4-nitroso-N-methyl-N,N-diphenylamine | 53158-79-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-nitroso-N-methyl-N,N-diphenylamine
• 英文别名: methyl-(4-nitroso-phenyl)-phenyl-amine；Methyl-(4-nitroso-phenyl)-phenyl-amin；N-Methyl-N-phenyl-4-nitroso-anilin；4-Nitroso-N-methyl-diphenylamin；(Methyl-phenyl-p-nitrosophenyl)-amin；4-nitroso-N-methyl-N,N-di-phenylamine；N-methyl-4-nitroso-N-phenylaniline
• CAS: 53158-79-5
• 化学式: C₁₃H₁₂N₂O
• 分子量: 212.251
• InChiKey: AZNGSKRANIVLTQ-UHFFFAOYSA-N

物化性质

• 熔点：
  44 °C
• 沸点：
  363.2±25.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  32.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-Hydroxynaphtho<2,1-d>-1,3-oxathiolone-2 、 4-nitroso-N-methyl-N,N-diphenylamine 以 溶剂黄146 为溶剂， 反应 0.17h， 以60%的产率得到9-N-Methyl-N-phenylaminobenzophenothiazin-5-one
  参考文献：
  名称：

  杂环奎宁胺的化学。6.苯并[a]吩噻嗪-5-酮与芳族胺的直接胺化

  摘要：

  DOI：

  10.1007/bf00505896
• 作为产物：
  描述：

  N-甲基二苯胺 在 盐酸 、 水 、 sodium nitrite 作用下， 生成 4-nitroso-N-methyl-N,N-diphenylamine
  参考文献：
  名称：

  Cloez, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1897, vol. 124, p. 898

  摘要：

  DOI：

文献信息

• COMPOUNDS AND ORGANIC LIGHT EMITTING DIODE USING THE SAME
  申请人：Jeon Byung-Sun

  公开号：US20100065828A1

  公开（公告）日：2010-03-18

  Disclosed are new compounds and an organic light emitting diode using the same. The organic light emitting diode using the new compound according to the present invention exhibits excellent characteristics in terms of actuating voltage, light efficiency, and lifespan.

  揭示了新化合物以及使用这些化合物的有机发光二极管。根据本发明的新化合物制成的有机发光二极管在驱动电压、光效率和寿命方面表现出优异的特性。
• AFANASEVA, G. B.;VYSOKOV, V. I.;CHUPAXIN, O. N.;UFIMTSEVA, I. S., XIMIYA GETEROTSIKL. SOEDIN., 1985, N 1, 49-52
  作者：AFANASEVA, G. B.、VYSOKOV, V. I.、CHUPAXIN, O. N.、UFIMTSEVA, I. S.

  DOI：——

  日期：——
• Compound And Organic Light Emitting Device Using The Same
  申请人：Cho Dong Wook

  公开号：US20080008907A1

  公开（公告）日：2008-01-10

  Disclosed is an organic light emitting device. The organic light emitting device comprises a first electrode, organic material layer(s) comprising a light emitting layer, and a second electrode. The first electrode, the organic material layer(s), and the second electrode form layered structure and at least one layer of the organic material layer(s) include the compound of Formula 1 or the compound of Formula 1 into which a thermosetting or photo-crosslinkable functional group is introduced.
• Compound and Organic Light Emitting Device Using the Same
  申请人：Cho Wook Dong

  公开号：US20080303414A1

  公开（公告）日：2008-12-11

  Disclosed is an organic light emitting device. The organic light emitting device comprises a first electrode, organic material layer(s) comprising a light emitting layer, and a second electrode. The first electrode, the organic material layer(s), and the second electrode form layered structure and at least one layer of the organic material layer(s) include the compound of Formula 1 or the compound of Formula 1 into which a thermosetting or photo-crosslinkable functional group is introduced.
• NEW COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：Hong Sung-Kil

  公开号：US20110127495A1

  公开（公告）日：2011-06-02

  The present invention provides a novel compound that is capable of largely improving life span, efficiency, electrochemical stability and thermal stability of the organic light emitting device, and an organic light emitting device in which said compound is included in an organic compound layer.