tris-<(6-methyl-2,2'-bipyrazine-2-yl)methyl>amine | 162149-15-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris-<(6-methyl-2,2'-bipyrazine-2-yl)methyl>amine
• 英文别名: 1-[6-(6-methylpyrazin-2-yl)pyrazin-2-yl]-N,N-bis[[6-(6-methylpyrazin-2-yl)pyrazin-2-yl]methyl]methanamine
• CAS: 162149-15-7
• 化学式: C₃₀H₂₇N₁₃
• 分子量: 569.631
• InChiKey: MPWMTXNWIUGKMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.7
• 重原子数：
  43
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  158
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  europium(III) chloride hexahydrate 、 tris-<(6-methyl-2,2'-bipyrazine-2-yl)methyl>amine 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Bodar-Houillon, Florence; Marsura, Alain, New Journal of Chemistry, 1996, vol. 20, # 10, p. 1041 - 1045

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基-6-(6-甲基吡嗪-2-基)吡嗪 在 三氯异氰尿酸 、 氨 、 sodium carbonate 作用下， 以 四氯化碳 、 乙腈 为溶剂， 反应 24.0h， 生成 tris-<(6-methyl-2,2'-bipyrazine-2-yl)methyl>amine
  参考文献：
  名称：

  Synthesis and luminescence properties of a new tripode containing 2,2′-bipyrazine subunits: The tris-[(6-methyl-2,2′-bipyrazine-2-yl)methyl]amine

  摘要：

  New 6-methyl-2,2'-bipyrazinyl tripodal ligand 5 and pentadendate ligand 6 have been obtained in a one step alkali metal ion assisted reaction or in two steps from a 6-bipyrazine derivative. Eu(lII) and Tb(III) complexes have been synthesized, UV-Vis spectra show strong absorbance of both complexes at 295nm. Excitation of the Eu(III) complex in acetonitrile causes an emission of Eu3+ ion at 614 nm occuring of the A-ET-E($) process efficiency, preferentially along the transition D-5(0) --> F-7(2).

  DOI：

  10.1016/0040-4039(94)02381-k

文献信息

• Synthesis and luminescence properties of a new tripode containing 2,2′-bipyrazine subunits: The tris-[(6-methyl-2,2′-bipyrazine-2-yl)methyl]amine
  作者：Florence Bodar-Houillon、Alain Marsura

  DOI：10.1016/0040-4039(94)02381-k

  日期：1995.2

  New 6-methyl-2,2'-bipyrazinyl tripodal ligand 5 and pentadendate ligand 6 have been obtained in a one step alkali metal ion assisted reaction or in two steps from a 6-bipyrazine derivative. Eu(lII) and Tb(III) complexes have been synthesized, UV-Vis spectra show strong absorbance of both complexes at 295nm. Excitation of the Eu(III) complex in acetonitrile causes an emission of Eu3+ ion at 614 nm occuring of the A-ET-E($) process efficiency, preferentially along the transition D-5(0) --> F-7(2).
• Bodar-Houillon, Florence; Marsura, Alain, New Journal of Chemistry, 1996, vol. 20, # 10, p. 1041 - 1045
  作者：Bodar-Houillon, Florence、Marsura, Alain

  DOI：——

  日期：——