N-(2-hydroxyethyl)-N,N-dibutylamine N-oxide | 95926-48-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2-hydroxyethyl)-N,N-dibutylamine N-oxide
• 英文别名: N-(2-Hydroxyethyl)-N,N-dibutylamin-N-oxid；N-butyl-N-(2-hydroxyethyl)butan-1-amine oxide
• CAS: 95926-48-0
• 化学式: C₁₀H₂₃NO₂
• 分子量: 189.298
• InChiKey: OEVODDGENRTTEE-UHFFFAOYSA-N

物化性质

• 熔点：
  97-99 °C (decomp)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二苯基硼酸酐 、 N-(2-hydroxyethyl)-N,N-dibutylamine N-oxide 以 乙醇 为溶剂， 以85%的产率得到4,4-dibutyl-2,2-diphenyl-1,3-dioxa-4-azonia-2-boratacyclohexane
  参考文献：
  名称：

  N-（2-羟烷基）-N，N-二烷基氨基-N-氧化物的合成与合成

  摘要：

  环状的各种二芳基硼酸螯合物B，N -betaine型（2,7，11）从合成ñ - （2-羟烷基） - N，N- -dialkylamine- Ñ -oxides（1）和二芳基硼酸试剂。它们在热诱导的分子内氧化还原反应中重排，在此期间，N-氧化物被脱氧，而硼酸部分则被氧化成硼酸状态。通过与N-氧化物（1）再螯合，将重排产物3、8和12转化为新的B，N-甜菜碱型螯合物5和9。

  DOI：

  10.1016/0022-328x(84)80698-1
• 作为产物：
  描述：

  2-(二丁氨基)乙醇 在 双氧水 作用下， 以43%的产率得到N-(2-hydroxyethyl)-N,N-dibutylamine N-oxide
  参考文献：
  名称：

  N-（2-羟烷基）-N，N-二烷基氨基-N-氧化物的合成与合成

  摘要：

  环状的各种二芳基硼酸螯合物B，N -betaine型（2,7，11）从合成ñ - （2-羟烷基） - N，N- -dialkylamine- Ñ -oxides（1）和二芳基硼酸试剂。它们在热诱导的分子内氧化还原反应中重排，在此期间，N-氧化物被脱氧，而硼酸部分则被氧化成硼酸状态。通过与N-氧化物（1）再螯合，将重排产物3、8和12转化为新的B，N-甜菜碱型螯合物5和9。

  DOI：

  10.1016/0022-328x(84)80698-1

文献信息

• Ethylenically unsaturated monomers for thickener compositions
  申请人：Bobsein Barrett Richard

  公开号：US20100286434A1

  公开（公告）日：2010-11-11

  New ethylenically unsaturated monomers are provided that can be (co)polymerized to provide a composition and method whereby the same group that is attached to or within the backbone of an associative thickener is reversibly switched between being hydrophilic and hydrophobic in nature. When the group that is attached to or within the backbone is rendered hydrophilic, the aqueous thickener is pourable and readily incorporated into aqueous polymer compositions. When this group is rendered hydrophobic, the thickener performs its thickening function efficiently. Switching is readily accomplished by adjusting the pH of the associative thickener composition and the aqueous polymer composition being thickened. The thickeners are prepared from the novel monomers by an aqueous solution polymerization.

  提供了新的具有乙烯基不饱和性的单体，可以进行(共)聚合以提供一种组合物和方法，其中连接到或在联合增稠剂骨架内的相同基团在亲水性和疏水性之间可逆地切换。当连接到或在骨架内的基团变为亲水性时，水性增稠剂是可倾倒的，并且容易与水性聚合物组成物混合。当这个基团变为疏水性时，增稠剂有效地执行其增稠功能。通过调整联合增稠剂组合物和被增稠的水性聚合物组成物的pH值，可以轻松实现切换。这些增稠剂通过水溶液聚合从新单体制备而成。
• Thickener composition and method for thickening aqueous systems
  申请人：Bobsein Barrett Richard

