Benzoin-sec-butylether | 21217-83-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: Benzoin-sec-butylether
• 英文别名: Benzoin-sek.-butylether；2-[(Butan-2-yl)oxy]-1,2-diphenylethan-1-one；2-butan-2-yloxy-1,2-diphenylethanone
• CAS: 21217-83-4
• 化学式: C₁₈H₂₀O₂
• 分子量: 268.356
• InChiKey: DBBSWURSQHDBEQ-UHFFFAOYSA-N

物化性质

• 沸点：
  380.7±30.0 °C(Predicted)
• 密度：
  1.051±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  sec-BuMgBr 、 联苯甲酰 在 氯化铵 作用下， 生成 Benzoin-sec-butylether 、 安息香精油 、 2-Hydroxy-3-methyl-1,2-diphenylpentan-1-one
  参考文献：
  名称：

  Holm, T., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1987, vol. 41, # 4, p. 278 - 284

  摘要：

  DOI：

文献信息

• Photosensitive compositions containing carbonylic halides as activators
  申请人：Dynachem Corporation

  公开号：EP0005379A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component. a photoinitiator, a colorformer capable of changing color upon contact with a suitable activator and a latent activator containing an organic halide will become insoluble and change color under the influence of actinic radiation. The organic halide is a carbonylic compound such as an aliphatic or cycloaliphatic ketone or an ester or amide of a dicarboxylic acid. The compositions are useful to make resists used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、与适当活化剂接触后能变色的着色剂和含有有机卤化物的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并变色。 有机卤化物是一种羰基化合物，如脂肪族或环脂族酮或二羧酸的酯或酰胺。 这些组合物可用于制造电子工业中用于制造印刷电路的抗蚀剂。
• Phototropic photosensitive compositions containing a fluoran colorformer
  申请人：Dynachem Corporation

  公开号：EP0005380A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component, a photoinitiator, a fluoran colorformer and a latent activator that releases or promotes the release of a Lewis acid, will become insoluble and change color under the influence of actinic radiation. These compositions are particularly useful to make dry film photoresists, which are widely used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、荧光显色剂和可释放或促进释放路易斯酸的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并改变颜色。这些成分特别适用于制造干膜光阻，干膜光阻在电子工业中广泛用于制造印刷电路。
• N-alkylindolylidene and N-alkylbenzothiazolylidene alkanones as sensitizers for photopolymer compositions
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0103294A1

  公开（公告）日：1984-03-21

  Photopolymerizable compositions comprising (a) at least one ethylenically unsaturated compound, (b) at least one photoinitiator or photoinitiator system, (c) sensitizing amount of an N-alkylindolylidene or N-alkylbenzothiazolylidene alkanone as defined, and optionally (d) at least one organic polymeric binder. The compositions, in layer form are useful in printing plates, litho films, photoresists, solder mask and for making image proofs. The products show sensitization to visible light.

  可进行光聚合的组合物，包括(a)至少一种乙烯基不饱和化合物，(b)至少一种光引发剂或光引发剂体系，(c)如定义的 N-烷基吲哚亚基或 N-烷基苯并噻唑亚基烷酮的敏化量，以及(d)可选的至少一种有机聚合物粘合剂。层状组合物可用于印版、平版印刷膜、光刻胶、阻焊层和制作图像样张。产品对可见光有敏化作用。
• Photopolymer films containing microencapsulated sensitometric adjuvants
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0217324A2

  公开（公告）日：1987-04-08

  Photopolymerizable elements comprising a support, a layer of a photopolymerizable composition and a protective layer, the photopolymerizable layer having in reactive association therewith, e.g., dispersed therein or in contact with the surface, pressure rupturable microcapsules containing therein at least one active component for the photopolymerizable composition, e.g., ethylenically unsaturated compound, sensitizer, photoinitiator, oxygen scavenger, and plasticizer. Process for the preparation of an activated photopolymerizable element and use are described wherein the microcapsules are ruptured, i.e., prior to imagewise exposure and development. The photopolymerizable elements are useful as color proofs, printing plates. etc.

  可光聚合元件包括一个支撑物、一层可光聚合组合物和一个保护层，可光聚合层与之反应结合，例如，分散在其中或与表面接触，压力可破裂微胶囊，其中含有至少一种可光聚合组合物的活性成分，例如，乙烯不饱和化合物、敏化剂、光引发剂、氧清除剂和增塑剂。描述了制备活化的可光聚合元素的工艺和用途，其中微胶囊是破裂的，即在图像曝光和显影之前。这种可感光聚合元素可用作彩色打样、印版等。
• HOLM T., ACTA CHEM. SCAND., 41,(1987) N 4, 278-284
  作者：HOLM T.

  DOI：——

  日期：——