((trimethylsilyl)(t-butyl)amino)(t-butylimino)(seleno)phosphorane | 53787-02-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: ((trimethylsilyl)(t-butyl)amino)(t-butylimino)(seleno)phosphorane
• CAS: 53787-02-3
• 化学式: C₁₁H₂₇N₂PSeSi
• 分子量: 325.368
• InChiKey: ZELWRFASRWVVAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  ((trimethylsilyl)(t-butyl)amino)(t-butylimino)(seleno)phosphorane 在 sodium hydroxide 、 水 作用下， 以 乙醚 、 乙腈 为溶剂， 反应 0.5h， 生成 Natrium-bis(tert-butylamido)selenophosphat
  参考文献：
  名称：

  Scherer, Otto J.; Forstinger, Klaus; Kaub, Juergen, Chemische Berichte, 1986, vol. 119, # 9, p. 2731 - 2747

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N'-bis(t-butyl)-N-(trimethylsilyl)-phosphenimidous amide 在 selenium 作用下， 以 苯 为溶剂， 生成 ((trimethylsilyl)(t-butyl)amino)(t-butylimino)(seleno)phosphorane
  参考文献：
  名称：

  Elementorganische amin/imin-verbindungen

  摘要：

  DOI：

  10.1016/s0022-328x(00)86461-x

文献信息

• Romanenko, V. D.; Shul'gin, V. F.; Skopenko, V. V., Journal of general chemistry of the USSR, 1985, vol. 55, p. 246 - 253
  作者：Romanenko, V. D.、Shul'gin, V. F.、Skopenko, V. V.、Chernega, A. N.、Antipin, M. Yu.、et al.

  DOI：——

  日期：——
• Genuine heterocycles from the acid-induced cyclization of (silylamino)(imino)(chalcogeno)phosphoranes and as a result of chloride ion abstraction from bis[bis(trimethylsilyl)amino]thiophosphoryl chloride
  作者：Neil Burford、Simon Mason、Rupert E. H. Spence、J. Marc Whalen、John F. Richardson、Robin D. Rogers

  DOI：10.1021/om00042a045

  日期：1992.6

  The thio and seleno derivatives of the tricoordinate phosphorane P[NtBu(SiMe3)](NtBu)E 1 (E = S, Se) undergo a novel cyclization upon reaction with Lewis acids. A number of derivatives of the NSiEP framework have been isolated and characterized, including X-ray crystal structures of three derivatives, the neutral complexes NtBuSiMe2SP(Me)NtBu.AlCl3 (2a) and NtBuSiMe2SeP(Me)NtBu-GaCl3 (3), and the triflate salt of the protonated complex [NtBuSiMe2SP(Me)NtBu.H+] (2c). The new compounds are rare examples of ring systems which contain only one atom of each element in the heterocyclic framework, systems for which we introduce the terminology "genuine heterocycles". A similar cyclization process is observed for the new thiophosphoryl chloride P[N(SiMe3)2]2(S)Cl (4) in the presence of chloride ion acceptors to give salts of the cation [N(SiMe3)SiMe2SP(Me)N(SiMe3)2]+ (5), a direct analog of genuine heterocycles 2. Two salts of 5 have been structurally characterized. Both cyclization reactions have been examined by variable-temperature P-31 and H-1 NMR spectroscopy, and speculations are made as to the nature of the observed intermediates. The NSiSP(N) genuine heterocyclic unit is shown to be thermodynamically unstable with respect to the isomeric NSiNP(S) 1,3-diazasilaphosphetidine framework 6. The isomerization process is initiated by reaction with a base and can also be promoted thermally for salts of 5.
• Romanenko, V. D.; Shul'gin, V. F.; Brusilovets, A. I., Journal of general chemistry of the USSR, 1983, vol. 53, p. 211 - 212
  作者：Romanenko, V. D.、Shul'gin, V. F.、Brusilovets, A. I.、Skopenko, V. V.、Markovskii, L. N.

  DOI：——

  日期：——
• Scherer, Otto J.; Jungmann, Heribert; Krueger, Carl, Chemische Berichte, 1984, vol. 117, # 7, p. 2382 - 2392
  作者：Scherer, Otto J.、Jungmann, Heribert、Krueger, Carl、Wolmershaeuser, Gotthelf

  DOI：——

  日期：——
• Scherer, Otto J.; Forstinger, Klaus; Kaub, Juergen, Chemische Berichte, 1986, vol. 119, # 9, p. 2731 - 2747
  作者：Scherer, Otto J.、Forstinger, Klaus、Kaub, Juergen、Sheldrick, William S.

  DOI：——

  日期：——