iPr2NB(N-tert-butyl-N-methallylamine(-2H)) | 1027098-22-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硼酸衍生物
• 英文名称: iPr2NB(N-tert-butyl-N-methallylamine(-2H))
• 英文别名: 1-tert-butyl-4-methyl-N,N-di(propan-2-yl)-5H-azaborol-2-amine
• CAS: 1027098-22-1
• 化学式: C₁₄H₂₉BN₂
• 分子量: 236.209
• InChiKey: NWFYFQHMBHWFOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.19
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iPr2NB(N-tert-butyl-N-methallylamine(-2H)) 、 双(三甲基硅烷基)氨基钾 以 not given 为溶剂， 生成 K[MeC3H2BN(tBu)N(iPr)2]
  参考文献：
  名称：

  Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry

  摘要：

  Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp(2)Zr(II)-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.

  DOI：

  10.1021/om8001075
• 作为产物：
  描述：

  BCl(N-tert-butyl-N-methallylamine(-2H)) 、 lithium diisopropyl amide 以 not given 为溶剂， 生成 iPr2NB(N-tert-butyl-N-methallylamine(-2H))
  参考文献：
  名称：

  Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry

  摘要：

  Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp(2)Zr(II)-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.

  DOI：

  10.1021/om8001075

文献信息

• Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry
  作者：Xiangdong Fang、Jalil Assoud

  DOI：10.1021/om8001075

  日期：2008.6.9

  Two synthetic methods for the preparation of tri- or tetrasubstituted 1,2-azaborolyls (Ab) are described. Both tri- and tetrasubstituted Ab rings can be conveniently attained via either dilithiation-directed or Cp(2)Zr(II)-mediated cyclization followed by transmetalation in good yields. In particular, anionic 1,2,4-trimethyl-1,2-azaborolyl and 1,2,3,4-tetramethyl-1,2-azaborolyl, readily prepared through our methods, have been demonstrated as good supporting ancillary ligands in group IV metal complexes.