2-(β-t-Butylallyl)-phenol | 92035-88-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(β-t-Butylallyl)-phenol
• 英文别名: 2-(3,3-Dimethyl-2-methylidenebutyl)phenol
• CAS: 92035-88-6
• 化学式: C₁₃H₁₈O
• 分子量: 190.285
• InChiKey: NBBNYHIOYFOFBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  五甲基乙醇 在 potassium carbonate 作用下， 以 二苯醚 、 丙酮 为溶剂， 生成 2-(β-t-Butylallyl)-phenol
  参考文献：
  名称：

  The ortho-Claisen Rearrangement. III. The Rearrangement of β-Alkylallyl Aryl Ethers^1,2

  摘要：

  DOI：

  10.1021/ja01476a021

文献信息

• Compositions useful as additives for lubricants and liquid fuels
  申请人：The Lubrizol Corporation

  公开号：EP0624638A1

  公开（公告）日：1994-11-17

  A composition comprising at least one compound of the general formula wherein each Ar is independently an aromatic group having from 4 to about 30 carbon atoms and from 0 to 3 optional substituents selected from the group consisting of amino, hydroxy- or alkyl- polyoxyalkyl, nitro, aminoalkyl, carboxy or combinations of two or more of said optional substituents, each R is independently a hydrocarbyl group, R1 is H or a hydrocarbyl group, R2 and R3 are each, independently, H or a hydrocarbyl group, R4 is a monovalent terminating group, each m is independently 0 or an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, lower alkoxy, (OR5)bOR6 or 0- wherein each R5 is independently a divalent hydrocarbyl group, R6 is H or hydrocarbyl and b is a number ranging from 1 to about 30 and c ranges from 1 to about 3, y is a number ranging from 1 to about 10 and wherein the sum m + c does not exceed the number of valences of the corresponding Ar available for substitution and at least one A is a group characterized by the formula wherein Rb, RC, Rd and Re are each independently H, hydroxyhydrocarbyl or hydrocarbyl groups, X is O, S or NRa wherein Ra is H, hydrocarbyl, hydroxyhydrocarbyl, aminohydrocarbyl or a group of the formula wherein each Y is a group of the formula or each R5 is a divalent hydrocarbyl group, each R7 is H, alkoxyalkyl, hydroxyalkyl, a hydrocarbyl group, an aminohydrocarbyl group, or an N-alkoxyalkyl- or hydroxyalkyl- substituted aminohydrocarbyl group, a is 0 or a number ranging from 1 to about 100 and D is a group of the formula In one embodiment, (I) is present in fuel compositions. In another embodiment it is used in lubricating oil compositions.

  一种包含至少一种通式化合物的组合物 其中每个 Ar 独立地为具有 4 至约 30 个碳原子的芳香基团，以及 0 至 3 个选自氨基、羟基或烷基聚氧烷基、硝基、氨基烷基、羧基或两个或多个所述任选取代基的组合的任选取代基，每个 R 独立地为烃基，R1 为 H 或烃基，R2 和 R3 各自独立地为 H 或烃基，R4 为单价终止基、每个 m 独立地为 0 或 1 至约 10 的整数，x 为 0 至约 8，每个 Z 独立地为 OH、低级烷氧基、(OR5)bOR6 或 0-，其中每个 R5 独立地为二价烃基、R6 是 H 或烃基，b 是 1 至约 30 之间的数值，c 是 1 至约 3 之间的数值，y 是 1 至约 10 之间的数值，其中 m + c 之和不超过相应 Ar 可用于取代的价数，且至少有一个 A 是具有以下式子特征的基团： a. R6 是 H 或烃基，b 是 1 至约 30 之间的数值，c 是 1 至约 3 之间的数值，y 是 1 至约 10 之间的数值，其中 m + c 之和不超过相应 Ar 可用于取代的价数。 其中 Rb、RC、Rd 和 Re 各自独立地为 H、羟基烃基或烃基、 X是O、S或NRa，其中Ra是H、烃基、羟基烃基、氨基烃基或式中的基团 其中每个 Y 都是式中的基团 或 每个 R5 是二价烃基，每个 R7 是 H、烷氧基烷基、羟基烷基、烃基、氨基烃基或被 N-烷氧基烷基或羟基烷基取代的氨基烃基，a 是 0 或 1 至约 100 的数字，D 是式中的一个基团 在一个实施方案中，(I) 存在于燃料组合物中。在另一个实施方案中，它用于润滑油组合物中。
• Fuel composition
  申请人：The Lubrizol Corporation

