2-hydroxybenzylamine-2'-hydroxy-5'-chlorobenzylidene | 4226-29-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-hydroxybenzylamine-2'-hydroxy-5'-chlorobenzylidene
• 英文别名: 5-chlorosalicylaldehyde-o-hydroxybenzyl amine；5-chlorosal-o-hyba；2-[(5-chloro-2-hydroxy-benzylidenamino)-methyl]-phenol；2-[(5-Chlor-2-hydroxy-benzylidenamino)-methyl]-phenol；5-Chlor-2-hydroxy-benzaldehyd-salicylimin；<5-Chlor-salicylal>-salicylamin；o-(5-Chloro-salicylideneaminomethyl)phenol；4-chloro-2-[(2-hydroxyphenyl)methyliminomethyl]phenol
• CAS: 4226-29-3
• 化学式: C₁₄H₁₂ClNO₂
• 分子量: 261.708
• InChiKey: WTZYOQIUSPVXHW-UHFFFAOYSA-N

物化性质

• 沸点：
  437.5±45.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  52.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-hydroxybenzylamine-2'-hydroxy-5'-chlorobenzylidene 、 nickel(II) acetate tetrahydrate 以 乙醇 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Syamal, A.; Gupta, B. K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1982, vol. 21, # 1, p. 83 - 84

  摘要：

  DOI：

文献信息

• Synthesis and Characterization of a Series of Mononuclear Manganese(IV) Complexes with<i>o</i>-(Salicylideneaminomethyl)phenol and Its Substituted Derivatives
  作者：Masahiro Mikuriya、Dai Jie、Yoshihisa Kakuta、Tadashi Tokii

  DOI：10.1246/bcsj.66.1132

  日期：1993.4

  A series of manganese(IV) complexes, [Mn (R, R′-L)2]·nS (R or R′ = H, Cl, Br, CH3O; n = 1/2, 1, 3/2, 2; S = H2O, THF (THF = tetrahydrofuran)) where H2(R, R′-L) denotes o-(salicylideneaminomethyl)phenol with the substituent R on the salicylideneamino ring and the R′ on the aminomethylphenol ring, have been prepared and characterized by infrared and electronic spectra, magnetic moments, cyclic voltammetry

  一系列锰(IV)配合物，[Mn (R, R'-L)2]·nS (R or R' = H, Cl, Br, CH3O; n = 1/2, 1, 3/2, 2 ; S = H2O, THF (THF = 四氢呋喃)) 其中 H2(R, R'-L) 表示邻（水杨基氨基甲基）苯酚，取代基 R 位于水杨基氨基环上，R' 位于氨基甲基苯酚环上，已制备并通过红外和电子光谱、磁矩、循环伏安法和光谱电化学实验表征。[Mn (5-Cl'-L)2]·2THF的分子结构已通过X射线晶体学确定。配体作为经向三齿 ONO 供体，复合物具有 MnO4N2 配位球。讨论了与分子结构相关的光谱、磁性和电化学特性。
• Metal Chelates of Cerium(III), Thorium(IV), and Dioxouranium(VI); Complexes with Some Derivatives of Aryl Schiff Bases
  作者：M. E. Moustafa

  DOI：10.1081/sim-120019998

  日期：2003.1.6

  New Ce(III), Th(IV) and U(VI) complexes with the aryl Schiff bases 2-hydroxybenzylamine-2'-hydroxybenzylidene (HL1), -2'-hydroxynaphthylidene (HL2), -2'-hydroxy-5'-bromobenzylidene (HL1), -2'-hydroxy-5'-chlorobenzylidene (HL4), 2'-hydroxy-3',5'-dichlorobenzylidene (HL5) and 2'-hydroxy-3-methoxybenzylidene (HL6) have been synthesized and characterized by elemental and thermal analyses, molar conductance, magnetic susceptibility, IR, H-1 NMR and electronic spectra. Elemental analyses along with conductometric titrations showed the formation of 1:1 and 1:2 (M:L) complexes while IR, molar conductance and H-1 NMR data proved that these ligands act as monobasic, tridentates for the 1: 1 and monobasic, bidentates for the 1:2 complexes with a coordination number of eight in both.
• Syamal, A.; Gupta, B. K., Journal of the Indian Chemical Society, 1982, vol. 59, p. 697 - 698
  作者：Syamal, A.、Gupta, B. K.

  DOI：——

  日期：——
• Yamaguchi, M., Nippon Kagaku Zasshi, 1953, vol. 74, p. 261 - 263
  作者：Yamaguchi, M.

  DOI：——

  日期：——
• Syamal, A.; Ahmed, S.; Kumar, D., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1989, vol. 28, # 9, p. 783 - 786
  作者：Syamal, A.、Ahmed, S.、Kumar, D.

  DOI：——

  日期：——