N1,N1,N3-trimethyl-N3-(2-(vinyloxy)ethyl)propane-1,3-diamine | 1196865-72-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N1,N1,N3-trimethyl-N3-(2-(vinyloxy)ethyl)propane-1,3-diamine
• 英文别名: Scavenger 2；N'-(2-ethenoxyethyl)-N,N,N'-trimethylpropane-1,3-diamine
• CAS: 1196865-72-1
• 化学式: C₁₀H₂₂N₂O
• 分子量: 186.297
• InChiKey: JRHZKFLACQKJRC-UHFFFAOYSA-N

物化性质

• 沸点：
  225.7±20.0 °C(Predicted)
• 密度：
  0.888±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  15.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-乙烯氧基乙醇 、 三甲基-1,3-丙二胺 在 4-二甲氨基吡啶 、 三乙胺 、 对甲苯磺酰氯 作用下， 以 二氯甲烷 为溶剂， 以18.3%的产率得到N1,N1,N3-trimethyl-N3-(2-(vinyloxy)ethyl)propane-1,3-diamine
  参考文献：
  名称：

  Di(ethylene glycol) vinyl ether: a highly efficient deactivating reagent for olefin metathesis catalysts

  摘要：

  A highly efficient method for deactivating commonly used olefin metathesis catalysts is described. Inexpensive and commercially available di(ethylene glycol) vinyl ether is found to quench both first- and second-generation Grubbs' carbenes in less than 10 min at room temperature. The resulting ruthenium byproducts are readily removed by silica gel purification. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.08.055
• 作为试剂：
  描述：

  二烯丙基丙二酸二乙酯 在 詹氏钌催化剂-1 、 N1,N1,N3-trimethyl-N3-(2-(vinyloxy)ethyl)propane-1,3-diamine 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以98%的产率得到3-环戊烯-1,1-二甲酸二乙酯
  参考文献：
  名称：

  Di(ethylene glycol) vinyl ether: a highly efficient deactivating reagent for olefin metathesis catalysts

  摘要：

  A highly efficient method for deactivating commonly used olefin metathesis catalysts is described. Inexpensive and commercially available di(ethylene glycol) vinyl ether is found to quench both first- and second-generation Grubbs' carbenes in less than 10 min at room temperature. The resulting ruthenium byproducts are readily removed by silica gel purification. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.08.055

文献信息

• Catalyst compositions and their use for hydrogenation of nitrile rubber
  申请人：ARLANXEO Deutschland GmbH

  公开号：US10508156B2

  公开（公告）日：2019-12-17

  Catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and specific co-catalysts are provided for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.

  提供了基于钌基或锇基络合物催化剂和特定助催化剂的催化剂组合物，用于在此类催化剂组合物存在下选择性氢化腈橡胶。
• PROCESS FOR HYDROGENATION OF NITRILE RUBBER USING CATALYST COMPOSITIONS COMPRISING A GRUBBS-HOVEYDA TYPE COMPLEX AND A TERMINAL OLEFIN
  申请人：ARLANXEO Deutschland GmbH

  公开号：EP2768611B1

  公开（公告）日：2018-08-01
• CATALYST COMPOSITIONS AND THEIR USE FOR HYDROGENATION OF NITRILE RUBBER
  申请人：LANXESS Deutschland Gmbh

  公开号：US20150025199A1

  公开（公告）日：2015-01-22

  This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts of the Grubbs-Hoveyda, Grela or Zhan type and specific co-catalysts comprising at least one vinyl group, pref. ethyl vinyl ether, and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions, preferably with a preceding metathesis step using the same complex catalyst as in the hydrogenation step.
• [EN] CATALYST COMPOSITIONS AND THEIR USE FOR HYDROGENATION OF NITRILE RUBBER<br/>[FR] COMPOSITIONS CATALYTIQUES ET LEUR UTILISATION POUR L'HYDROGÉNATION DE CAOUTCHOUC NITRILE
  申请人：LANXESS DEUTSCHLAND GMBH

  公开号：WO2013057289A2

  公开（公告）日：2013-04-25

  This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and specific co-catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.
• Di(ethylene glycol) vinyl ether: a highly efficient deactivating reagent for olefin metathesis catalysts
  作者：Weidong Liu、Paul J. Nichols、Nathan Smith

  DOI：10.1016/j.tetlet.2009.08.055

  日期：2009.11

  A highly efficient method for deactivating commonly used olefin metathesis catalysts is described. Inexpensive and commercially available di(ethylene glycol) vinyl ether is found to quench both first- and second-generation Grubbs' carbenes in less than 10 min at room temperature. The resulting ruthenium byproducts are readily removed by silica gel purification. (C) 2009 Elsevier Ltd. All rights reserved.