  公开号：EP0624639A1

  公开（公告）日：1994-11-17

  A fuel composition comprising a major amount of a normally liquid fuel and a minor amount of at least one compound of the general formula wherein each Ar is independently an aromatic group having from 4 to about 30 carbon atoms and from 0 to 3 optional substituents selected from the group consisting of amino, hydroxy- or alkyl- polyoxyalkyl, nitro, aminoalkyl, carboxy or combinations of two or more of said optional substituents, each R is independently a hydrocarbyl group, R1 is H or a hydrocarbyl group, R2 and R3 are each, independently, H or a hydrocarbyl group, R4 is a monovalent terminating group, each m is independently 0 or an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, lower alkoxy, (OR5)bOR6 or 0- wherein each R5 is independently a divalent hydrocarbyl group, R6 is H or hydrocarbyl and b is a number ranging from 1 to about 30 and c ranges from 1 to about 3, y is a number ranging from 1 to about 10 and wherein the sum m + c does not exceed the number of valences of the corresponding Ar available for substitution and at least one A is independently an amide or an amide-containing group. In one embodiment, (I) is present in an amount effective to provide total fuel intake system cleanliness in a port fuel injected internal combustion engine.

  一种燃料组合物，它包含主要量的正常液体燃料和少量的至少一种通式化合物 其中每个 Ar 独立地为具有 4 至约 30 个碳原子的芳香基团，以及 0 至 3 个选自氨基、羟基或烷基聚氧烷基、硝基、氨基烷基、羧基或两个或两个以上所述任选取代基的组合的任选取代基，每个 R 独立地为烃基，R1 为 H 或烃基，R2 和 R3 各自独立地为 H 或烃基，R4 为单价终止基，每个 m 独立地为 0 或范围为 1 至约 10 的整数、x 范围为 0 至约 8，且每个 Z 独立地为 OH、低级烷氧基、(OR5)bOR6 或 0-，其中每个 R5 独立地为二价烃基，R6 为 H 或烃基，b 为范围为 1 至约 30 的数字，c 为范围为 1 至约 3 的数字，y 为范围为 1 至约 10 的数字，其中 m+c 之和不超过相应 Ar 可用于取代的价数，且至少一个 A 独立地为酰胺或含酰胺基团。在一个实施方案中，(I)的存在量可有效提供端口燃料喷射内燃机进气系统的总体清洁度。
• Two-stroke engine lubricant and method of using same
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0696635A2

  公开（公告）日：1996-02-14

  Two-stroke cycle engine lubricant and lubricant fuel composition comprise a composition prepared by reacting an aromatic compound of the formula with a carboxylic reactant         R¹ CO(CRR³)x COOR¹⁰ and optionally, ammonia or amines. In another embodiment the 2-stroke cycle lubricants contain a carboxylic composition of the formula wherein the various groups are defined herein.

  二冲程循环发动机润滑油和润滑油燃料组合物包括一种通过反应式如下的芳香族化合物制备的组合物 与羧基反应物 R¹ CO(CRR³)x COOR¹⁰ 以及氨或胺。 在另一个实施方案中，二冲程循环润滑剂含有式中的羧基组合物 其中各基团的定义见本文。
• Antioxidant composition for motor gasoline
  申请人：Gupta Ateet Anurag

  公开号：US20050091914A1

  公开（公告）日：2005-05-05

  An antioxidant composition effective for stabilizing gasoline and gasoline components contains from approximately 50-95% by weight of at least one Mannich base and from approximately 5-50% by weight of at least one amine. The Mannich base is derived from p-substituted phenols or from cashew nut shell liquid.
• US5336278A
  申请人：——

  公开号：US5336278A

  公开（公告）日：1994-08-09