2,6-dimethyl-2-hydroxy-1,2,3,4-tetrahydronaphthalene | 127780-24-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 2,6-dimethyl-2-hydroxy-1,2,3,4-tetrahydronaphthalene
• CAS: 127780-24-9
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: VVWHQMROLVOPDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.23
• 重原子数：
  13.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  2,6-二甲基萘 在 TMPPMnCl sodium tetrahydroborate 、 氧气 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 1.0h， 以14.3%的产率得到3t,7-dimethyl-1r,3c-dihydroxy-1,2,3,4-tetrahydronaphthalene
  参考文献：
  名称：

  Oxygen-manganese porphyrinate-sodium borohydride system for oxidizing aromatic hydrocarbons

  摘要：

  In the presence of sodium borohydride as reducing agent, porphyrin complexes of manganese catalyze the oxidation of 2,6-dimethylnaphthalene by molecular oxygen, resulting in a mixture of polyoxidized tetralin derivatives, among which products containing 1,3-diol, epoxyalcoholic, and beta-hydroxyketonic groupings predominate. The nature of the components of the oxidizing system has a substantial influence on the ratio of products and the rate of oxidation.

  DOI：

  10.1007/bf00962391

文献信息

• Vasil'eva, L. L.; Lukasheva, E. A.; Solov'eva, A. B., Russian Journal of Physical Chemistry, 1990, vol. 64, # 2, p. 282 - 283
  作者：Vasil'eva, L. L.、Lukasheva, E. A.、Solov'eva, A. B.、Pivnitskii, K. K.

  DOI：——

  日期：——
• Oxygen-manganese porphyrinate-sodium borohydride system for oxidizing aromatic hydrocarbons
  作者：L. L. Vasil'eva、E. A. Lukashova、A. B. Solov'eva、K. K. Pivnitskii

  DOI：10.1007/bf00962391

  日期：1990.6

  In the presence of sodium borohydride as reducing agent, porphyrin complexes of manganese catalyze the oxidation of 2,6-dimethylnaphthalene by molecular oxygen, resulting in a mixture of polyoxidized tetralin derivatives, among which products containing 1,3-diol, epoxyalcoholic, and beta-hydroxyketonic groupings predominate. The nature of the components of the oxidizing system has a substantial influence on the ratio of products and the rate of oxidation.