2-(1,2-dihydroacenaphthylen-1-yl)propan-2-ol | 92669-63-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(1,2-dihydroacenaphthylen-1-yl)propan-2-ol
• 英文别名: 1-(2-hydroxy-2-propyl)acenaphthene
• CAS: 92669-63-1
• 化学式: C₁₅H₁₆O
• 分子量: 212.291
• InChiKey: NQWCEFAMRPZNCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-苊基(二异丁基)铝 在 对甲苯磺酸 作用下， 以 正庚烷 、 氯仿 、 苯 为溶剂， 反应 1.25h， 生成 2-(1,2-dihydroacenaphthylen-1-yl)propan-2-ol
  参考文献：
  名称：

  Organometallic compounds of Group III. 40. Kinetic control and locoselectivity in the electrophilic cleavage of allylic aluminum compounds: reactions of acenaphthenylaluminum reagents with carbonyl substrates

  摘要：

  DOI：

  10.1021/jo00198a011

文献信息

• DTBB-Catalysed Lithiation of Acenaphthylene and Reaction with Carbonyl Compounds
  作者：Cecilia Gómez、Miguel Yus、Victor Lillo

  DOI：10.1055/s-2008-1042943

  日期：2008.4

  The reaction of acenaphthylene with an excess of lithium powder and a catalytic amount of DTBB (7.5 mol%) in tetrahydrofuran at -70 °C followed by treatment with a carbonyl compound [Me 2 CO, Et 2 CO, I-Pr 2 CO, ( C-C 3 H 5 ) 2 CO, cyclopentanone, cyclohexanone, 2-adamantanone, Ph 2 CO, T-BuCHO] leads, after hydrolysis with water, to an easily chromatographically separable mixture of two products resulting

  苊与过量的锂粉和催化量的 DTBB (7.5 mol%) 在四氢呋喃中于 -70 °C 反应，然后用羰基化合物 [Me 2 CO, Et 2 CO, I-Pr 2 CO, (CC 3 H 5 ) 2 CO, 环戊酮, 环己酮, 2-金刚烷酮, Ph 2 CO, T-BuCHO] 用水水解后，在 1,2-位置和 1 位的单取代，分别。该反应是区域选择性和立体选择性的，因此在二取代化合物的情况下，仅获得反式非对映异构体。
• EISCH, J. J.;FICHTER, K. C., J. ORG. CHEM., 1984, 49, N 24, 4631-4639
  作者：EISCH, J. J.、FICHTER, K. C.

  DOI：——

  日期：——
• POSITIVE RESIST COMPOSITION AND PATTERNING PROCESS
  申请人：Hatakeyama Jun

  公开号：US20130084529A1

  公开（公告）日：2013-04-04

  A positive resist composition comprising a polymer having carboxyl groups substituted with an acid labile group having formula (1), (2) or (3) exhibits a high contrast of alkaline dissolution rate before and after exposure, a high resolution, a reduced acid diffusion rate, and forms a pattern with good profile, minimal edge roughness, and etch resistance. In formula (1), R 1 , R 2 , R 5 , R 6 , R 8 , and R 9 are alkyl, aryl, or alkenyl, R 3 , R 4 , R 7 , R 10 , and R 11 are hydrogen, alkyl, alkoxy, acyloxy, halogen, cyano, nitro, hydroxyl or trifluoromethyl, M is methylene or ethylene, R is a single bond or linking group.
• US8574817B2
  申请人：——

  公开号：US8574817B2

  公开（公告）日：2013-11-05
• Organometallic compounds of Group III. 40. Kinetic control and locoselectivity in the electrophilic cleavage of allylic aluminum compounds: reactions of acenaphthenylaluminum reagents with carbonyl substrates
  作者：John J. Eisch、Kenneth C. Fichter

  DOI：10.1021/jo00198a011

  日期：1984.11