hexan-2-one semicarbazone | 3622-64-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: hexan-2-one semicarbazone
• 英文别名: Hexan-2-on-semicarbazon；Methylbutylketon-semicarbazon；Methyl-butylketon-semicarbazon；Hexanon-(2)-semicarbazon；2-Hexanon-semicarbazon；Hexan-2-onsemicarbazon；Butylmethylketone semicarbazone；(hexan-2-ylideneamino)urea
• CAS: 3622-64-8
• 化学式: C₇H₁₅N₃O
• mdl: MFCD20542083
• 分子量: 157.216
• InChiKey: HWOZJMWUVWDNOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.714
• 拓扑面积：
  67.5
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2928000090

反应信息

• 作为反应物：
  描述：

  hexan-2-one semicarbazone 在 tetraethylammonium bromate 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以64%的产率得到2-己酮
  参考文献：
  名称：

  Baruah, Akashi; Nath, Utpal; Das, Satya Sandhya, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006, vol. 45, # 9, p. 2157 - 2160

  摘要：

  DOI：
• 作为产物：
  描述：

  2-己酮 生成 hexan-2-one semicarbazone
  参考文献：
  名称：

  The magnetic susceptibility of some semicarbazones, oximes and 2:4-dinitrophenylhydrazones

  摘要：

  DOI：

  10.1039/tf9595501689

文献信息

• Basic Alumina as an Efficient Catalyst for Preparation of Semicarbazones in Solvent Free Conditions
  作者：Ali Reza Kiasat、Foad Kazemi、Mehdi Fallah Mehrjardi

  DOI：10.1002/jccs.200700189

  日期：2007.10

  An efficient and simple procedure for conversion of different classes of aldehydes and ketones into the corresponding semicarbazones with semicarbazide hydrochloride using basic alumina is studied.

  研究了一种使用碱性氧化铝将不同类别的醛和酮转化为相应的氨基脲与氨基脲盐酸盐的有效且简单的程序。
• Blaise; Luttringer, Bulletin de la Societe Chimique de France, 1905, vol. <3>33, p. 821
  作者：Blaise、Luttringer

  DOI：——

  日期：——
• Wolff, Justus Liebigs Annalen der Chemie, 1912, vol. 394, p. 85
  作者：Wolff

  DOI：——

  日期：——
• Synthesis and IR Spectral Study of Semicarbazone and Thiosemicarbazones of 4-Methyl-2-pentanone and Their Metal Complexes
  作者：Pratibha Patel、B. V. Agarwala

  DOI：10.1080/00945719608004397

  日期：1996.11

  Novel copper(II) and nickel(II) complexes having the molecular formula [ML(2)X(2)].2H(2)O, (L = 4 - methyl-2-pentanone thiosemicarbazone or 4-methyl-2-pentanone semicarbazone and X = Cl-, CH3COO- or 1/2 SO42-) were synthesised and characterised on the basis of elemental analyses, molar conductance and IR spectral studies, The IR data indicate that both ligands are neutral bidentate, coordinating through the azomethine nitrogen and ketonic oxygen in the semicarbazone and thionic sulfur in the thiosemicarbazone. The low molar conductance values suggest the complexes to be nonelectrolytes and the involvement of anions in the coordination. An octahedral geometry has been proposed for all these new bisligated complexes.
• Baruah, Akashi; Nath, Utpal; Das, Satya Sandhya, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006, vol. 45, # 9, p. 2157 - 2160
  作者：Baruah, Akashi、Nath, Utpal、Das, Satya Sandhya、Das, Pranab Jyoti

  DOI：——

  日期：——