thiophosphoric acid O,O'-dimethyl ester-O''-p-tolyl ester | 4901-37-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: thiophosphoric acid O,O'-dimethyl ester-O''-p-tolyl ester
• 英文别名: Thiophosphorsaeure-O,O'-dimethylester-O''-p-tolylester；Thiophosphorsaeure-O,O-dimethy-O-(4-methylphenyl)-ester；O,O-Dimethyl-O-(4-methylphenyl)-thiophosphorsaeure；O,O-Dimethyl-O-(4-methyl-phenyl)-thiophosphat；O,O-Dimethyl-O-(p-kresyl)-thiophosphat；Phosphorothioic acid, O,O-dimethyl O-p-tolyl ester；dimethoxy-(4-methylphenoxy)-sulfanylidene-λ5-phosphane
• CAS: 4901-37-5
• 化学式: C₉H₁₃O₃PS
• 分子量: 232.24
• InChiKey: KOZKFPKNGBHIMU-UHFFFAOYSA-N

物化性质

• 沸点：
  272.2±33.0 °C(Predicted)
• 密度：
  1.278 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  thiophosphoric acid O,O'-dimethyl ester-O''-p-tolyl ester 在 /BRN= 956566/ 作用下， 以 丙酮 为溶剂， 生成 Tetramethylammonium-O-methyl-O-(p-kresyl)-thiophosphat
  参考文献：
  名称：

  Jentzsch,R. et al., Journal fur praktische Chemie (Leipzig 1954), 1975, vol. 317, p. 721 - 732

  摘要：

  DOI：
• 作为产物：
  描述：

  p-tolyl phosphorodichloridothionate 在 甲醇 作用下， 生成 thiophosphoric acid O,O'-dimethyl ester-O''-p-tolyl ester
  参考文献：
  名称：

  Method for the manufacture of o-aryl o, o-di-(lower-alkyl) phosphorothioates

  摘要：

  公开号：

  US02887505A1

文献信息

• EMISSIVE SENSORS AND DEVICES INCORPORATING THESE SENSORS
  申请人：Swager Timothy M.

  公开号：US20110142717A1

  公开（公告）日：2011-06-16

  The present invention generally relates to luminescent and/or optically absorbing compositions and/or precursors to those compositions, including solid films incorporating these compositions/precursors, exhibiting increased luminescent lifetimes, quantum yields, enhanced stabilities and/or amplified emissions. The present invention also relates to sensors and methods for sensing analytes through luminescent and/or optically absorbing properties of these compositions and/or precursors. Examples of analytes detectable by the invention include electrophiles, alkylating agents, thionyl halides, and phosphate ester groups including phosphoryl halides, cyanides and thioates such as those found in certain chemical warfare agents. The present invention additionally relates to devices and methods for amplifying emissions, such as those produced using the above-described compositions and/or precursors, by incorporating the composition and/or precursor within a polymer having an energy migration pathway. In some cases, the compositions and/or precursors thereof include a compound capable of undergoing a cyclization reaction.
• Jentzsch,R. et al., Journal fur praktische Chemie (Leipzig 1954), 1975, vol. 317, p. 721 - 732
  作者：Jentzsch,R. et al.

  DOI：——

  日期：——
• Method for the manufacture of o-aryl o, o-di-(lower-alkyl) phosphorothioates
  申请人：DOW CHEMICAL CO

  公开号：US02887505A1

  公开（公告）日：1959-05-19