N,N-Bis(4-methoxyphenyl)-4'-methyl[1,1'-biphenyl]-4-amine | 135722-67-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-Bis(4-methoxyphenyl)-4'-methyl[1,1'-biphenyl]-4-amine
• 英文别名: N,N-bis(4-methoxyphenyl)-4-(4-methylphenyl)aniline
• CAS: 135722-67-7
• 化学式: C₂₇H₂₅NO₂
• 分子量: 395.501
• InChiKey: XHEMTJNXVKSQIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4,4'-二甲氧基二苯胺 、 alkaline earth salt of/the/ methylsulfuric acid 在 铜 、 potassium carbonate 作用下， 以 硝基苯 为溶剂， 以31.6%的产率得到N,N-Bis(4-methoxyphenyl)-4'-methyl[1,1'-biphenyl]-4-amine
  参考文献：
  名称：

  含有偶氮化合物的层状光感受器中的电子转移过程

  摘要：

  光致电子转移（ET）是有机光电器件中载流子光生最重要的过程。在基于偶氮化合物的层状光感受器中，载流子光生通过空穴传输材料 (HTM) 的掺入而敏感。我们研究了这个过程以阐明高度敏化的机制。首先，测量并比较层状光感受器和载流子生成层的光致 ET 效率和整体量子效率。HTM 增强光诱导 ET 的结果意味着 HTM 催化作用以减少活化能。尽管这种外在 ET 独立于电场发生，但随后的成对解离取决于电场。下一个，通过使用 50 多个光感受器在很宽的范围内改变能隙，研究了 ET 的能隙依赖性。测量的效率针对能隙绘制，其中未观察到倒置区域。

  DOI：

  10.1246/bcsj.73.785

文献信息

• ELECTROCHROMIC COMPOUND, ELECTROCHROMIC COMPOSITION, AND ELECTROCHROMIC ELEMENT
  申请人：Goto Daisuke

  公开号：US20180208834A1

  公开（公告）日：2018-07-26

  An electrochromic compound represented by the following formula (1) is provided: where each of R 1 to R 9 and Ar 1 to Ar 6 independently represents one of a hydrogen atom, a halogen atom, a monovalent organic group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, a group in which two or more aryl and/or heteroaryl groups are condensed with each other to form a ring, and a polymerizable functional group; and at least one of Ar 1 to Ar 6 represents an aryl group, a heteroaryl group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, or a group in which at least two aryl or heteroaryl groups are condensed with each other to form a ring.

  提供以下式（1）所表示的一个电致变色化合物：其中R1至R9和Ar1至Ar6中的每一个独立表示氢原子、卤原子、一价有机基团、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的基团、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的环、以及可聚合的功能基团；并且Ar1至Ar6中至少有一个表示芳基、杂环芳基、通过共价键相互连接的两个或更多芳基和/或杂环芳基组成的基团，或者至少有两个芳基或杂环芳基通过共价键相互连接形成环。
• Electrochromic element, optical filter, lens unit, imaging apparatus, and window member
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10444588B2

  公开（公告）日：2019-10-15

  Provided is an electrochromic element, including: a pair of electrodes; and an electrochromic layer disposed between the pair of electrodes and containing a plurality of kinds of organic electrochromic compounds, in which: at least one kind of the plurality of kinds of organic electrochromic compounds includes an organic electrochromic compound having an absorption peak in a wavelength region of 700 nm or more during coloring thereof; and when an optical density in a decolored state thereof is defined as 0, a fluctuation ratio of a transmittance in a wavelength region of from 650 nm or more to 700 nm or less with respect to a central transmittance is within ±15% at an optical density of 0.3.

  提供了一种电致变色元件，包括：一对电极；以及设置在这对电极之间的电致变色层，其中包含多种有机电致变色化合物，其中多种有机电致变色化合物中的至少一种包括在其着色过程中在 700 纳米或更高波长区域具有吸收峰的有机电致变色化合物；当其脱色状态下的光密度定义为 0 时，在光密度为 0 时，从 650 纳米或更高到 700 纳米或更低波长区域的透射率相对于中心透射率的波动比在±15%以内。3.
• Electrochromic compound, electrochromic composition, and electrochromic element
  申请人：Goto Daisuke

  公开号：US10975296B2

  公开（公告）日：2021-04-13

  An electrochromic compound represented by the following formula (1) is provided: where each of R1 to R9 and Ar1 to Ar6 independently represents one of a hydrogen atom, a halogen atom, a monovalent organic group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, a group in which two or more aryl and/or heteroaryl groups are condensed with each other to form a ring, and a polymerizable functional group; and at least one of Ar1 to Ar6 represents an aryl group, a heteroaryl group, a group in which two or more aryl and/or heteroaryl groups are bound to each other via a covalent bond, or a group in which at least two aryl or heteroaryl groups are condensed with each other to form a ring.

  提供了一种由下式（1）表示的电致变色化合物： 其中 R1 至 R9 和 Ar1 至 Ar6 各自独立地代表氢原子、卤素原子、一价有机基团、两个或两个以上芳基和/或杂芳基通过共价键相互结合的基团、两个或两个以上芳基和/或杂芳基相互缩合形成环的基团和可聚合官能团中的一种；Ar1 至 Ar6 中的至少一个代表芳基、杂芳基、两个或两个以上芳基和/或杂芳基通过共价键相互结合的基团，或至少两个芳基或杂芳基相互缩合形成环的基团。
• OPTICAL DETECTOR
  申请人：BASF SE

  公开号：EP3036503B1

  公开（公告）日：2019-08-07
• ELECTROCHROMIC ELEMENT, OPTICAL FILTER, LENS UNIT, IMAGING APPARATUS, AND WINDOW MEMBER
  申请人：Canon Kabushiki Kaisha

  公开号：EP3320392B1

  公开（公告）日：2021-10-27