tris(4-(phenanthren-9-yl)phenyl)amine | 349669-79-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tris(4-(phenanthren-9-yl)phenyl)amine
• 英文别名: (TPA-PA)；4-phenanthren-9-yl-N,N-bis(4-phenanthren-9-ylphenyl)aniline
• CAS: 349669-79-0
• 化学式: C₆₀H₃₉N
• 分子量: 773.976
• InChiKey: IUYBZMCOLOWDCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.5
• 重原子数：
  61
• 可旋转键数：
  6
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-溴菲 在 四(三苯基膦)钯 、 正丁基锂 、 sodium carbonate 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 72.5h， 生成 tris(4-(phenanthren-9-yl)phenyl)amine
  参考文献：
  名称：

  Highly efficient deep-blue electroluminescence based on the triphenylamine-cored and peripheral blue emitters with segregative HOMO–LUMO characteristics

  摘要：

  为了获得高效稳定的蓝色电致发光，特意设计并合成了两种新型星形化合物，它们由中心三苯胺（TPA）和外围蒽（AN）或菲（PA）两个官能团组成，在最高占位分子轨道和最低未占位分子轨道（HOMO 和 LUMO）之间具有明显的分离电子密度分布特征。作为发光层，它们不仅表现出高效的深蓝色电致发光，而且由于结合了多种优势特性（电化学、热和形态稳定性），在有机发光二极管（OLED）中也具有良好的稳定性。特别是对于三苯胺羰基菲（TPA-PA）来说，7.23% 的外部量子效率是未掺杂深蓝色有机发光二极管的最佳结果，而且该器件的寿命也得到了提高，在相同的器件条件下是 2-甲基-9,10-二（2-萘基）蒽（MADN）的两倍。

  DOI：

  10.1039/c1jm14639d

文献信息

• Facile one-pot nanocatalysts encapsulation of palladium–NHC complexes for aqueous Suzuki–Miyaura couplings
  作者：Chao Chen、Qing Zheng、Shengliang Ni、Hangxiang Wang

  DOI：10.1039/c7nj04836j

  日期：——

  nanoparticle encapsulation to fabricate water-soluble nanocatalysts (NCs) for aqueous cross-coupling reactions. To achieve this goal, three types of N-heterocyclic carbene (NHC)–palladium (Pd) complexes (i.e., 1b, 2b, and 3b) with the chemical formula [PdL(CH3CN)Cl]PF6 (where L is a bidentate pyridine- or pyrimidine-bearing NHC ligand) have been synthesized, and their structures were characterized by NMR spectroscopy

  使用水作为溶剂的有机转化已成为广泛研究的焦点。我们在此提出了一种策略，该策略使用简单的纳米颗粒封装来制造水溶性纳米催化剂（NC），以进行水交叉偶联反应。为了实现这一目标，三种类型的N-杂环卡宾的（NHC） -钯（Pd）的复合物（即，图1b，图2b，和图3b具有化学式）[PDL（CH 3 CN）CL] PF 6（其中L是含二齿吡啶或嘧啶的NHC配体）已被合成，并且它们的结构通过NMR光谱和X射线晶体学表征。利用一种简便的一锅封装方法，水不溶性Pd-NHC复合物可以整合到由两亲共聚物组成的胶束的疏水核中。这些水分散的纳米颗粒在Suzuki-Miyaura水溶液偶联中表现出出色的催化活性。在这些NC中，发现在其NHC配体上带有异氰酸酯部分的3b -NC在测试的反应条件下是活性最高的催化剂。更令人印象深刻的是，3b -NC可以重复使用至少五个循环而不会显着降低催化活性。
• Integrated System Built for Small-Molecule Semiconductors via High-Throughput Approaches
  作者：Jianchang Wu、Jiyun Zhang、Manman Hu、Patrick Reiser、Luca Torresi、Pascal Friederich、Leopold Lahn、Olga Kasian、Dirk M. Guldi、M. Eugenia Pérez-Ojeda、Anastasia Barabash、Juan S. Rocha-Ortiz、Yicheng Zhao、Zhiqiang Xie、Junsheng Luo、Yunuo Wang、Sang Il Seok、Jens A. Hauch、Christoph J. Brabec

  DOI：10.1021/jacs.3c03271

  日期：2023.8.2

  system for the high-throughput synthesis, purification, and characterization of molecules with a large variety. Based on the principle “Like dissolves like,” we combine theoretical calculations and a robotic platform to accelerate the purification of those molecules. With this platform, a material library containing 125 molecules and their optical-electronic properties was built within a timeframe of

  可溶液加工的结构可变小分子半导体的高通量合成既是机遇也是挑战。大量不同的分子为基于实验数据的快速材料发现和机器学习提供了可能性。然而分子结构的多样性导致了分子溶解度、极性、结晶度等性质的复杂性，给溶液处理和纯化带来了巨大的挑战。在这里，我们首先报道了一种用于多种分子的高通量合成、纯化和表征的集成系统。基于“同类相溶”的原理，我们结合理论计算和机器人平台来加速这些分子的纯化。借助该平台，在几周的时间内构建了包含 125 个分子及其光电特性的材料库。更重要的是，我们设计的高重复性重结晶是进一步升级和工业化生产的可靠途径。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND DISPLAY
  申请人：Kambe Emiko

  公开号：US20110024736A1

  公开（公告）日：2011-02-03

  An organic electroluminescent includes an organic layer with a total thickness of 150 nm or over is included between an anode and a cathode. The organic layer includes a light-emitting layer containing a host material of a polycyclic aromatic hydrocarbon compound with a basic skeleton having three to seven ring members, and hole supply layers arranged between the anode and the light-emitting layer and having a smaller thickness than a thickness of the light-emitting layer.
• ORGANIC ELECTROLUMINESCENT ELEMENT AND DISPLAY DEVICE
  申请人：SONY CORPORATION

  公开号：US20150171356A1

  公开（公告）日：2015-06-18

  An organic electroluminescence device that includes, between an anode 41 and a cathode 42 , an organic layer stacked structure 43 that comprises stacked plural emitting layers that emit light of different colors, wherein the organic electroluminescent device comprises, between the emitting layers, at least one intermediate layer that comprises a compound represented by the following formula (1) in which at least one of Ar 1 , Ar 2 and Ar 3 is a group represented by the following formula (2):
• ORGANIC LIGHT EMITTING DEVICE
  申请人：LG DISPLAY CO., LTD.

  公开号：US20210384437A1

  公开（公告）日：2021-12-09

  The present disclosure relates to an organic light emitting device. In particular, the present disclosure relates to an organic light emitting diode and an organic light emitting device each of which includes at least one emitting material layer comprising an anthracene-based host substituted with at least one deuterium and a boron-based dopant, at least one electron blocking layer comprising an aryl-substituted amine-based compound, and optionally at least one hole blocking layer comprising at least one of an azine-based compound and a benzimidazole-based compound. The organic light emitting diode and the organic light emitting device has improved luminous efficiency and enhanced luminous lifespan.