bis(2-(i-butylsulfanyl)-ethyl)amine | 220436-76-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(2-(i-butylsulfanyl)-ethyl)amine
• 英文别名: 2-(2-methylpropylsulfanyl)-N-[2-(2-methylpropylsulfanyl)ethyl]ethanamine
• CAS: 220436-76-0
• 化学式: C₁₂H₂₇NS₂
• 分子量: 249.485
• InChiKey: APZQQEGQOXKMEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  62.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  potassium tetrachloropalladate(II) 、 bis(2-(i-butylsulfanyl)-ethyl)amine 、 水 以 乙醇 、 水 为溶剂， 以56%的产率得到[PdCl(bis(2-(i-butylsulfanyl)-ethyl)amine)]Cl*2H2O
  参考文献：
  名称：

  Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water

  摘要：

  一种具有[SNS]供体组合的水兼容Pd(II)螯合剂，[L1PdCl]Cl·2H2O [L1 = 双(2-(异丁硫基)乙基)胺]已被分离并结晶学特征化；其在223 K下的固态晶格含有四聚体的梯状水聚合物，阳离子、阴离子和水簇之间存在大量的氢键，这种水溶性配合物在水相中在75°C下对苯硼酸和选定芳基溴化物的Suzuki-Miyaura偶联反应表现出活性。

  DOI：

  10.1039/b802043d

文献信息

• Quinoline derivative and use of same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0818512A1

  公开（公告）日：1998-01-14

  Quinoline compound, zinc halogenide complex and zinc complex suited for use in an electro-luminescence element, a fluorescent material and an ultraviolet absorption material, and a preparation process for these compounds are described. These compounds and a tautomer of the same has a strong luminescent intensity and is used for an EL material, the compound of zinc halogenide complex and zinc complex and a tautomer of the same has absorption at a wave length of 400nm or less and is used for an ultraviolet absorption material, and further the quinoline compound and a tautomer has a strong luminescent intensity and is used for a fluorescent material. The zinc halogenide complex and zinc complex can be prepared by each other related preparation processes directly from a quinoline derivative and a phthalimide derivative, or by way of the quinoline compound which is obtained from these derivatives.

  描述了适用于电致发光元件、荧光材料和紫外线吸收材料的喹啉化合物、卤化锌络合物和锌络合物，以及这些化合物的制备工艺。 这些化合物及其同系物具有很强的发光强度，可用于电致发光材料；卤化锌络合物和锌络合物的化合物及其同系物在波长为 400nm 或以下时有吸收，可用于紫外线吸收材料；此外，喹啉化合物及其同系物具有很强的发光强度，可用于荧光材料。 卤化锌络合物和锌络合物可以直接从喹啉衍生物和邻苯二甲酰亚胺衍生物，或通过从这些衍生物中得到的喹啉化合物，通过彼此相关的制备工艺制备。
• Rewritable optical information recording medium, recording and reproducing methods, as well as recording and reproducing apparatus
  申请人：Tamada Sakuya

  公开号：US20060088786A1

  公开（公告）日：2006-04-27

  A rewritable optical information recording medium including a recording layer composed of an organic dye film is provided, in which recording and erasing information can be performed reversibly by laser light irradiation. A rewritable optical information recording medium including at least one organic dye film which is substantially made of only at least one kind of organic dye compounds as a recording film is provided. The recording and erasure of information are performed by a reversible physical change of the organic dye film substance caused by laser light irradiation. Specifically, data recording is performed by a physical change locally caused by the irradiation of recording laser light, data reproduction is performed by detecting change in intensity of returned light of reproducing laser light having less power than the recording laser light, and data erasure is performed by applying at least once continuous light or pulse light having laser power more than the reproducing laser light and less than the recording laser light. The physical change is a change in shape.
• US6132640A
  申请人：——

  公开号：US6132640A

  公开（公告）日：2000-10-17
• US6407242B1
  申请人：——

  公开号：US6407242B1

  公开（公告）日：2002-06-18
• Isolation of an [SNS]Pd(ii) pincer with a water ladder and its Suzuki coupling activity in water
  作者：Shi-Qiang Bai、T. S. Andy Hor

  DOI：10.1039/b802043d

  日期：——

  A water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L1PdCl]Cl·2H2O [L1 = bis-(2-(i-butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki–Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75 °C.

  一种具有[SNS]供体组合的水兼容Pd(II)螯合剂，[L1PdCl]Cl·2H2O [L1 = 双(2-(异丁硫基)乙基)胺]已被分离并结晶学特征化；其在223 K下的固态晶格含有四聚体的梯状水聚合物，阳离子、阴离子和水簇之间存在大量的氢键，这种水溶性配合物在水相中在75°C下对苯硼酸和选定芳基溴化物的Suzuki-Miyaura偶联反应表现出活性。