  公开号：US20100261813A1

  公开（公告）日：2010-10-14

  A composition and method whereby the same group that is attached to or within the backbone of an associative thickener is reversibly switched between being hydrophilic and hydrophobic in nature. The group comprises a tertiary amine, or tertiary phosphine and has a hydrocarbon radical bonded to the amine nitrogen atom or phosphine phosphorus atom, which hydrocarbon radical is pendant to the backbone and contains fewer than 10 carbon atoms. When the group that is attached to or within the backbone is rendered hydrophilic, the aqueous thickener is pourable and readily incorporated into aqueous polymer compositions. When this group is rendered hydrophobic, the thickener performs its thickening function efficiently. Switching is readily accomplished by adjusting the pH of the associative thickener composition and the aqueous polymer composition being thickened.

  一种构成和方法，其中与关联增稠剂的主干相连或内部的相同基团可在亲水性和疏水性之间可逆地切换。该基团包括三级胺或三级膦，并且具有与胺氮原子或膦磷原子结合的碳氢基团，该碳氢基团悬挂于主干上并且含有少于10个碳原子。当与主干相连的基团变为亲水性时，水性增稠剂是可倾倒的并且容易混合在水性聚合物组合物中。当这个基团变为疏水性时，增稠剂有效地完成其增稠功能。通过调整关联增稠剂组合物和被增稠的水性聚合物组合物的pH值，可轻松实现切换。
• Polymer Composition
  申请人：Rohm and Haas Company

  公开号：EP2112206A1

  公开（公告）日：2009-10-28

  A composition and method whereby the same group that is attached to or within the backbone of an associative thickener is reversibly switched between being hydrophilic and hydrophobic in nature. When the group that is attached to or within the backbone is rendered hydrophilic, the aqueous thickener is pourable and readily incorporated into aqueous polymer compositions. When this group is rendered hydrophobic, the thickener performs its thickening function efficiently. Switching is readily accomplished by adjusting the pH of the associative thickener composition and the aqueous polymer composition being thickened.

  一种组合物和方法，在这种组合物和方法中，附着在缔合增稠剂骨架上或骨架内的相同基团可在亲水性和疏水性之间进行可逆转换。当附着在骨架上或骨架内的基团被亲水化时，水性增稠剂具有流动性，并容易与水性聚合物组合物结合。当该基团变为疏水性时，增稠剂就能有效地发挥其增稠功能。通过调节缔合型增稠剂组合物和被增稠的水性聚合物组合物的 pH 值，可轻松实现切换。
• Thickened compositions and method for thickening aqueous polymer compositions
  申请人：Rohm and Haas Company

  公开号：EP2166044A1

  公开（公告）日：2010-03-24

  Thickened aqueous compositions, and a method for controlling viscosity drift for thickened aqueous compositions comprising a pigment, a polymer containing polymerized units of phosphate- or phosphonate-containing monomers, and an acid suppressible thickener.

  增稠水基组合物，以及控制增稠水基组合物粘度漂移的方法，该组合物包含颜料、含磷酸或含膦酸单体聚合单元的聚合物，以及可抑制酸的增稠剂。
• Single-site catalysts containing chelating N-oxide ligands
  申请人：EQUISTAR CHEMICALS, L.P.

  公开号：US20030032744A1

  公开（公告）日：2003-02-13

  A single-site olefin polymerization catalyst and method of making it are disclosed. The catalyst comprises an activator and an organometallic complex. The complex comprises a Group 3 to 10 transition or lanthanide metal, M, and at least one chelating N-oxide ligand that is bonded to M. Molecular modeling results indicate that single-site catalysts based on certain chelating N-oxide ligands (e.g., 2-hydroxypyridine) will rival the performance of catalysts based on cyclopentadienyl and substituted cyclopentadienyl ligands.

  本发明公开了一种单位烯烃聚合催化剂及其制造方法。催化剂包括活化剂和有机金属络合物。分子建模结果表明，基于某些螯合 N-氧化物配体（如 2-羟基吡啶）的单位催化剂的性能可与基于环戊二烯基和取代环戊二烯基配体的催化剂相媲美。