(1,5-Dimethyl-hex-4-enyloxy)-triisopropyl-silane | 220466-95-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (1,5-Dimethyl-hex-4-enyloxy)-triisopropyl-silane
• 英文别名: 6-Methylhept-5-en-2-yloxy-tri(propan-2-yl)silane
• CAS: 220466-95-5
• 化学式: C₁₇H₃₆OSi
• 分子量: 284.558
• InChiKey: BLDIFPJNAIDYFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.31
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (1,5-Dimethyl-hex-4-enyloxy)-triisopropyl-silane 在 二甲基硫 、 臭氧 、 丙酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  A synthesis of the ring system of terpestacin

  摘要：

  The ring system of the sesterterpene terpestacin has been obtained from a cyclopentanic precursor prepared from endo-3-bromocamphor and from an acyclic keto phosphonate prepared from 6-methylhept-5-en-2-one. The connection of both compounds has been achieved by a Horner-Wadsworth-Emmons reaction on the one hand and by a McMurry reaction on the other. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)02535-0
• 作为产物：
  描述：

  6-甲基-5-庚烯-2-酮 在 咪唑 、 lithium aluminium tetrahydride 作用下， 以 乙醚 、 N,N-二甲基甲酰胺 为溶剂， 反应 9.0h， 生成 (1,5-Dimethyl-hex-4-enyloxy)-triisopropyl-silane
  参考文献：
  名称：

  A synthesis of the ring system of terpestacin

  摘要：

  The ring system of the sesterterpene terpestacin has been obtained from a cyclopentanic precursor prepared from endo-3-bromocamphor and from an acyclic keto phosphonate prepared from 6-methylhept-5-en-2-one. The connection of both compounds has been achieved by a Horner-Wadsworth-Emmons reaction on the one hand and by a McMurry reaction on the other. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)02535-0

文献信息

• A synthesis of the ring system of terpestacin
  作者：Marie-Paule Mermet-Mouttet、Kiroubagaranne Gabriel、Denis Heissler

  DOI：10.1016/s0040-4039(98)02535-0

  日期：1999.1

  The ring system of the sesterterpene terpestacin has been obtained from a cyclopentanic precursor prepared from endo-3-bromocamphor and from an acyclic keto phosphonate prepared from 6-methylhept-5-en-2-one. The connection of both compounds has been achieved by a Horner-Wadsworth-Emmons reaction on the one hand and by a McMurry reaction on the other. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.