胺 以 乙醇 为溶剂， 生成 (E)-2-dimethylaminomethyl-3,5,5-trimethylcyclohexanone oxime hydrochloride 、 (Z)-2-dimethylaminomethyl-3,3,5-trimethylcyclohexanone oxime hydrochloride
  参考文献：
  名称：

  Mannich Condensation of 3,3,5-Trimethylcyclohexanone and Its Oxime

  摘要：

  3,3,5-三甲基环己酮与多聚甲醛和二甲胺或盐酸苄胺的曼尼希缩合涉及初始酮中的两个活化亚甲基，得到具有平位氨甲基取代基的化合物。主要异构体是通过在空间位阻较小的碳原子上加成形成的。同样，3,3,5-三甲基环己酮肟的E和Z异构体的曼尼希缩合在两个亚甲基上发生反应，并且氨甲基片段的加成优先发生在更靠近肟羟基的亚甲基上。

  DOI：

  10.1007/s11178-006-0045-5
• 作为产物：
  描述：

  3,3,5-三甲基环己酮 在 羟胺 作用下， 生成 (Z)-3,3,5-trimethylcyclohexanone oxime 、 (E)-3,3,5-trimethylcyclohexanone oxime
  参考文献：
  名称：

  Mannich Condensation of 3,3,5-Trimethylcyclohexanone and Its Oxime

  摘要：

  3,3,5-三甲基环己酮与多聚甲醛和二甲胺或盐酸苄胺的曼尼希缩合涉及初始酮中的两个活化亚甲基，得到具有平位氨甲基取代基的化合物。主要异构体是通过在空间位阻较小的碳原子上加成形成的。同样，3,3,5-三甲基环己酮肟的E和Z异构体的曼尼希缩合在两个亚甲基上发生反应，并且氨甲基片段的加成优先发生在更靠近肟羟基的亚甲基上。

  DOI：

  10.1007/s11178-006-0045-5

文献信息

• Curable photochromic composition including a segmented polymer
  申请人：Transitions Optical, Ltd.

  公开号：US11525027B2

  公开（公告）日：2022-12-13

  The present invention relates to a curable photochromic composition that includes: (a) a photochromic compound; and (b) a segmented polymer that includes active hydrogen groups, at least one first segment, and at least one second segment, in which, (i) each first segment independently includes a (meth)acrylic polymer segment, and (ii) each second segment independently includes at least one of, a polycarbonate segment, a polyester segment, a polyether segment, a polyurethane segment, and combinations of two or more thereof. The curable photochromic composition further includes (c) a curing agent having reactive functional groups that are reactive with the active hydrogen groups of the segmented polymer (a), in which the curing agent includes at least one of, a polyisocyanate, a polyisothiocyanate, and an aminoplast. The present invention also relates to photochromic articles that include at least one layer formed from the curable photochromic composition of the present invention.

  本发明涉及一种可固化的光致变色组合物，该组合物包括(a) 光致变色化合物；和 (b) 包括活性氢基、至少一个第一段和至少一个第二段的分段聚合物，其中，(i) 每个第一段独立地包括（甲基）丙烯酸聚合物段，和 (ii) 每个第二段独立地包括聚碳酸酯段、聚酯段、聚醚段、聚氨酯段中的至少一种，以及其中两种或两种以上的组合。可固化的光致变色组合物还包括(c)具有与分段聚合物(a)的活性氢基反应的活性官能团的固化剂，其中固化剂包括多异氰酸酯、多异硫氰酸盐和氨基树脂中的至少一种。本发明还涉及光致变色物品，该物品包括至少一层由本发明的可固化光致变色组合物形成的层。
• Thermosetting compositions containing hydroxy functional polymers prepared by atom transfer radical polymerization
  申请人：——

  公开号：US20020012751A1

  公开（公告）日：2002-01-31

  A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) capped polyisocyanate crosslinking agent, e.g., a trimer of 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane capped with e-caprolactam or 1H-2,5-dimethyl pyrazole, and (b) hydroxy functional polymer, is described. The hydroxy functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.

  本文介绍了一种热固性组合物，该组合物是一种可共同反应的固体微粒混合物，其中包含 (a) 封端多异氰酸酯交联剂，例如用 e-己内酰胺或 1H-2,5-二甲基吡唑封端的 1-异氰酸酯-3,3,5-三甲基-5-异氰酸基甲基环己烷三聚体，以及 (b) 羟基功能聚合物。羟基功能聚合物是通过原子转移自由基聚合法制备的，具有明确的聚合物链结构和小于 2.5 的多分散指数。本发明的热固性组合物可用作粉末涂料组合物。
• CURABLE PHOTOCHROMIC COMPOSITION INCLUDING A SEGMENTED POLYMER
  申请人：Transitions Optical, Ltd.

  公开号：EP3665239A1

  公开（公告）日：2020-06-17
• PHOTOCHROMIC ARTICLE
  申请人：Transitions Optical, Ltd.

  公开号：EP3877433A1

  公开（公告）日：2021-09-15
• POLYMER COMPOSITIONS CONTAINING MECHANOCHROMIC POLYMERS
  申请人：PPG INDUSTRIES OHIO, INC.

  公开号：US20130274412A1

  公开（公告）日：2013-10-17

  The present invention relates to a polymer composition that includes a polymer having at least one polymer segment represented by the following Formula (I), With reference to Formula (I): M independently for each w is a residue of a monomer; φ is a residue of a mechanochromic compound having at least two reactive groups that are each independently bonded to one monomer residue M; w, independently for each z, is an integer of at least 1; and z is an integer of at least 2. The mechanochromic compound is selected from at least one of the following, (a) a spirooxazine compound represented by the following Formula (II), and (b) an indenonaphthopyran represented by the following Formula (III),